scholarly journals Comparative Study on Degradability Characteristics of Evaporitic and Carbonate Rocks from Al Ain, United Arab Emirates

2021 ◽  
Vol 906 (1) ◽  
pp. 012130
Author(s):  
Hasan Arman ◽  
Mahmoud Abu Saima ◽  
Osman Abdelghany ◽  
Safwan Paramban

Abstract The slake durability index (SDI) test is a well know and extensively used to measure the degradability behaviour of rocks especially for weak rocks like mudstone, shale, evaporites, carbonates, etc. The degradability of rocks plays a critical role in engineering design process either on or in the rock mass for safe and sustainable structures. Evaporitic and carbonate rocks are vulnerable to physical, chemical and mechanical weathering, break down, as result of wetting-drying processes during the SDI test. Evaporites and carbonates are outcropped at the surface and subsurface of the Al Ain city, which is located on the south-eastern of Abu Dhabi, capital city of the United Arab Emirates (UAE) at various level, and it is one of the rapid growing cities in the UAE. However, the detailed comparative data on the slaking behaviour of evaporites and carbonates are not available presently in the study area. Therefore, this paper provides a comparative study on the degradability characteristics of evaporitic and carbonate rocks in the city of Al Ain as well as comprehensive data for the study area. 142 rock blocks (∼ 40×40×40 cm3 in size), which represent evaporitic (48 blocks) and carbonate (94 blocks) rocks were collected from various accessible either surfaces outcrops or excavated areas from the study area. 48 and 94 slake durability test samples of evaporites and carbonates were prepared and slake durability tests were performed according to the American Society for Testing and Materials (ASTM) standards. Furthermore, their compositional and textural characteristics were examined using polarized-light microscope, X-ray diffractometry (XRD), X-ray fluorescence (XRF) and scanning electron microscope (SEM). The degradability data for evaporite and carbonate rocks designate medium to very low and extremely high to very high values based on the classification after multiple cycling, Id1 to Id4, processes, respectively. The weight loss values from the first to the fourth cycles (Id1–Id4) of evaporite and carbonate samples are approximately 24–95 and 0.68-4.22 wt%. Obviously, evaporites are highly vulnerable compare to carbonates because of their differences in chemical and mineralogical structures and their reactions to the slaking fluid of distilled water. Hydration-dehydration effects on the evaporitic rocks may occur within short time compare to the carbonate rocks due to their natural occurrences. Thus, this study provide comparable and details information for the degradability characteristics of evaporitic and carbonate rocks, and likely improve the understanding of the durability of both rock types in the study area and elsewhere. Especially, such a reliable and inclusive information will compromise a practical guideline for engineers and decision makers to overcome difficulties on durability problems associated with evaporites and carbonates in the study area and elsewhere.

Author(s):  
Adekunle Dawodu ◽  
Yousef M. Abdulrazzaq ◽  
Abdulbari Bener ◽  
Inge Kappel ◽  
Larry Liddle ◽  
...  

2011 ◽  
Vol 4 (03) ◽  
pp. 160-164 ◽  
Author(s):  
Eiji Tamiya ◽  
Noriyuki Suzuki ◽  
Nobuhiko Ito ◽  
Sulan Dai ◽  
Teruhiko Aoyagi ◽  
...  

2004 ◽  
Vol 339 (5) ◽  
pp. 1103-1113 ◽  
Author(s):  
Siddhartha Roy ◽  
Surbhi Gupta ◽  
Satyabrata Das ◽  
K. Sekar ◽  
Dipankar Chatterji ◽  
...  

2013 ◽  
Vol 69 (10) ◽  
pp. 2072-2080 ◽  
Author(s):  
Adam Round ◽  
Elizabeth Brown ◽  
Romain Marcellin ◽  
Ulrike Kapp ◽  
Corey S. Westfall ◽  
...  

The combination of protein crystallography and small-angle X-ray scattering (SAXS) provides a powerful method to investigate changes in protein conformation. These complementary structural techniques were used to probe the solution structure of the apo and the ligand-bound forms of theArabidopsis thalianaacyl acid–amido synthetase GH3.12. This enzyme is part of the extensive GH3 family and plays a critical role in the regulation of plant hormones through the formation of amino-acid-conjugated hormone productsviaan ATP-dependent reaction mechanism. The enzyme adopts two distinct C-terminal domain orientations with `open' and `closed' active sites. Previous studies suggested that ATP only binds in the open orientation. Here, the X-ray crystal structure of GH3.12 is presented in the closed conformation in complex with the nonhydrolysable ATP analogue AMPCPP and the substrate salicylate. Using on-line HPLC purification combined with SAXS measurements, the most likely apo and ATP-bound protein conformations in solution were determined. These studies demonstrate that the C-terminal domain is flexible in the apo form and favours the closed conformation upon ATP binding. In addition, these data illustrate the efficacy of on-line HPLC purification integrated into the SAXS sample-handling environment to reliably monitor small changes in protein conformation through the collection of aggregate-free and highly redundant data.


1995 ◽  
Vol 20 (5) ◽  
pp. 426-433 ◽  
Author(s):  
AHMAD M. RAGHEB ◽  
ABDEL-HAMEED H. ELGAZZAR ◽  
ALY K. IBRAHIM ◽  
EZZATT HIGAZI ◽  
ABDEL-RAHMAN MAHMOUD ◽  
...  

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