scholarly journals Design of Shape Memory Thermoplastic Material Systems for FDM-Type Additive Manufacturing

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4254
Author(s):  
Paulina A. Quiñonez ◽  
Leticia Ugarte-Sanchez ◽  
Diego Bermudez ◽  
Paulina Chinolla ◽  
Rhyan Dueck ◽  
...  
Keyword(s):  
Additive Manufacturing ◽  
Shape Memory ◽  
Thermomechanical Processing ◽  
Material Selection ◽  
Shape Memory Polymer ◽  
Fused Filament Fabrication ◽  
Materials Development ◽  
Thermoplastic Material ◽  
Polymer Systems ◽  
Injection Molded

The work presented here describes a paradigm for the design of materials for additive manufacturing platforms based on taking advantage of unique physical properties imparted upon the material by the fabrication process. We sought to further investigate past work with binary shape memory polymer blends, which indicated that phase texturization caused by the fused filament fabrication (FFF) process enhanced shape memory properties. In this work, two multi-constituent shape memory polymer systems were developed where the miscibility parameter was the guide in material selection. A comparison with injection molded specimens was also carried out to further investigate the ability of the FFF process to enable enhanced shape memory characteristics as compared to other manufacturing methods. It was found that blend combinations with more closely matching miscibility parameters were more apt at yielding reliable shape memory polymer systems. However, when miscibility parameters differed, a pathway towards the creation of shape memory polymer systems capable of maintaining more than one temporary shape at a time was potentially realized. Additional aspects related to impact modifying of rigid thermoplastics as well as thermomechanical processing on induced crystallinity are also explored. Overall, this work serves as another example in the advancement of additive manufacturing via materials development.

scholarly journals AM-FFF of Objects Using Commercial PLA Based Shape Memory Polymer Printed by an Open-Source 3D Printer

2020 ◽  
Vol 31 ◽  
pp. 30-34
Author(s):  
N. Dresler ◽  
A. Ulanov ◽  
M. Aviv ◽  
D. Ashkenazi ◽  
A. Stern
Keyword(s):  
Additive Manufacturing ◽  
3D Printing ◽  
Shape Memory ◽  
Open Source ◽  
Shape Memory Polymer ◽  
Manufacturing Processes ◽  
3D Printer ◽  
4D Printing ◽  
Fused Filament Fabrication ◽  
Memory Cycle

The 4D additive manufacturing processes are considered today as the "next big thing" in R&D. The aim of this research is to provide two examples of commercial PLA based shape memory polymer (SMP) objects printed on an open-source 3D printer in order to proof the feasibility of such novel 4D printing process. To that purpose, a PLA based filament of eSUN (4D filament e4D-1white, SMP) was chosen, and two applications, a spring and a vase, were designed by 3D-printing with additive manufacturing (AM) fused filament fabrication (FFF) technique. The 4D-printed objects were successfully produced, the shape memory effect and their functionality were demonstrated by achieving the shape-memory cycle of programming, storage and recovery.

scholarly journals Fused Filament Fabrication-4D-Printed Shape Memory Polymers: A Review

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 701
Author(s):  
Sara Valvez ◽  
Paulo N. B. Reis ◽  
Luca Susmel ◽  
Filippo Berto
Keyword(s):  
Mechanical Properties ◽  
Additive Manufacturing ◽  
Shape Memory ◽  
Structural Integrity ◽  
Shape Memory Polymer ◽  
Shape Memory Polymers ◽  
Layer By Layer ◽  
4D Printing ◽  
Fused Filament Fabrication ◽  
External Stimuli

Additive manufacturing (AM) is the process through which components/structures are produced layer-by-layer. In this context, 4D printing combines 3D printing with time so that this combination results in additively manufactured components that respond to external stimuli and, consequently, change their shape/volume or modify their mechanical properties. Therefore, 4D printing uses shape-memory materials that react to external stimuli such as pH, humidity, and temperature. Among the possible materials with shape memory effect (SME), the most suitable for additive manufacturing are shape memory polymers (SMPs). However, due to their weaknesses, shape memory polymer compounds (SMPCs) prove to be an effective alternative. On the other hand, out of all the additive manufacturing techniques, the most widely used is fused filament fabrication (FFF). In this context, the present paper aims to critically review all studies related to the mechanical properties of 4D-FFF materials. The paper provides an update state of the art showing the potential of 4D-FFF printing for different engineering applications, maintaining the focus on the structural integrity of the final structure/component.

Physical Microfabrication of Shape-Memory Polymer Systems via Bicomponent Fiber Spinning

2016 ◽  
Vol 37 (22) ◽  
pp. 1837-1843 ◽  
Author(s):  
Syamal S. Tallury ◽  
Behnam Pourdeyhimi ◽  
Melissa A. Pasquinelli ◽  
Richard J. Spontak
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer ◽  
Fiber Spinning ◽  
Polymer Systems ◽  
Bicomponent Fiber

Additive Manufacturing of Shape Memory Polymer Composites for Futuristic Technology

2021 ◽  
Author(s):  
Jigar Patadiya ◽  
Adwait Gawande ◽  
Ganapati Joshi ◽  
Balasubramanian Kandasubramanian
Keyword(s):  
Additive Manufacturing ◽  
Shape Memory ◽  
Polymer Composites ◽  
Shape Memory Polymer

scholarly journals In Search of the Optimal Conditions to Process Shape Memory Alloys (NiTi) Using Fused Filament Fabrication (FFF)

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4718
Author(s):  
Pedro Carreira ◽  
Fábio Cerejo ◽  
Nuno Alves ◽  
Maria Teresa Vieira
Keyword(s):  
Additive Manufacturing ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
Sintering Temperature ◽  
Production Costs ◽  
Layer By Layer ◽  
Secondary Phases ◽  
Fused Filament Fabrication ◽  
Near Net Shape ◽  
Niti Shape Memory Alloys

