Fine-structure-changing collision cross sections within the low-lyingnD2states of rubidium induced by ground-state rubidium atoms

1984 ◽  
Vol 29 (2) ◽  
pp. 617-624 ◽  
Author(s):  
J. W. Parker ◽  
H. A. Schuessler ◽  
R. H. Hill ◽  
B. G. Zollars
Keyword(s):  
Fine Structure ◽  
Cross Sections ◽  
Ground State ◽  
Rubidium Atoms ◽  
Collision Cross Sections

Inelastic Collisions between Excited Alkali Atoms and Molecules. VIII. 62P1/2–62P3/2 Mixing and Quenching in Mixtures of Rubidium with H2, HD, D2, N2, CH4, and CD4

1973 ◽  
Vol 51 (3) ◽  
pp. 257-265 ◽  
Author(s):  
I. N. Siara ◽  
L. Krause
Keyword(s):  
Fine Structure ◽  
Cross Sections ◽  
Ground State ◽  
Inelastic Collisions ◽  
Fluorescent Intensity ◽  
Rubidium Vapor ◽  
Sensitized Fluorescence ◽  
Molecular Gases ◽  
Alkali Atoms ◽  
Intensity Ratios

Excitation transfer between the 62P fine-structure substates in rubidium, induced in inelastic collisions with ground-state molecules, has been studied using techniques of sensitized fluorescence. Rubidium vapor in mixtures with various molecular gases was irradiated with each component of the 2P rubidium doublet in turn, and measurements of sensitized-to-resonance fluorescent intensity ratios yielded the following mixing cross sections Q12(2P1/2 → 2P3/2) and Q21(2P1/2 ← 2P3/2), as well as effective quenching cross sections Q1X(2P1/2 → 2XJ″) and Q2X(2P3/2 → 2XJ″). For collisions with H2: Q12(2P1/2 → 2P3/2) = (41 ± 5) Å2; Q21(2P1/2 ← 2P3/2) = (26 ± 3) Å2; Q1X(2P1/2 → 2XJ″) = (36 ± 9) Å2; Q2X(2P3/2 → 2XJ″) = (31 ± 8) Å2. For HD: Q12 = (42 ± 5) Å2; Q21 = (27 ± 4) Å2; Q1X = (47 ± 13) Å2; Q2X = (38 ± 10) Å2. For D2: Q12 = (42 ± 5) Å2; Q21 = (27 ± 4) Å2; Q1X = (28 ± 8) Å2; Q2X = (21 ± 7) Å2. For N2: Q12 = (107 ± 15) Å2; Q21 = (70 ± 10) Å2; Q1X = (128 ± 44) Å2; Q2X = (126 ± 33) Å2. For CH4: Q12 = (38 ± 6) Å2; Q21 = (24 ± 3) Å2; Q1X = (129 ± 41) Å2; Q2X = (114 ± 37) Å2. For CD4: Q12 = (52 ± 7) Å2; Q21 = (34 ± 5) Å2; Q1X = (82 ± 30) Å2; Q2X = (76 ± 22) Å2. An analysis of these results suggests the possibility of resonances with various molecular rotational and vibrational transitions.

Photoneutron cross sections in 7Li

1977 ◽  
Vol 55 (5) ◽  
pp. 428-433 ◽  
Author(s):  
H. Ferdinande ◽  
N. K. Sherman ◽  
K. H. Lokan ◽  
C. K. Ross
Keyword(s):  
Fine Structure ◽  
Excited State ◽  
Cross Section ◽  
Cross Sections ◽  
Ground State ◽  
Reasonable Agreement ◽  
Branching Ratio ◽  
Energy Spectra ◽  
Average Value ◽  
First Excited State

Photoneutron energy spectra from 7Li have been measured by time-of-flight methods, for bremsstrahlung end-point energies increasing in 2 MeV steps from 13 to 25 MeV. The ground-state and approximate first-excited-state differential cross sections at 90° have been obtained from 8.5 to 23 MeV. No pronounced fine structure has been observed. The measured branching ratio to the first excited state falls from an average value of 0.70 between 10.3 and 14.5 MeV to an average of 0.29 between 14.5 and 18 MeV, and rises again to an average of 0.38 between 18 and 23 MeV. This behaviour can be explained by a crude theoretical model in which 1p → 2s and 1p → 1d single particle transitions dominate below 18 MeV. The calculation predicts a branching ratio of 0.50 near threshold, falling to 0.23 at higher energies, in reasonable agreement with the experiment. The integrated value of the ground-state cross section up to 23 MeV is about (38.7 ± 3.9) MeV mb, while that for the first excited state is about (17.2 ± 3.4) MeV mb. Together they account for 39% of the exchange-augmented dipole sum of 7Li.

Transfer of Electronic Excitation between the 62P3/2 and 62P1/2 States of Rubidium Induced by Collisions with Rubidium Atoms

1974 ◽  
Vol 52 (17) ◽  
pp. 1635-1640 ◽  
Author(s):  
Paul W. Pace ◽  
J. B. Atkinson
Keyword(s):  
Fine Structure ◽  
Cross Sections ◽  
Electronic Excitation ◽  
Empirical Relationship ◽  
Optical Excitation ◽  
Nitrogen Laser ◽  
Rubidium Vapor ◽  
Rubidium Atoms ◽  
Structure Splitting ◽  
The Cross

The cross sections for excitation transfer between the 62P fine structure levels of rubidium, induced in collisions with ground state rubidium atoms, have been measured using a nitrogen laser pumped dye laser as the optical excitation source in a fluorescence experiment. Rubidium vapor was irradiated with each component of the 2P rubidium doublet in turn, and measurements of the relative intensities of fluorescence yielded the following cross sections: [Formula: see text] These results are consistent with the empirical relationship between the magnitude of the cross sections and the fine structure splitting that has previously been established for the alkalis.

