Pressure-Induced Fm-3m
R-3 Phase Transition in NaSbF6
1997 ◽
Vol 53
(1)
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pp. 25-31
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Keyword(s):
X Ray
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High-pressure X-ray diffraction measurements on NaSbF6 powder were performed up to 5.63 (7) GPa. At ∼0.1 GPa the cubic low-pressure phase with ordered ReO3-type crystal structure undergoes a phase transition into a rhombohedral LiSbF6-type modification. The high-pressure behaviour of this phase is characterized by rotations and distortions of the coordination octahedra, but it also can be described with a sphere-packing deformation. The octahedral distortions are probably caused by cation–cation repulsions.
2008 ◽
Vol 63
(6)
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pp. 707-712
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2007 ◽
Vol 62
(6)
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pp. 759-764
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