Synthesis and crystal structure of [Zn6Br4(C9H18NO)4(OH)4]·2C3H6O2
2020 ◽
Vol 76
(7)
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pp. 998-1002
Keyword(s):
The complete molecule of the hexametallic title complex, namely, tetrabromidotetra-μ-hydroxido-hexakis[μ-2-methyl-3-(pyrrolidin-1-yl)propan-2-olato]hexazinc(II) acetone disolvate, [Zn6Br4(C9H18NO)4(OH)4]·2C3H6O2, is generated by a crystallographic centre of symmetry. Two of the unique zinc atoms adopt distorted ZnO2NBr tetrahedral coordination geometries and the other adopts a ZnO3N tetrahedral arrangement. Both unique alkoxide ligands are N,O-chelating and both hydroxide ions are μ2 bridging. The crystal structure displays an O—H...O hydrogen bond between a μ2-OH group and an acetone solvent molecule. The Hirshfeld surface has been calculated and is described.
2019 ◽
Vol 75
(11)
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pp. 1808-1811
2014 ◽
Vol 70
(9)
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pp. m310-m311
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2016 ◽
Vol 72
(7)
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pp. 984-987
2015 ◽
Vol 71
(9)
◽
pp. m154-m155
2020 ◽
Vol 76
(11)
◽
pp. 1771-1774
Keyword(s):
2017 ◽
Vol 73
(11)
◽
pp. 1612-1615
2021 ◽
Vol 77
(8)
◽
pp. 834-838
2021 ◽
Vol 77
(5)
◽
pp. 542-546
2015 ◽
Vol 71
(8)
◽
pp. m152-m153
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