Dimethyl(2-oxido-1-naphthaldehydeisonicotinoylhydrazonato)tin(IV) methanol solvate

2006 ◽  
Vol 62 (4) ◽  
pp. m836-m837
Author(s):  
Shao-Wen Chen ◽  
Han-Dong Yin ◽  
Da-Qi Wang
Keyword(s):  
Molecular Structure ◽  
Complex Molecule ◽  
Solvent Molecule ◽  
Title Complex ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal ◽  
Hydrogen Bonded

In the molecular structure of the title complex, [Sn(CH3)2(C17H11N3O2)]·CH3OH, the Sn atom is in a distorted trigonal–bipyramidal coodination, with Sn—O distances of 2.099 (6) and 2.128 (6) Å. A methanol solvent molecule is O—H...N hydrogen bonded to the complex molecule.

scholarly journals Chiral crystallization of a zinc(II) complex

2021 ◽  
Vol 77 (5) ◽  
pp. 542-546
Author(s):  
Shabana Noor ◽  
Shintaro Suda ◽  
Tomoyuki Haraguchi ◽  
Fehmeeda Khatoon ◽  
Takashiro Akitsu
Keyword(s):  
Hydrogen Bond ◽  
Schiff Base ◽  
Complex Molecule ◽  
Solvent Molecule ◽  
Hirshfeld Surface ◽  
Supramolecular Interactions ◽  
Orthorhombic Space Group ◽  
Complex Molecules ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal

The compound, {6,6′-dimethoxy-2,2′-[(4-azaheptane-1,7-diyl)bis(nitrilomethanylidyne)]diphenolato}zinc(II) methanol monosolvate, [Zn(C22H27N3O4)]·CH3OH, at 298 K crystallizes in the orthorhombic space group Pna21. The Zn atom is coordinated by a pentadentate Schiff base ligand in a distorted trigonal–bipyramidal N3O2 geometry. The equatorial plane is formed by the two phenolic O and one amine N atom. The axial positions are occupied by two amine N atoms. The distorted bipyramidal geometry is also supported by the trigonality index (τ), which is found to be 0.85 for the molecule. In the crystal, methanol solvent molecule is connected to the complex molecule by an O—H...O hydrogen bond and the complex molecules are connected by weak supramolecular interactions, so achiral molecules generate a chiral crystal. The Hirshfeld surface analysis suggests that H...H contacts account for the largest percentage of all interactions.

Aqua(2-chloronicotinato)triphenyltin(IV)

2006 ◽  
Vol 62 (4) ◽  
pp. m685-m686
Author(s):  
Hao-Long Xu ◽  
Han-Dong Yin ◽  
Gang Li
Keyword(s):  
Solid State ◽  
Water Molecule ◽  
Title Complex ◽  
The Other ◽  
Carboxylate Group ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal ◽  
Hydrogen Bonded

The title complex, [Sn(C6H5)3(C6H3ClNO2)(H2O)], is five-coordinate with a distorted trigonal–bipyramidal geometry in the solid state. The O atom of the carboxylate group occupies one of the axial sites and the O atom of the water molecule occupies the other. Water H atoms are involved in an intermolecular hydrogen-bonded network with the uncoordinated carboxylate O atom and the pyridine N atom; the interactions lead to two types of rings.

[2-Oxidobenzaldehyde (4-hydroxylbenzoyl)hydrazonato]diphenyltin(IV) ethanol solvate

2006 ◽  
Vol 62 (7) ◽  
pp. m1504-m1505 ◽  
Author(s):  
Min Hong ◽  
Han-Dong Yin ◽  
Da-Qi Wang
Keyword(s):  
Crystal Packing ◽  
Title Complex ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Ethanol Solvate ◽  
Solvent Molecules ◽  
Distorted Trigonal Bipyramidal ◽  
Hydrogen Bonded

In the title complex, [Sn(C6H5)2(C14H10N2O3)]·C2H6O, the Sn atom is in a distorted trigonal–bipyramidal geometry, with Sn—O distances of 2.077 (4) and 2.130 (4) Å. The crystal packing shows a hydrogen-bonded dimeric arrangement of two Sn complexes and two ethanol solvent molecules located about a crystallographic inversion centre.

scholarly journals The crystal and molecular structure of the bis(N,N,N′,N′-tetramethylethanediamine) adduct of I(Br)InInBr2, In2Br3I•2C6H16N2, an indium–indium bonded molecule

