The Invasion of the Periodic Table by Physics
Although John Dalton had reintroduced the notion of atoms to science, many debates followed among chemists, most of whom refused to accept that atoms existed literally. One of these skeptical chemists was Mendeleev, but as we saw in the previous chapter this does not seem to have prevented him from publishing the most successful periodic system of all those proposed at the time. Following the work of physicists like Einstein and Perrin, the atom’s reality became more and more firmly established starting at the turn of the twentieth century. Einstein’s 1905 paper on Brownian motion, using statistical methods, provided conclusive theoretical justification for the existence of atoms but lacked experimental support. The latter was soon provided by the French experimental physicist Jean Perrin. This work led in turn to many lines of research aimed at exploring the structure of the atom, and many developments that were to have a big influence on attempts to understand the periodic system theoretically. In this chapter we consider some of this atomic research as well as several other key discoveries in twentieth-century physics that contributed to what might be called the invasion of the periodic table by physics. The discovery of the electron, the first hint that the atom had a substructure, came in 1897 at the hands of the legendary J. J. Thomson, working at the Cavendish laboratory in Cambridge. A little earlier, in 1895, Wilhelm Conrad Röntgen had discovered X-rays in Würzburg, Germany. These new rays would soon be put to very good use by Henry Moseley, a young physicist working first in Manchester and, for the remainder of his short scientific life, in Oxford. Just a year after Röntgen had described his X-rays, Henri Becquerel in Paris discovered the enormously important phenomenon of radioactivity, whereby certain atoms break up spontaneously while emitting a number of different, new kinds of rays. The term “radioactivity” was actually coined by the Polish-born Marie Slodowska (later Curie).