scholarly journals Three-dimensional mapping of the optical centers in the bulk of natural diamond by photoluminescent spectroscopy

2021 ◽  
Vol 2127 (1) ◽  
pp. 012049
Author(s):  
N G Stsepuro ◽  
M S Kovalev ◽  
G K Krasin ◽  
P A Danilov ◽  
S I Kudryashov

Abstract Optically active defects in natural diamonds form specific spectral bands in the optical absorption and luminescence spectra and are called optical centers. Optical centers in the visible spectral range and their corresponding defects are called color centers. Spectral absorption and luminescence bands usually occupy several tens of nanometers in the spectral range and often have a complex structure. This spectral structure is unique to each optical center. The stationary broadband UV-MIR characterization of the set of optically active defects in the bulk of natural diamond with a widely varying concentration of impurities was carried out in this work. Comparison of the initial and modified impurity-defect structures of near-surface diamond layers was carried out by the method of cathodoluminescence and cathodoluminescence topography.

2002 ◽  
Author(s):  
G. Gajiev ◽  
V. G. Golubev ◽  
D. A. Kurdyukov ◽  
Alexander B. Pevtsov ◽  
V. V. Travnikov

Sensors ◽  
2021 ◽  
Vol 21 (8) ◽  
pp. 2758
Author(s):  
Alberto Taffelli ◽  
Sandra Dirè ◽  
Alberto Quaranta ◽  
Lucio Pancheri

Photodetectors based on transition metal dichalcogenides (TMDs) have been widely reported in the literature and molybdenum disulfide (MoS2) has been the most extensively explored for photodetection applications. The properties of MoS2, such as direct band gap transition in low dimensional structures, strong light–matter interaction and good carrier mobility, combined with the possibility of fabricating thin MoS2 films, have attracted interest for this material in the field of optoelectronics. In this work, MoS2-based photodetectors are reviewed in terms of their main performance metrics, namely responsivity, detectivity, response time and dark current. Although neat MoS2-based detectors already show remarkable characteristics in the visible spectral range, MoS2 can be advantageously coupled with other materials to further improve the detector performance Nanoparticles (NPs) and quantum dots (QDs) have been exploited in combination with MoS2 to boost the response of the devices in the near ultraviolet (NUV) and infrared (IR) spectral range. Moreover, heterostructures with different materials (e.g., other TMDs, Graphene) can speed up the response of the photodetectors through the creation of built-in electric fields and the faster transport of charge carriers. Finally, in order to enhance the stability of the devices, perovskites have been exploited both as passivation layers and as electron reservoirs.


Author(s):  
Angeli Jayme ◽  
Imad L. Al-Qadi

A thermomechanical coupling between a hyper-viscoelastic tire and a representative pavement layer was conducted to assess the effect of various temperature profiles on the mechanical behavior of a rolling truck tire. The two deformable bodies, namely the tire and pavement layer, were subjected to steady-state-uniform and non-uniform temperature profiles to identify the significance of considering temperature as a variable in contact-stress prediction. A myriad of ambient, internal air, and pavement-surface conditions were simulated, along with combinations of applied tire load, tire-inflation pressure, and traveling speed. Analogous to winter, the low temperature profiles induced a smaller tire-pavement contact area that resulted in stress localization. On the other hand, under high temperature conditions during the summer, higher tire deformation resulted in lower contact-stress magnitudes owing to an increase in the tire-pavement contact area. In both conditions, vertical and longitudinal contact stresses are impacted, while transverse contact stresses are relatively less affected. This behavior, however, may change under a non-free-rolling condition, such as braking, accelerating, and cornering. By incorporating temperature into the tire-pavement interaction model, changes in the magnitude and distribution of the three-dimensional contact stresses were manifested. This would have a direct implication on the rolling resistance and near-surface behavior of flexible pavements.


2004 ◽  
Vol 443-444 ◽  
pp. 333-336
Author(s):  
N. Guillou ◽  
C. Livage ◽  
W. van Beek ◽  
G. Férey

Ni7(C4H4O4)4(OH)6(H2O)3. 7H2O, a new layered nickel(II) succinate, was prepared hydrothermally (180°C, 48 h, autogenous pressure) from a 1:1.5:4.1:120 mixture of nickel (II) chloride hexahydrate, succinic acid, potassium hydroxide and water. It crystallizes in the monoclinic system (space group P21/c, Z = 4) with the following parameters a = 7.8597(1) Å, b = 18.8154(3)Å, c = 23.4377(4) Å,ϐ = 92.0288(9)°, and V = 3463.9(2) Å3. Its structure, which contains 55 non-hydrogen atoms, was solved ab initio from synchrotron powder diffraction data. It can be described from hybrid organic-inorganic layers, constructed from nickel oxide corrugated chains. These chains are built up from NiO6hexameric units connected via a seventh octahedron. Half of the succinates decorate the chains, and the others connect them to form the layers. The three dimensional arrangement is ensured by hydrogen bonds directly between two adjacent layers and via free water molecules.


2014 ◽  
Vol 90 (12) ◽  
Author(s):  
Bivas Saha ◽  
Gururaj V. Naik ◽  
Sammy Saber ◽  
Cem Akatay ◽  
Eric A. Stach ◽  
...  

2007 ◽  
Vol 15 (2) ◽  
pp. 26-31 ◽  
Author(s):  
Ben Lich

DualBeam instruments that combine the imaging capability of scanning electron microscopy (SEM) with the cutting and deposition capability of a focused ion beam (FIB) provide biologists with a powerful tool for investigating three-dimensional structure with nanoscale (1 nm-100 nm) resolution. Ever since Van Leeuwenhoek used the first microscope to describe bacteria more than 300 years ago, microscopy has played a central role in scientists' efforts to understand biological systems. Light microscopy is generally limited to a useful resolution of about a micrometer. More recently the use of confocal and electron microscopy has enabled investigations at higher resolution. Used with fluorescent markers, confocal microscopy can detect and localize molecular scale features, but its imaging resolution is still limited. SEM is capable of nanometer resolution, but is limited to the near surface region of the sample.


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