scholarly journals Mean-field description of ionic size effects with nonuniform ionic sizes: A numerical approach

2011 ◽  
Vol 84 (2) ◽  
Author(s):  
Shenggao Zhou ◽  
Zhongming Wang ◽  
Bo Li
Author(s):  
Jun-Sik Sin

In this paper, we investigate the consequences of ion association, coupled with the considerations of finite size effects and orientational ordering of Bjerrum pairs as well as ions and water...


2017 ◽  
Vol 22 (1) ◽  
pp. 95-111 ◽  
Author(s):  
Pei Liu ◽  
Manman Ma ◽  
Zhenli Xu

AbstractThe interaction force between likely charged particles/surfaces is usually repulsive due to the Coulomb interaction. However, the counterintuitive like-charge attraction in electrolytes has been frequently observed in experiments, which has been theoretically debated for a long time. It is widely known that the mean field Poisson-Boltzmann theory cannot explain and predict this anomalous feature since it ignores many-body properties. In this paper, we develop efficient algorithm and perform the force calculation between two interfaces using a set of self-consistent equations which properly takes into account the electrostatic correlation and the dielectric-boundary effects. By solving the equations and calculating the pressure with the Debye-charging process, we show that the self-consistent equations could be used to study the attraction between like-charge surfaces from weak-coupling to mediate-coupling regimes, and that the attraction is due to the electrostatics-driven entropic force which is significantly enhanced by the dielectric depletion of mobile ions. A systematic investigation shows that the interaction forces can be tuned by material permittivity, ionic size and valence, and salt concentration, and that the like-charge attraction exists only for specific regime of these parameters.


2019 ◽  
Vol 21 (27) ◽  
pp. 14858-14864 ◽  
Author(s):  
Cong Pan ◽  
Shasha Yi ◽  
Zhonghan Hu

Complex nonlinear responses of fluids to charge walls are predicted by mean-field theory.


Crystals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 976
Author(s):  
Nicola Simon ◽  
Maximilian Krause ◽  
Paul Heinemann ◽  
Hannes Erdle ◽  
Thomas Böhlke ◽  
...  

Multi-phase materials often times consist of constituents with high contrasts in phase-specific mechanical properties. Here, even after homogeneous plastic deformation phase-specific residual stresses develop that may affect the components behaviour in service. For numerical simulation of phase-specific residual stresses, knowledge of the particular phase-specific strain hardening behaviour is essential. In this study, the strain hardening of ferrite and austenite in cold rolled duplex stainless steel of type X2CrNiN23-4 is investigated. By means of X-ray diffraction, the phase-specific load partitioning and residual stress evolution are analysed for uniaxial load application in three directions within the sheets plane, taking into account the sheet metals phase specific anisotropy. In order to assess the necessity for experimental determination of anisotropic phase specific behaviour, the strain hardening parameters, derived from only one loading direction, are implemented in a mean-field approach for prediction of phase-specific stresses. A simplified simulation approach is applied that only considers macroscopic plastic anisotropy and results are compared to experimental findings. For all investigated loading directions, it was observed that austenite is the high-strength phase. This load partitioning behaviour was confirmed by the evolution of phase-specific residual stresses as a result of uniaxial elasto-plastic loading. With the simplified and fast numerical approach, satisfying results for prediction of anisotropic phase-specific (residual) stresses are obtained.


2021 ◽  
Author(s):  
Dimiter N Petsev ◽  
Frank van Swol ◽  
Laura J D Frink
Keyword(s):  

1977 ◽  
Vol 32 (12) ◽  
pp. 1435-1437 ◽  
Author(s):  
S. Zuca ◽  
M. Constantinescu

Abstract The cationic self-diffusion coefficients in molten (Tl-Na)NO3 and (Tl -Rb)NO3 systems were investigated as a function of temperature and concentration. The obtained data were examined from the viewpoint of polarization and ionic size effects.


1997 ◽  
Vol 282-287 ◽  
pp. 797-798 ◽  
Author(s):  
Xiaojia Chen ◽  
Jian Sha ◽  
Zhuan Xu ◽  
Zhengkuan Jiao ◽  
Qirui Zhang
Keyword(s):  

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