scholarly journals Quasi-one-dimensional magnetic properties of NiNb2−xVxO6 compounds synthesized at high pressure in a nonstandard columbite-type structure

2021 ◽  
Vol 103 (9) ◽  
Author(s):  
J. Peña ◽  
M. A. Gusmão ◽  
O. Isnard
2010 ◽  
Vol 470 ◽  
pp. S742-S743 ◽  
Author(s):  
Ichihiro Yamauchi ◽  
Taisuke Suzuki ◽  
Yasuhiro Shimizu ◽  
Masayuki Itoh ◽  
Nao Takeshita ◽  
...  

1997 ◽  
Vol 499 ◽  
Author(s):  
H. Takizawa ◽  
K. Uheda ◽  
T. Endo ◽  
M. Shimada

ABSTRACTA new high-pressure polymorph of CrSb2 was synthesized under high-pressure/ temperature conditions of 7–7.7 GPa and 600–650°C. The crystal structure is body-centered tetragonal with the space group 14/mcm, which is assigned to CuAl2-type structure. The experiments under various pressure conditions revealed that the high-pressure polymorph was formed above 5.5 GPa, and the compound crystallized into the low-pressure marcasite-type structure below 5 GPa. The characteristic of the high-pressure phase is the metallic bond nature including the formation of Cr-Cr-Cr linear chain along the c-axis. The compound shows metallic conductivity and itinerant-electron ferromagnetic behavior with the Curie temperature of ca. 160 K.


2000 ◽  
Vol 62 (17) ◽  
pp. 11581-11584 ◽  
Author(s):  
C. Sekine ◽  
T. Uchiumi ◽  
I. Shirotani ◽  
K. Matsuhira ◽  
T. Sakakibara ◽  
...  

2005 ◽  
Vol 61 (3) ◽  
pp. 246-249 ◽  
Author(s):  
K. G. Bramnik ◽  
H. Ehrenberg ◽  
S. Buhre ◽  
H. Fuess

The ternary oxide MnReO4, manganese rhenium oxide, has been synthesized under a high pressure of 5.5 GPa at 1473 K and its crystal structure has been determined by single-crystal X-ray diffraction. MnReO4 crystallizes in a wolframite-type structure with average bond lengths of 〈Re—O〉 = 1.935 and 〈Mn—O〉 = 2.160 Å that are in good agreement with the ionic radii of Re6+ and Mn2+. The magnetic properties of MnReO4 have been studied by SQUID measurements, revealing magnetic ordering below 275 (10) K and a weak ferromagnetic component of the ordered magnetic structure.


Author(s):  
Gunter Heymann ◽  
Elisabeth Selb ◽  
Toni Buttlar ◽  
Oliver Janka ◽  
Martina Tribus ◽  
...  

By high-pressure/high-temperature multianvil synthesis a new high-pressure (HP) phase of Co3TeO6 was obtained. The compound crystallizes in the acentric trigonal crystal system of the Ni3TeO6-type structure with space group R3...


Author(s):  
Mario Falsaperna ◽  
Gavin B G Stenning ◽  
Ivan da Silva ◽  
Paul James Saines

This study probes the structure and the magnetic properties of members of the Ln(HCO2)(C2O4) (Ln = Sm3+-Er3+) family of coordination frameworks. These frameworks adopt a Pnma orthorhombic structure with one-dimensional...


Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 378
Author(s):  
Li Zhao ◽  
Zhiwei Hu ◽  
Hanjie Guo ◽  
Christoph Geibel ◽  
Hong-Ji Lin ◽  
...  

We report on the synthesis and physical properties of cm-sized CoGeO3 single crystals grown in a high pressure mirror furnace at pressures of 80 bar. Direction dependent magnetic susceptibility measurements on our single crystals reveal highly anisotropic magnetic properties that we attribute to the impact of strong single ion anisotropy appearing in this system with TN∼33.5 K. Furthermore, we observe effective magnetic moments that are exceeding the spin only values of the Co ions, which reveals the presence of sizable orbital moments in CoGeO3.


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