Printing Parameters of Fused Filament Fabrication Affect Key Properties of Four-Dimensional Printed Shape-Memory Polymers

2021 ◽  
Author(s):  
Katy Pieri ◽  
Bailey M. Felix ◽  
Teng Zhang ◽  
Pranav Soman ◽  
James H. Henderson
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymers ◽  
Fused Filament Fabrication ◽  
Printing Parameters

scholarly journals Additive Manufacturing of Information Carriers Based on Shape Memory Polyester Urethane

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1005 ◽  
Author(s):  
Dilip Chalissery ◽  
Thorsten Pretsch ◽  
Sarah Staub ◽  
Heiko Andrä
Keyword(s):  
Additive Manufacturing ◽  
Shape Memory ◽  
Shape Memory Polymers ◽  
Qr Code ◽  
Stimuli Responsive ◽  
Fused Filament Fabrication ◽  
Responsive Materials ◽  
Manufacturing Method ◽  
Polyester Urethane ◽  
Machine Readable

Shape memory polymers (SMPs) are stimuli-responsive materials, which are able to retain an imposed, temporary shape and recover the initial, permanent shape through an external stimulus like heat. In this work, a novel manufacturing method is introduced for thermoresponsive quick response (QR) code carriers, which originally were developed as anticounterfeiting technology. Motivated by the fact that earlier manufacturing processes were sometimes too time-consuming for production, filaments of a polyester urethane (PEU) with and without dye were extruded and processed into QR code carriers using fused filament fabrication (FFF). Once programmed, the distinct shape memory properties enabled a heating-initiated switching from non-decodable to machine-readable QR codes. The results demonstrate that FFF constitutes a promising additive manufacturing technology to create complex, filigree structures with adjustable horizontal and vertical print resolution and, thus, an excellent basis to realize further technically demanding application concepts for shape memory polymers.

scholarly journals Fused Filament Fabrication-4D-Printed Shape Memory Polymers: A Review

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 701
Author(s):  
Sara Valvez ◽  
Paulo N. B. Reis ◽  
Luca Susmel ◽  
Filippo Berto
Keyword(s):  
Mechanical Properties ◽  
Additive Manufacturing ◽  
Shape Memory ◽  
Structural Integrity ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Layer By Layer ◽  
4D Printing ◽  
Fused Filament Fabrication ◽  
External Stimuli

Additive manufacturing (AM) is the process through which components/structures are produced layer-by-layer. In this context, 4D printing combines 3D printing with time so that this combination results in additively manufactured components that respond to external stimuli and, consequently, change their shape/volume or modify their mechanical properties. Therefore, 4D printing uses shape-memory materials that react to external stimuli such as pH, humidity, and temperature. Among the possible materials with shape memory effect (SME), the most suitable for additive manufacturing are shape memory polymers (SMPs). However, due to their weaknesses, shape memory polymer compounds (SMPCs) prove to be an effective alternative. On the other hand, out of all the additive manufacturing techniques, the most widely used is fused filament fabrication (FFF). In this context, the present paper aims to critically review all studies related to the mechanical properties of 4D-FFF materials. The paper provides an update state of the art showing the potential of 4D-FFF printing for different engineering applications, maintaining the focus on the structural integrity of the final structure/component.

Tissue Integration of Two Different Shape-Memory Polymers with Poly(ε-Caprolactone) Switching Segment in Rats

2008 ◽  
Author(s):  
Bernhard Hiebl ◽  
Dorothee Rickert ◽  
Rosemarie Fuhrmann ◽  
Friedrich Jung ◽  
Andres Lendlein ◽  
...  
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymers ◽  
Tissue Integration

scholarly journals Design of Shape Memory Thermoplastic Material Systems for FDM-Type Additive Manufacturing

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4254
Author(s):  
Paulina A. Quiñonez ◽  
Leticia Ugarte-Sanchez ◽  
Diego Bermudez ◽  
Paulina Chinolla ◽  
Rhyan Dueck ◽  
...  
Keyword(s):  
Additive Manufacturing ◽  
Shape Memory ◽  
Thermomechanical Processing ◽  
Material Selection ◽  
Shape Memory Polymer ◽  
Fused Filament Fabrication ◽  
Materials Development ◽  
Thermoplastic Material ◽  
Polymer Systems ◽  
Injection Molded

The work presented here describes a paradigm for the design of materials for additive manufacturing platforms based on taking advantage of unique physical properties imparted upon the material by the fabrication process. We sought to further investigate past work with binary shape memory polymer blends, which indicated that phase texturization caused by the fused filament fabrication (FFF) process enhanced shape memory properties. In this work, two multi-constituent shape memory polymer systems were developed where the miscibility parameter was the guide in material selection. A comparison with injection molded specimens was also carried out to further investigate the ability of the FFF process to enable enhanced shape memory characteristics as compared to other manufacturing methods. It was found that blend combinations with more closely matching miscibility parameters were more apt at yielding reliable shape memory polymer systems. However, when miscibility parameters differed, a pathway towards the creation of shape memory polymer systems capable of maintaining more than one temporary shape at a time was potentially realized. Additional aspects related to impact modifying of rigid thermoplastics as well as thermomechanical processing on induced crystallinity are also explored. Overall, this work serves as another example in the advancement of additive manufacturing via materials development.

Three-dimensional Graphene Coated Shape Memory Polyurethane Foam with Fast Responsive Performance

2021 ◽  
Author(s):  
Tianjiao Wang ◽  
Jun Zhao ◽  
Chuanxin Weng ◽  
Tong Wang ◽  
Yayun Liu ◽  
...  
Keyword(s):  
Shape Memory ◽  
Polyurethane Foam ◽  
Three Dimensional ◽  
Shape Memory Polymers ◽  
Practical Applications ◽  
External Stimuli ◽  
Shape Memory Polyurethane

Shape memory polymers (SMPs) that change shapes as designed by external stimuli have become one of the most promising materials as actuators, sensors, and deployable devices. However, their practical applications...

Macroporous Superhydrophobic Coatings with Switchable Wettability Enabled by Smart Shape Memory Polymers

2021 ◽  
pp. 2002111
Author(s):  
Calen J. Leverant ◽  
Yifan Zhang ◽  
Maria A. Cordoba ◽  
Sin‐Yen Leo ◽  
Nilesh Charpota ◽  
...  
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymers ◽  
Superhydrophobic Coatings

scholarly journals Harnessing reversible dry adhesion using shape memory polymer microparticles

RSC Advances ◽  
2021 ◽  
Vol 11 (32) ◽  
pp. 19616-19622
Author(s):  
Wenbing Li ◽  
Junhao Liu ◽  
Wanting Wei ◽  
Kun Qian
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Memory Effects ◽  
Reversible Adhesion ◽  
Dry Adhesion ◽  
Bonding Property ◽  
Shape Memory Effects ◽  
Polymer Microparticles

Shape memory polymers can provide excellent bonding property because of their shape memory effects. This paper proposes an adhesive unit that is capable of repeatable smart adhesion and exhibits reversible adhesion under heating.

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