A method for the determination of heat and light fastness of insoluble organic pigments

1982 ◽  
Vol 11 (12) ◽  
pp. 14-18
Author(s):  
M.A. Rabah ◽  
A.A. Aboukhashaba ◽  
M.S. Aly
Author(s):  
Joel Bernstein

The occurrence of the polymorphism of pigments is surveyed, with a special emphasis on three of the most important classes of pigments: quinacridones, perylenes, and phthalocyanines. Organic pigments are molecular crystals of very low solubility that provide the colors for industrial and consumer products. The properties of those compounds, including color, stability, light fastness, etc., all depend intimately on the structure, hence on the existence of polymorphism and the specific polymorphic form. The chapter summarizes much of the known information of the known and reported polymorphism of pigments in tabular form, including the scientific and patent literature, patent references, and entries in the Cambridge Structural Database. The chapter closes with a discussion of the isomorphism of pigments.


2020 ◽  
Vol 49 (4) ◽  
pp. 273-281 ◽  
Author(s):  
Emine Arman Kandirmaz ◽  
Arif Ozcan ◽  
Duygu Er Ulusoy

Purpose Stimulant-sensitive materials exhibit physical or chemical reversible changes in their properties as a result of environmental variables. One of these materials is thermochromic materials. Materials with thermochromic sensitivity change their color with heat exchange. For this reason, it can be used in many different fields such as security inks. Such substances decompose rapidly by being affected by weather conditions. Furthermore, the particle sizes are larger than normal pigments, and therefore, it is difficult to stabilize thermochromic dyes. Because of all these adverse conditions, thermochromic colorants must be protected before use in the ink. This protection is planned to be provided by the microcapsulation technique. The purpose of this study is to determine the thermochromic printing inks that can be stored stably by microcapsulation technique, to protect it from environmental conditions and the determination of printability parameters. Design/methodology/approach In this study, capsules with a core material of thermochromic dyeing with polyurea formaldehyde (PUF) or poly-phenolmelamine formaldehyde (PMF) shell were synthesized at appropriate pH and temperature using the appropriate solvent and mixing speed. The chemical structure and dimensions of the obtained capsules were examined by ATR-FTIR and scanning electron microscopy, respectively. The produced thermochromic microcapsules were mixed with alkyd resin and mineral oil and screen printing ink was obtained. Printability tests such as surface morphology, color, gloss and light fastness were applied. Findings As a result, it was determined that PMF is not a suitable encapsulation technique for thermochromic dyes under suitable conditions and eliminates thermochromic property by providing heat stability. It was found that PUF microcapsulation can be used in thermochromic dyestuff encapsulation and does not lose the thermochromic property. It has also been found that PUF microcapsules increase the lightfastness and stability of thermochromic dye ink. Originality/value This study provides experimental research on the encapsulation of a thermochromic dye and its use in ink.


1966 ◽  
Vol 25 ◽  
pp. 93-97
Author(s):  
Richard Woolley

It is now possible to determine proper motions of high-velocity objects in such a way as to obtain with some accuracy the velocity vector relevant to the Sun. If a potential field of the Galaxy is assumed, one can compute an actual orbit. A determination of the velocity of the globular clusterωCentauri has recently been completed at Greenwich, and it is found that the orbit is strongly retrograde in the Galaxy. Similar calculations may be made, though with less certainty, in the case of RR Lyrae variable stars.


1999 ◽  
Vol 190 ◽  
pp. 549-554
Author(s):  
Nino Panagia

Using the new reductions of the IUE light curves by Sonneborn et al. (1997) and an extensive set of HST images of SN 1987A we have repeated and improved Panagia et al. (1991) analysis to obtain a better determination of the distance to the supernova. In this way we have derived an absolute size of the ringRabs= (6.23 ± 0.08) x 1017cm and an angular sizeR″ = 808 ± 17 mas, which give a distance to the supernovad(SN1987A) = 51.4 ± 1.2 kpc and a distance modulusm–M(SN1987A) = 18.55 ± 0.05. Allowing for a displacement of SN 1987A position relative to the LMC center, the distance to the barycenter of the Large Magellanic Cloud is also estimated to bed(LMC) = 52.0±1.3 kpc, which corresponds to a distance modulus ofm–M(LMC) = 18.58±0.05.


1961 ◽  
Vol 13 ◽  
pp. 29-41
Author(s):  
Wm. Markowitz
Keyword(s):  

A symposium on the future of the International Latitude Service (I. L. S.) is to be held in Helsinki in July 1960. My report for the symposium consists of two parts. Part I, denoded (Mk I) was published [1] earlier in 1960 under the title “Latitude and Longitude, and the Secular Motion of the Pole”. Part II is the present paper, denoded (Mk II).


1972 ◽  
Vol 1 ◽  
pp. 27-38
Author(s):  
J. Hers

In South Africa the modern outlook towards time may be said to have started in 1948. Both the two major observatories, The Royal Observatory in Cape Town and the Union Observatory (now known as the Republic Observatory) in Johannesburg had, of course, been involved in the astronomical determination of time almost from their inception, and the Johannesburg Observatory has been responsible for the official time of South Africa since 1908. However the pendulum clocks then in use could not be relied on to provide an accuracy better than about 1/10 second, which was of the same order as that of the astronomical observations. It is doubtful if much use was made of even this limited accuracy outside the two observatories, and although there may – occasionally have been a demand for more accurate time, it was certainly not voiced.


2000 ◽  
Vol 179 ◽  
pp. 205-208
Author(s):  
Pavel Ambrož ◽  
Alfred Schroll

AbstractPrecise measurements of heliographic position of solar filaments were used for determination of the proper motion of solar filaments on the time-scale of days. The filaments have a tendency to make a shaking or waving of the external structure and to make a general movement of whole filament body, coinciding with the transport of the magnetic flux in the photosphere. The velocity scatter of individual measured points is about one order higher than the accuracy of measurements.


1975 ◽  
Vol 26 ◽  
pp. 341-380 ◽  
Author(s):  
R. J. Anderle ◽  
M. C. Tanenbaum

AbstractObservations of artificial earth satellites provide a means of establishing an.origin, orientation, scale and control points for a coordinate system. Neither existing data nor future data are likely to provide significant information on the .001 angle between the axis of angular momentum and axis of rotation. Existing data have provided data to about .01 accuracy on the pole position and to possibly a meter on the origin of the system and for control points. The longitude origin is essentially arbitrary. While these accuracies permit acquisition of useful data on tides and polar motion through dynamio analyses, they are inadequate for determination of crustal motion or significant improvement in polar motion. The limitations arise from gravity, drag and radiation forces on the satellites as well as from instrument errors. Improvements in laser equipment and the launch of the dense LAGEOS satellite in an orbit high enough to suppress significant gravity and drag errors will permit determination of crustal motion and more accurate, higher frequency, polar motion. However, the reference frame for the results is likely to be an average reference frame defined by the observing stations, resulting in significant corrections to be determined for effects of changes in station configuration and data losses.


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