Yttrium iron garnet (Y3Fe5O12) films were prepared by a sol-gel method followed by an annealing process at 500,600,700,800, and 900°C in oxygen atmosphere for 2 hours. The microstructure characterization carried out by an X-ray diffractometer showed that the film started to crystalline into YIG phase at 700°C. The average grain size of the films measured using a field emission scanning electron microscope gave the average value of 20 to 70 nm. The magnetic properties measured by a vibrating sample magnetometer showed that all of the films were soft magnetic materials. The saturation magnetization values increased with the increment of annealing temperature. However, the coercivity values were independence with temperatures.Keywords:Thinfilms;Crystalline;Sol-gelmethod;
AbstractCerium substituted yttrium iron garnet (Ce0.2Y2.8Fe5O12; Ce-YIG) nanoparticles were produced via the sol-gel method from solutions of Ce-, Y- and Fe-based precursors, a solvent and a chelating agent. The solutions were dried at 200°C and heat treated at temperatures between 800 °C and 1400°C for 3 h in air. The effects of pH and annealing temperature on the structure, phase formation, magnetic properties and crystallite size were investigated. A cubic YIG phase was obtained for the sample annealed at 1400 °C. The presented results showed that the pH value of the starting solution affects the crystal size and consequently, the saturation magnetization.
In the present work, the sinterability and formation of nanosized yttrium iron garnet (Y3Fe5O12), yttrium perovskite ferrite (YFeO3), cobalt, nickel and zinc iron spinel (CoFe2O4, NiFe2O4 and ZnFe2O4, respectively) powders by an aqueous sol-gel processes are investigated. The phase purity of synthesized nano-compounds was characterized by powder X-ray diffraction analysis (XRD). The microstructural evolution and morphological features of obtained transition metal ferrites were studied by scanning electron microscopy (SEM). The possible application of these nanosized transition metal ferrites as ceramic pigments was demonstrated.
Effect of pH and annealing temperature on the structural and magnetic properties of cerium-substituted yttrium iron garnet powders produced by the sol-gel method