Preparation and characterisation of silica supported organic hybrid pigments

2014 ◽  
Vol 43 (6) ◽  
pp. 325-331 ◽  
Author(s):  
Yong Zhang ◽  
Xuening Fei ◽  
Lu Yu ◽  
Lingyun Cao ◽  
Baolian Zhang

Purpose The purpose of the work reported in this paper is to prepare hybrid pigments fabricated by depositing pigment yellow 12 (PY12) on the surface of silica gel to improve the application performance of the resulting pigments. The particle size distribution, optical properties, thermal stability, water dispersibility and flowability of the pigments with and without silica gel modification were studied. Design/methodology/approach The hybrid pigments were synthesised with different amount of silica gel. The modified pigments were characterised by Fourier transforms infrared spectroscopy, X-ray diffraction, thermal analysis, scanning electron microscopy and transmission electron microscopy. Findings The particle size distribution of the modified pigments was found to have been altered significantly. This can be explained by the interaction between pigments and silica gel, which prevented self-aggregation of pigment particles and hence improved the properties of pigments. Research limitations/implications Only silica supports and pigment yellow 12 were evaluated. Other pigments could also be studied. Practical implications Modification of pigment particles with smaller particle size can increase the efficiency of the modified pigment, in terms of colour shade and tinting strength, due to better particle size distribution. Originality/value The paper demonstrates that inorganic core can prevent self-aggregation of pigment particles, and the application properties of such pigment depend on the resulting degree of dispersion of pigment particles.

1953 ◽  
Vol 26 (2) ◽  
pp. 441-446
Author(s):  
M. van den Tempel

Abstract The particle size distribution of the rubber globules in Hevea latex has been studied by means of electron microscopy. Most of the particles, even in concentrated latex, are less than 0.2 micron in diameter and are, consequently, not visible in the light microscope. These small particles have considerable influence on the specific interface, but they contain only a few per cent of the rubber present.


2016 ◽  
Vol 45 (5) ◽  
pp. 363-370 ◽  
Author(s):  
Fatemeh Andami ◽  
Maryam Ataeefard ◽  
Farhood Najafi ◽  
Mohammad Reza Saeb

Purpose Printing toners are polymer composites accountable for transmission of digital images onto target substrates. Bearing in mind the ever increasing demand for high quality digital printing, modification and/or integration of existing techniques for manufacturing toners with favourable morphological and colour characteristics appears of vital importance. The present study aims to uncover the significance of in-situ polymerisation method, i.e. suspension, emulsion and mini-emulsion to control the microstructure of toner particles (particle size, particle size distribution and sphereness) while keeping the energy required for polymerisation along with reaction conversion at a reasonable level. Design/methodology/approach Assessment of particle size, particle size distribution and reaction conversion visualised the potential of suspension, emulsion and mini-emulsion polymerisation techniques to control microstructure, and colour characteristics of synthesized toners as well. Findings The results provided support for the fact that either the emulsion or mini-emulsion polymerisation routes will result in toners having an acceptable particle size and particle size distribution in the presence of a redox precursor. The higher monomer conversion at low temperature, as compared to the suspension polymerisation, was noticeable. Practical implications Analysing the glass transition temperature and colour characteristics of the resulting toners elucidated the superiority of mini-emulsion with respect to the other two cases which ranks this method on account of application. Originality/value For the first time, mini-emulsion route was put into practice and toners with acceptable colour and microstructure features were synthesised. In spite of lower polymerisation temperature and higher conversion of mini-emulsion compared to suspension and emulsion polymerisation techniques, further investigations are required to fine-tuning the properties of toners produced through this method.


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