Investigation of Fine Structure in the Photoneutron Cross Sections of 16O and 208Pb

1975 ◽  
Vol 53 (15) ◽  
pp. 1434-1442 ◽  
Author(s):  
R. G. Johnson ◽  
J. D. Irish ◽  
K. G. McNeill
Keyword(s):  
Fine Structure ◽  
High Resolution ◽  
Differential Cross Section ◽  
Cross Section ◽  
Cross Sections ◽  
Ground State ◽  
Center Of Mass ◽  
Energy Spectra ◽  
Neutron Time ◽  
Good Agreement

The structure in the photoneutron cross sections of 16O and 208Pb has been studied by the measurement of high resolution photoneutron energy spectra using the neutron time-of-flight technique and bremsstrahlung irradiations. For 16O, the ground state differential cross section at 98° has been deduced between 17.3 and 28.5 MeV and is in good agreement with most previous studies. Fine structure is seen throughout the cross section. Eight neutron energy spectra for 208Pb from bremsstrahlung endpoint energies in the range 11.0 to 15.5 MeV were obtained. Strong peaks are seen at center of mass neutron energies of 1.67, 1.85, 2.06, 2.19, 2.68, 3.15, 3.27, 3.50, 3.77, and 4.03 MeV with weaker peaks elsewhere. The energies of these peaks are in good agreement with previous measurements in this laboratory. The energies of peaks in the spectra are compared with recent cross section measurements.

Sensitized fluorescence in vapors of alkali metals. XII. 42P1/2–42P3/2 mixing in potassium, induced in collisions with ground-state rubidium atoms

1969 ◽  
Vol 47 (2) ◽  
pp. 223-226 ◽  
Author(s):  
E. S. Hrycyshyn ◽  
L. Krause
Keyword(s):  
Cross Sections ◽  
Ground State ◽  
Alkali Metals ◽  
Resonance Radiation ◽  
Total Cross Sections ◽  
Sensitized Fluorescence ◽  
Rubidium Atoms ◽  
Partial Pressures ◽  
Potassium Vapor ◽  
Detailed Balancing

The total cross sections for collisions between excited potassium and unexcited rubidium atoms, leading to the transfer of excitation between the 42P states in potassium, have been determined in a sensitized fluorescence experiment. The experiments were carried out at partial pressures of potassium vapor lower than 10−5 mm Hg, at which the imprisonment of resonance radiation may be disregarded. The cross sections Q12″ (42P1/2 → 42P3/2) and Q21″ (42P1/2 ← 42P3/2) equal 260 Å2 and 175 Å2, respectively, and are in the ratio predicted by the principle of detailed balancing.

scholarly journals Spin Effects in the (e, 2e) Cross Section of Xenon

1996 ◽  
Vol 49 (2) ◽  
pp. 383 ◽  
Author(s):  
B Granitza ◽  
X Guo ◽  
JM Hum ◽  
J Lower ◽  
S Mazevet ◽  
...  
Keyword(s):  
Electron Beam ◽  
Fine Structure ◽  
Electron Impact ◽  
Cross Section ◽  
Cross Sections ◽  
Ground State ◽  
Closed Shell ◽  
Spin Effects ◽  
Incident Electron Beam ◽  
Series Of Experiments

In a series of experiments investigating the spin-dependent aspects of electron impact induced ionisation of atoms with a spin-resolved incident electron beam we have measured spin-resolved (e, 2e) cross sections for xenon. By experimentally resolving the fine structure levels of the ground state residual ion the existence of an effect analogous to the fine structure effect in excitation has been established, whereby strong and opposite polarisation effects are observed in the ionisation of a spinless closed shell target leading to a fine structure doublet.

82D3/2 ↔ 82D5/2 excitation transfer in rubidium induced in collisions with ground-state Rb atoms

1981 ◽  
Vol 59 (4) ◽  
pp. 548-554 ◽  
Author(s):  
M. Głódz ◽  
J. B. Atkinson ◽  
L. Krause
Keyword(s):  
Fine Structure ◽  
Cross Sections ◽  
Ground State ◽  
Photon Counting ◽  
Excitation Transfer ◽  
Atomic Fluorescence ◽  
Rubidium Vapor ◽  
Two Photon ◽  
Photon Excitation ◽  
Structure State

Cross sections for inelastic transfer between the 82D3/2 and 82D5/2 fine-structure states in rubidium, induced in resonant collisions with ground-state Rb atoms, have been determined using an experimental method involving two-photon excitation of atomic fluorescence. Rubidium vapor in a fluorescence cell was irradiated with pulses of 641 nm radiation from a N2 laser-pumped dye-laser tuned to excite one of the 82D states. The resulting fluorescence included the direct component originating from the optically excited state and a sensitized component arising from the other fine-structure state populated by collisions. Relative intensities of the fluorescent components, determined by photon-counting techniques, yielded the cross sections for excitation transfer: Q(2D3/2 → 2D5/2) = 8.1 × 10−13 cm2; Q(2D3/2 ← 2D5/2) = 5.5 × 1013 cm2; as well as [Formula: see text], the effective quenching cross section. The excitation transfer cross sections which are considered accurate to within ±20% are in the ratio predicted by the principle of detailed balancing.

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