In Situ U‐Th‐Pb Dating and Sr‐Nd Isotope Analysis of Bastnäsite by LA‐(MC)‐ICP‐MS

2019 ◽  
Vol 43 (4) ◽  
pp. 543-565 ◽  
Author(s):  
Yue‐Heng Yang ◽  
Fu‐Yuan Wu ◽  
Qiu‐Li Li ◽  
Yamirka Rojas‐Agramonte ◽  
Jin‐Hui Yang ◽  
...  
Keyword(s):  
2020 ◽  
Author(s):  
Johannes Hammerli

<p>The long-lived radiogenic isotope systems Lu-Hf and Sm-Nd have been widely used by geochemists to study magma sources and crustal residential times of (igneous) rocks in order to understand how early crust formed and to model the production rate and volume of continental crust on global and regional-scales during the last ~4.4 Ga. However, while throughout most of Earth’s history Nd and Hf isotope signatures in terrestrial rocks are well correlated due to their very similar geochemical behavior, some of Earth’s oldest rocks show an apparent inconsistency in their Nd and Hf isotope signatures. While Hf isotopes in early Archean rocks are generally (near) chondritic, Nd isotope signatures can be distinctly super- or sub-chondritic. The super-chondritic Nd isotope values in Eoarchean samples would suggest that these rocks are derived from a mantle reservoir depleted by prior crust extraction. The chondritic Hf isotope values, on the other hand, support a mantle source from which no significant volume of crust had been extracted. While a range of different processes, some of them speculative, might explain this Hf-Nd isotope paradox, recent research [1, 2] has shown that relatively simple, post-magmatic, open-system processes can explain decoupling of the typically correlative Hf-Nd isotope signatures. This talk will focus on the importance of identifying Nd-bearing accessory minerals in (Archean) rocks to understand how the Sm-Nd isotope system is controlled and how in situ isotope and trace element analyses by LA-(MC)-ICP-MS in combination with detailed petrographic observations help to understand when and via which processes the two isotope systems become decoupled. Reconstructing the isotopic evolution of the different isotope systems since formation of the protoliths has important implications for our understanding of early crust formation and questions some of the proposed current models for early crust extraction from the mantle.</p><p> </p><p>[1] Hammerli et al. (2019) Chem. Geol 2; [2] Fisher et al. (2020) EPSL</p>


2017 ◽  
Vol 32 (7) ◽  
pp. 1312-1319 ◽  
Author(s):  
Mona Weyrauch ◽  
Martin Oeser ◽  
Annika Brüske ◽  
Stefan Weyer

In this study, an in situ technique for high-precision determination of Ni stable isotope ratios by femtosecond-laser ablation-multicollector-ICP-MS (fs-LA-MC-ICP-MS) was developed.


2022 ◽  
Author(s):  
Chao Wang ◽  
et al.

Text S1: Analytical methods. Figure S1: Zr versus selected element variation diagrams to highlight the effects of alteration and metamorphism for the basalts from Langjiexue area. Figure S2: (A) Ti/Y vs. TiO2, and (B) Ti/Y vs. MgO diagrams for the basalt samples from the Langjiexue in Tethyan Himalaya. Table S1: Representative Permian-Triassic magmatic events along the Tethyan Himalaya. Table S2: Zircon LA-ICP-MS U-Pb in-situ analyzing results for zircons from the Langjiexue basalts. Table S3: Whole-rock major, trace element and Sr-Nd isotope data of Langjiexue basalts.


Minerals ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 85 ◽  
Author(s):  
Laura Whyatt ◽  
Stefan Peters ◽  
Andreas Pack ◽  
Christopher L. Kirkland ◽  
Tonci Balic-Zunic ◽  
...  

A metasomatic zone formed between the contact of a 2940 ± 5 Ma intrusive trondhjemite sheet in the Archean dunite of the Seqi Ultramafic Complex, SW Greenland, consists of three distinct mineral zones dominated by (1) talc, (2) anthophyllite, and (3) phlogopite. These zones supposedly resulted from a process of dissolution of olivine by silica rich fluid residual from the trondhjemite magma, with crystallization of secondary minerals along a compositional gradient in the fluid phase. A zircon crystal inclusion in a large (4 cm) olivine porphyroblast was dated in situ via LA-ICP-MS U–Pb isotope analysis, yielding a weighted mean 207Pb/206Pb age of 2963 ± 1 Ma, which coincides with granulite facies metamorphism and potential dehydration. Considering phase relations appropriate for the dunite composition, we deduced the talc forming conditions to be at temperatures of 600–650 °C and at a pressure below 1 GPa. This is supported by oxygen isotope data for talc, anthophyllite and phlogopite in the metasomatic zone, which suggests formation in the temperature range of 600–700 °C from fluids that had a δ18O of ~8‰ and a Δ’17O0.528 of about −40 ppm, i.e., from fluids that could have been derived from the late stage trondhjemite sheet.


2006 ◽  
Vol 21 (7) ◽  
pp. 666 ◽  
Author(s):  
Klaus Peter Jochum ◽  
Brigitte Stoll ◽  
Kirstin Herwig ◽  
Matthias Willbold

2016 ◽  
Vol 31 (7) ◽  
pp. 1414-1422 ◽  
Author(s):  
Lüyun Zhu ◽  
Yongsheng Liu ◽  
Tingting Ma ◽  
Jie Lin ◽  
Zhaochu Hu ◽  
...  

The spiked in-house standards provide a new approach for in situ Os isotope analysis of sulfides.


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