Direct experimental determination of the K2pand Cl2pcore-level binding energy shifts between molecular and solid KCl: Line broadening effects

2012 ◽  
Vol 85 (12) ◽  
Author(s):  
M. Patanen ◽  
G. M. Bancroft ◽  
S. Aksela ◽  
H. Aksela
1994 ◽  
Vol 9 (3) ◽  
pp. 180-186 ◽  
Author(s):  
P. Scardi ◽  
L. Lutterotti ◽  
P. Maistrelli

A simple procedure was devised for the preparation of a standard KCl powder to be used for the experimental determination of the instrumental profile in the Bragg–Brentano geometry. The standard was tested on several diffractometers, and narrow Bragg reflections in the range 28°–132° were recorded adopting various experimental conditions. Profiles were modeled with analytical functions, to describe the trend of width and shape of the instrumental profile as a function of the diffraction angle. Some indications were given to perform reliable profile fitting and line broadening analysis; a high resolution setup, obtained by employing narrow slits, large goniometer radius, and a monochromator in the diffracted beam, gives narrow reflections, even though the intensity of the diffracted beam is considerably reduced. The choice of these experimental conditions, which can be achieved using the majority of the commercial instruments, leads to symmetrical profiles, even at relatively low angle (2Θ=28°), which are highly recommended for reliable profile fitting and line broadening analysis.


2016 ◽  
Vol 477 ◽  
pp. 292-297 ◽  
Author(s):  
M. Zibrov ◽  
S. Ryabtsev ◽  
Yu. Gasparyan ◽  
A. Pisarev

2010 ◽  
Vol 12 (6) ◽  
pp. 063003 ◽  
Author(s):  
S Aksela ◽  
M Patanen ◽  
S Urpelainen ◽  
H Aksela

2013 ◽  
Vol 750-752 ◽  
pp. 1860-1863 ◽  
Author(s):  
Ivana Turekova ◽  
Zuzana Szabova ◽  
Ivana Kasalova ◽  
Tomáš Chrebet

Activation energy is the minimum energy that must have molecules that on their mutual collision has occurred chemical reaction. Activation energy can be calculated by quantum-mechanical relations for the binding energy, or the experimentally determined from the temperature dependence of the rate constant. Paper deals with the calculation of the activation energy using the results of experimental determination of ignition temperatures of food dust.


1999 ◽  
Vol 96 (6) ◽  
pp. 1111-1116 ◽  
Author(s):  
E. Falcon ◽  
S. Fauve ◽  
C. Laroche

Sign in / Sign up

Export Citation Format

Share Document