This research was performed so as to investigate the additive manufacturing of NiTi shape memory alloys, which is associated with direct processes, such as selective laser melting. In addition to its expensive production costs, NiTi readily undergoes chemical and phase modifications, mainly as a result of Ni loss during processing as a result of high temperatures. This research explores the potential usefulness of NiTi as well as its limitations using indirect additive processes, such as fused filament fabrication (FFF). The first step was to evaluate the NiTi critical powder volume content (CPVC) needed to process high-quality filaments (via extrusion). A typical 3D printer can build a selected part/system/device layer-by-layer from the filaments, followed by debinding and sintering (SDS), in order to generate a near-net-shape object. The mixing, extruding (filament), printing (shaping), debinding, and sintering steps were extensively studied in order to optimize their parameters. Moreover, for the sintering step, two main targets should be met, namely: the reduction of contamination during the process in order to avoid the formation of secondary phases, and the decrease in sintering temperature, which also contributes to reducing the production costs. This study aims to demonstrate the possibility of using FFF as an additive manufacturing technology for processing NiTi.

scholarly journals Development of siloxane-based amphiphiles as cell stabilizers for porous shape memory polymer systems

2016 ◽  
Vol 478 ◽  
pp. 334-343 ◽  
Author(s):  
Sayyeda M. Hasan ◽  
Alexandra D. Easley ◽  
Mary Beth Browning Monroe ◽  
Duncan J. Maitland
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer ◽  
Polymer Systems

Mechanical Behavior of a Shape Memory Polymer

2006 ◽  
Author(s):  
Xin Wu ◽  
Leonard Dauerman ◽  
Song Zhang ◽  
Xiao Qiao ◽  
Jose Mabesa
Keyword(s):  
Shape Memory ◽  
Shape Memory Polymer ◽  
Isothermal Holding ◽  
Strain Recovery ◽  
Control Mode ◽  
Plastic Behavior ◽  
Polymer Systems ◽  
Potential Applications ◽  
Number Of Cycles ◽  
Holding Temperature

In recent years shape memory effect in polymer systems has drawn great attention for its potential applications for MEMS and medical devices. In this paper, the visco-elastic and plastic behavior and strain recovery characteristics of a thermoplastic have been studied extensively. Creep deformation by compression was performed under load or displacement control mode, and under monotonic or cyclic loading. The strain recovery ratio of the shape memory polymer is found to be strongly affected by the deformation temperature, isothermal holding temperature and time, amount of forward strain and relaxation time, and the number of cycles of strain/recovery. The creep behavior of the material is modeled.

Additive manufacturing of shape memory polymers: effects of print orientation and infill percentage on mechanical properties

2018 ◽  
Vol 24 (4) ◽  
pp. 744-751 ◽  
Author(s):  
Jorge Villacres ◽  
David Nobes ◽  
Cagri Ayranci
Keyword(s):  
Mechanical Properties ◽  
Additive Manufacturing ◽  
Shape Memory ◽  
Fused Deposition Modeling ◽  
Shape Memory Polymer ◽  
Longitudinal Axis ◽  
Layer By Layer ◽  
Content Type ◽  
Material Extrusion ◽  
Fused Deposition

Purpose Material extrusion additive manufacturing, also known as fused deposition modeling, is a manufacturing technique in which objects are built by depositing molten materials layer-by-layer through a nozzle. The use and application of this technique has risen dramatically over the past decade. This paper aims to first, report on the production and characterization of a shape memory polymer material filament that was manufactured to print shape memory polymer objects using material extrusion additive manufacturing. Additionally, it aims to investigate and outline the effects of major printing parameters, such as print orientation and infill percentage, on the elastic and mechanical properties of printed shape memory polymer samples. Design/methodology/approach Infill percentage was tested at three levels, 50, 75 and 100 per cent, while print orientation was tested at four different angles with respect to the longitudinal axis of the specimens at 0°, 30°, 60° and 90°. The properties examined were elastic modulus, ultimate tensile strength and maximum strain. Findings Results showed that print angle and infill percentage do have a significant impact on the manufactured test samples. Originality/value Findings can significantly influence the tailored design and manufacturing of smart structures using shape memory polymer and material extrusion additive manufacturing.

scholarly journals Additive Manufacturing of Information Carriers Based on Shape Memory Polyester Urethane

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1005 ◽  
Author(s):  
Dilip Chalissery ◽  
Thorsten Pretsch ◽  
Sarah Staub ◽  
Heiko Andrä
Keyword(s):  
Additive Manufacturing ◽  
Shape Memory ◽  
Shape Memory Polymers ◽  
Qr Code ◽  
Stimuli Responsive ◽  
Fused Filament Fabrication ◽  
Responsive Materials ◽  
Manufacturing Method ◽  
Polyester Urethane ◽  
Machine Readable

Shape memory polymers (SMPs) are stimuli-responsive materials, which are able to retain an imposed, temporary shape and recover the initial, permanent shape through an external stimulus like heat. In this work, a novel manufacturing method is introduced for thermoresponsive quick response (QR) code carriers, which originally were developed as anticounterfeiting technology. Motivated by the fact that earlier manufacturing processes were sometimes too time-consuming for production, filaments of a polyester urethane (PEU) with and without dye were extruded and processed into QR code carriers using fused filament fabrication (FFF). Once programmed, the distinct shape memory properties enabled a heating-initiated switching from non-decodable to machine-readable QR codes. The results demonstrate that FFF constitutes a promising additive manufacturing technology to create complex, filigree structures with adjustable horizontal and vertical print resolution and, thus, an excellent basis to realize further technically demanding application concepts for shape memory polymers.

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