1984 ◽  
Vol 62 (3) ◽  
pp. 601-605 ◽  
Author(s):  
Masood A. Khan ◽  
Clovis Peppe ◽  
Dennis G. Tuck
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Crystal And Molecular Structure ◽  
Heavy Atom ◽  
Orthorhombic Space Group ◽  
Trigonal Bipyramidal ◽  
Cell Dimensions ◽  
Unit Cell Dimensions ◽  
Heavy Atom Method ◽  
Distorted Trigonal Bipyramidal

The crystal structure of the title compound has been determined by the heavy atom method. The crystals are orthorhombic, space group Pbca, with unit cell dimensions a = 22.795(3) Å, b = 17.518(2) Å, c = 12.396(3) Å, Z = 8; R = 0.0409 for 1527 unique "observed" reflections. The structure is disordered, with each halogen site (X) occupied by 75% Br, 25% I. The molecule consists of two X2(tmen)In units (tmen = N,N,N′,N′-tetramethylethanediamine) with distorted trigonal bipyramidal geometry, joined by an In—In bond 2.775(2) Å in length.

Crystal and molecular structure of diorganoammonium oxalatotrimethylstannate, [R2NH2][Me3Sn(C2O4)] (R=i-Bu, cyclohexyl)

2011 ◽  
Vol 34 (5-6) ◽  
pp. 127-130 ◽  
Author(s):  
Yaya Sow ◽  
Libasse Diop ◽  
Kieran C. Molloy ◽  
Gabrielle Kociok-Köhn
Keyword(s):  
Molecular Structure ◽  
Hydrogen Bonds ◽  
Diffraction Study ◽  
Crystal And Molecular Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Trigonal Bipyramidal ◽  
Trans Complex ◽  
A Chain ◽  
Distorted Trigonal Bipyramidal

Abstract The title compounds [R2NH2][C2O4SnMe3](R=i-Bu, Cy), in which tin atoms adopt a distorted trigonal bipyramidal configuration, have been prepared and submitted to an X-ray diffraction study. These compounds have been obtained from the reaction of (Cy2NH2)2C2O4·H2O or (i-Bu2NH2)2C2O4 with SnMe3Cl. In both [R2NH2][C2O4SnMe3] compounds, the trans complex has an almost regular trigonal bipyramidal geometry around the tin atom. The SnMe3 residues are connected as a chain with bridging oxalate anions in a trans-SnC3O2 framework, the oxygen atoms being in axial positions. The cations connect linear adjacent chains through NH…O hydrogen bonds giving layered structures.

[4-(Dimethylamino)pyridine-κN]bis(pentane-2,4-dionato-κ2 O,O′)copper(II)

2006 ◽  
Vol 62 (5) ◽  
pp. m1142-m1143 ◽  
Author(s):  
Leonard F. Lindoy ◽  
John C. McMurtrie ◽  
David Schilter
Keyword(s):  
Title Complex ◽  
Twofold Axis ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal

The title complex, [Cu(C5H7O2)2(C7H10N2)], is disposed about a twofold axis and forms a discrete molecule with the metal adopting a distorted trigonal–bipyramidal geometry within an NO4 donor set.

scholarly journals [2-(2,2′-Bipyridin-6-yl-κ2N1,N1′)benzo[b][1,5]naphthyridine-κN1]dichloridozinc

IUCrData ◽  
2016 ◽  
Vol 1 (11) ◽  
Author(s):  
Yosuke Tezuka ◽  
Kiyoshi Tsuge ◽  
Hideki Ohtsu
Keyword(s):  
Title Complex ◽  
Stacking Interactions ◽  
Coordination Environment ◽  
Axis Direction ◽  
Trigonal Bipyramidal ◽  
Π Stacking ◽  
Distorted Trigonal Bipyramidal

The coordination environment of the zinc(II) ion in the title complex, [ZnCl2(C22H14N4)], is distorted trigonal–bipyramidal comprised by three N atoms from the 2-([2,2′-bipyridin]-6-yl)benzo[b][1,5]naphthyridine ligand and two Cl−ions. In the crystal, neighbouring molecules are connected by π–π stacking interactions along thea-axis direction.

scholarly journals Crystal structure of a mixed-valence μ-oxide Sn12cluster

2014 ◽  
Vol 70 (11) ◽  
pp. m378-m379 ◽  
Author(s):  
Marina M. Kireenko ◽  
Kirill V. Zaitsev ◽  
Sergey S. Karlov ◽  
Mikhail P. Egorov ◽  
Andrei V. Churakov
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Complex Molecule ◽  
Mixed Valence ◽  
Asymmetric Unit ◽  
Coordination Numbers ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal Coordination ◽  
Solvent Molecules ◽  
Distorted Trigonal Bipyramidal

