scholarly journals Enhanced light-harvesting by plasmonic hollow gold nanospheres for photovoltaic performance

2018 ◽  
Vol 5 (1) ◽  
pp. 171350 ◽  
Author(s):  
Hao Ding ◽  
Jindian Lv ◽  
Huaping Wu ◽  
Guozhong Chai ◽  
Aiping Liu

A ‘sandwich'-structured TiO 2 NR/HGN/CdS photoanode was successfully fabricated by the electrophoretic deposition of hollow gold nanospheres (HGNs) on the surface of TiO 2 nanorods (NRs). The HGNs presented a wide surface plasmon resonance character in the visible region from 540 to 630 nm, and further acted as the scatter elements and light energy ‘antennas' to trap the local-field light near the TiO 2 NR/CdS layer, resulting in the increase of the light harvesting. An outstanding enhancement in the photochemical behaviour of TiO 2 NR/HGN/CdS photoanodes was attained by the contribution of HGNs in increasing the light absorption and the number of electron-hole pairs of photosensitive semiconductors. The optimized photochemical performance of TiO 2 NR/HGN/CdS photoanodes by using plasmonic HGNs demonstrated their potential application in energy conversion devices.

2019 ◽  
Vol 55 (78) ◽  
pp. 11754-11757 ◽  
Author(s):  
Lang Pei ◽  
Taozhu Li ◽  
Yongjun Yuan ◽  
Tao Yang ◽  
Jiasong Zhong ◽  
...  

The localized surface plasmon resonance and Schottky junction in the TaON@Ni hybrid photocatalyst improve the light harvesting and promote the electron–hole separation and transport of TaON.


Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2206
Author(s):  
Gaoqian Yuan ◽  
Gen Zhang ◽  
Kezhuo Li ◽  
Faliang Li ◽  
Yunbo Cao ◽  
...  

Loading a noble metal on Bi4Ti3O12 could enable the formation of the Schottky barrier at the interface between the former and the latter, which causes electrons to be trapped and inhibits the recombination of photoelectrons and photoholes. In this paper, AgPt/Bi4Ti3O12 composite photocatalysts were prepared using the photoreduction method, and the effects of the type and content of noble metal on the photocatalytic performance of the catalysts were investigated. The photocatalytic degradation of rhodamine B (RhB) showed that the loading of AgPt bimetallic nanoparticles significantly improved the catalytic performance of Bi4Ti3O12. When 0.10 wt% noble metal was loaded, the degradation rate for RhB of Ag0.7Pt0.3/Bi4Ti3O12 was 0.027 min−1, which was respectively about 2, 1.7 and 3.7 times as that of Ag/Bi4Ti3O12, Pt/Bi3Ti4O12 and Bi4Ti3O12. The reasons may be attributed as follows: (i) the utilization of visible light was enhanced due to the surface plasmon resonance effect of Ag and Pt in the visible region; (ii) Ag nanoparticles mainly acted as electron acceptors to restrain the recombination of photogenerated electron-hole pairs under visible light irradiation; and (iii) Pt nanoparticles acted as electron cocatalysts to further suppress the recombination of photogenerated electron-hole pairs. The photocatalytic performance of Ag0.7Pt0.3/Bi4Ti3O12 was superior to that of Ag/Bi4Ti3O12 and Pt/Bi3Ti4O12 owing to the synergistic effect between Ag and Pt nanoparticles.


2012 ◽  
Vol 22 (1) ◽  
pp. 130-139 ◽  
Author(s):  
Jen-Fu Yin ◽  
Jian-Ging Chen ◽  
Jiann-T'suen Lin ◽  
Dibyendu Bhattacharya ◽  
Ying-Chan Hsu ◽  
...  

Radiology ◽  
2016 ◽  
Vol 281 (2) ◽  
pp. 427-435 ◽  
Author(s):  
Junjie Li ◽  
Min Zhou ◽  
Fengyong Liu ◽  
Chiyi Xiong ◽  
Wanqin Wang ◽  
...  

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