Similarity analysis of stacking sequences in a SiC nanowire pair grown from the same catalyst nanoparticle using Levenshtein distance

Microscopy ◽  
2020 ◽  
Vol 69 (4) ◽  
pp. 234-239
Author(s):  
Takayuki Kataoka ◽  
Takumi Noguchi ◽  
Hideo Kohno

Abstract Stacking faults are easily formed in silicon carbide (SiC) crystals, and this is also the case for SiC nanowires. The stacking faults exercise influences on SiC’s properties, therefore it is important to understand their formation mechanism and to control their formation for applications of SiC and its nanowires. In this study, we propose a method for investigating stacking faults’ formation mechanism in nanowires and provide its proof of concept. Stacking sequences in a pair of SiC nanowires that were grown from the same metal catalyst nanoparticle were quantified as a pair of binary sequences, and Levenshtein distances between partial sequences extracted from the two sequences were measured to detect similarity between them, and the result was compared with that obtained using a surrogate data of one sequence. The similarity analysis using Levenshtein distances works as a probe for investigating possible influences of some phenomena in the catalyst nanoparticle on the formation of stacking faults. The analysis did not detect a correlation between the two sequences. Although a possibility that the formation of stacking faults in the nanowires were owing to some phenomena in the catalyst nanoparticle cannot be denied, the extrinsic cause in the catalyst nanoparticle was not detected through our analysis in this case.

2007 ◽  
Vol 7 (2) ◽  
pp. 580-583 ◽  
Author(s):  
K. F. Cai ◽  
Q. Lei ◽  
A. X. Zhang

SiC nanowires are prepared by pyrolysis of hexamethyldisilane (HMDS), at 1200 °C in a flowing Ar atmosphere. The length of the nanowires is in millimeter scale. Transmission electron microscopy observations indicate that the diameters of the SiC nanowires are in the range of about 8 to 120 nm, and that most of the nanowires have numerous stacking faults. The formation mechanism of the nanowires is proposed.


2013 ◽  
Vol 740-742 ◽  
pp. 209-212 ◽  
Author(s):  
Rooban Venkatesh K.G. Thirumalai ◽  
Bharat Krishnan ◽  
Albert Davydov ◽  
Joseph Neil Merrett ◽  
Yaroslav Koshka

A method was developed for growing SiC nanowires without depositing a metal catalyst on the targeted surfaces prior to the CVD growth. The proposed method utilizes in-situ vapor-phase catalyst delivery via sublimation of the catalyst from a metal source placed in the hot zone of the CVD reactor, followed by condensation of the catalyst-rich vapor on the bare substrate surface to form the catalyst nanoparticles. The vapor-phase catalyst delivery and the resulting nanowire density was found to be influenced by both the gas flow rate and the catalyst diffusion through the boundary layer above the catalyst source. The origin of undesirable bushes of nanowires and the role of the C/Si ratio were established.


2008 ◽  
Vol 8 (7) ◽  
pp. 3504-3510 ◽  
Author(s):  
K. L. Wallis ◽  
M. Wieligor ◽  
T. W. Zerda ◽  
S. Stelmakh ◽  
S. Gierlotka ◽  
...  

SiC nanowires were obtained by a reaction between vapor silicon and multiwall carbon nanotubes, CNT, in vacuum at 1200 °C. Raman and IR spectrometry, X-ray diffraction and high resolution transmission electron microscopy, HRTEM, were used to characterize properties of SiC nanowires. Morphology and chemical composition of the nanowires was similar for all samples, but concentration of structural defects varied and depended on the origin of CNT. Stacking faults were characterized by HRTEM and Raman spectroscopy, and both techniques provided complementary results. Raman microscopy allowed studying structural defects inside individual nanowires. A thin layer of amorphous silicon carbide was detected on the surface of nanowires.


RSC Advances ◽  
2014 ◽  
Vol 4 (35) ◽  
pp. 18360-18364 ◽  
Author(s):  
Zhaohui Huang ◽  
Haitao Liu ◽  
Kai Chen ◽  
Minghao Fang ◽  
Juntong Huang ◽  
...  

Twinned SiC nanowires were prepared on a silicon wafer by a simple catalyst-free thermal chemical vapour deposition (CVD) method.


2014 ◽  
Vol 12 (0) ◽  
pp. 145-148 ◽  
Author(s):  
Masato Morita ◽  
Masanobu Karasawa ◽  
Takahiro Asaka ◽  
Masanori Owari

2018 ◽  
Vol 768 ◽  
pp. 179-186
Author(s):  
Peng Fei Zhang ◽  
Bin Yang ◽  
Zhi Lu ◽  
Guang Xin Wang

The mechanically-alloyed amorphous 2SiB3CN powder was used as the precursor for the preparation of SiC nanowires in the current work. Annealed at 1700 °C in argon for 2 hrs, the composite powder was covered by a large amount of grey-green SiC nanowires. SEM, TEM and XRD results reveal that the nanowires are 200 to 1000 nanometers in diameter and hundreds of micrometers in length. Bamboo-shaped and nodular-like β-SiC nanowire accounts for the major part of the products. The bamboo-shaped nanowires have perfect periodicity and periodically distributed stacking faults. Further research indicates that traces of iron in raw powders acts as catalyst, promoting the V-L-S process of the nanowire growth. Current route provides a new method for the large-scale preparation of the periodically structured SiC nanowires, which may find applications in nano sensors, optoelectronic devices, etc.


CrystEngComm ◽  
2020 ◽  
Vol 22 (24) ◽  
pp. 4074-4078 ◽  
Author(s):  
Zhihui Hu ◽  
Zhi Chen ◽  
Juntong Huang ◽  
Mingge Yan ◽  
Meng Zhang ◽  
...  

3C-SiC nanowires with nanosheets were synthesized via a direct reaction of Si vapor (from solid silicon) and SiO vapor (from silicon and silicon dioxide) with graphene nanosheets at 1500 °C without any additional metal catalyst.


1976 ◽  
Vol 10 (12) ◽  
pp. 1081-1085 ◽  
Author(s):  
H-r Pak ◽  
T Saburi ◽  
S Nenno

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