The mixed-valence μ-oxide Sn12cluster, decacarbonyltetra-μ4-oxido-hexa-μ3-oxido-tetrakis[μ-2,2′-(pyridine-2,6-diyl)bis(1,1-diphenylethanolato)]decatin(II)ditin(IV)dimolybdenum(O)(2Mo—Sn) toluene heptasolvate, [Mo2Sn12(C33H27NO2)4O10(CO)10]·7C7H8, has a crystallographically imposed inversion centre. The asymmetric unit also contains three and a half toluene solvent molecules, one of which is disordered about a centre of symmetry. The complex molecule comprises six distinct Sn atom species with four different coordination numbers, namely 3, 4, 5, and 6. The SnIIatoms forming the central Sn10O10core adopt distorted trigonal–pyramidal, square-pyramidal and octahedral coordination geometries provided by the μ-oxide atoms and by the O- and N-donor atoms of two pyridinediethanolate ligands. The terminal SnIVatoms have distorted trigonal–bipyramidal coordination geometries, with a μ4-oxide atom and the N atom of a pyridinediethanolate ligand occupying the axial positions, and the Mo atom of a Mo(CO)5group and the alkoxy O atoms of a ligand forming the equatorial plane. In the crystal, weak intra- and intermolecular C—H...O hydrogen bonds are observed.

scholarly journals Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium

2015 ◽  
Vol 71 (2) ◽  
pp. m31-m32 ◽  
Author(s):  
Md. Serajul Haque Faizi ◽  
Natalia O. Sharkina ◽  
Yuliya M. Davydenko
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Equatorial Plane ◽  
Title Complex ◽  
Coordination Geometry ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal

In the mononuclear title complex, [CdBr2(C20H17N3)(C3H7NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-ylmethylene)ethanamine (IQME), the coordination geometry around the Cd2+atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd—N = 2.401 (3) Å] and one dimethylformamide O-atom donor [Cd—O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd—N = 2.293 (3) Å] and two bromides [Cd—Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the CdIIatom from the equatorial plane being 0.046 (1) Å. An intramolecular C—H...Br interaction occurs. In the crystal, N—H...Br interactions generate [101] chains.

Synthesis and characterization of octahedral and trigonal bipyramidal transition metal complexes incorporating chelating gallate ligands: crystal and molecular structure of [Me2Ga(N2C5H7)(OCH2CH2NMe2)]Ni[(N2C5H7)2GaMe2]

1980 ◽  
Vol 58 (11) ◽  
pp. 1091-1100 ◽  
Author(s):  
Kenneth S. Chong ◽  
Steven J. Rettig ◽  
Alan Storr ◽  
James Trotter
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Transition Metal Complexes ◽  
Crystal And Molecular Structure ◽  
Synthesis And Characterization ◽  
Chelating Ligands ◽  
Full Matrix ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal

The preparation and physical properties of octahedral and trigonal bipyramidal complexes incorporating the tris-chelating ligands [Me2Ga(N2C5H7)(OCH2CH2NR′2)]− (R′ = H or Me) are described. Crystals of [dimethylbis(3,5-dimethyl-1-pyrazolyl)gallato (N(2),N′(2))][dimethyl (3,5 - dimethyl-1-pyrazolyl) (N,N-dimethylethanolamino(gallato (N(2), O, N(3))]nickel(II) are triclinic, a = 20.8562(11), b = 9.1536(4), c = 8.2798(4) Å, α = 100.204(3), β = 85.513(4), γ = 101.989(3)°, Z = 2, space group [Formula: see text]. The structure was solved by Patterson and Fourier syntheses and was refined by full-matrix least-squares procedures to R = 0.048 and Rw = 0.078 for 5508 reflections with I ≥ 3σ(I). The coordination about the Ni atom is distorted trigonal bipyramidal with the two nitrogen atoms from the Me2Ga(N2C5H7)2 ligand occupying equatorial positions. The tridentate Me2Ga(N2C5H7)(OCH2CH2NMe2) ligand is meridionally coordinated with the oxygen in the equatorial and the two nitrogens in the axial positions. Important bond lengths (corrected for libration) are: Ni—N(eq), 2.005(3) and 2.006(3), Ni—O, 1.993(3), Ni—N(pz—ax), 2.072(3), Ni—N(amino), 2.229(3), Ga—O, 1.913(3), Ga—N, 1.971(3)–1.989(3), and Ga—C, 1.961(10)–1.986(6) Å.

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