Transverse and axial resolution of femtosecond laser ablation

Femtosecond lasers are capable of precise ablation that produce surgical dissections in vivo. The transverse and axial resolution of the laser damage inside the bulk are important parameters of ablation. The transverse resolution is routinely quantified, but the axial resolution is more difficult to measure and is less commonly performed. In some in vivo samples, fine dissections can also be difficult to visualize, but in vitro samples may allow clear imaging. Using a 1040-nm, 400-fs pulsed laser, we performed ablation inside agarose and glass, producing clear and persistent damage spots. Near the ablation threshold of both media, we found that the axial resolution is similar to the transverse resolution. We also ablated neuron cell bodies and fibers in C. elegans and demonstrate submicrometer resolution in both the transverse and axial directions, consistent with our results in agarose and glass. Using simple yet rigorous methods, we define the resolution of laser ablation in transparent media along all directions.

Revealing the Quadrupole Radiation of Liquid Gallium Nanospheres

Gallium (Ga) nanospheres (NSs) with diameters ranging from 50 to 300 nm are fabricated by using femtosecond laser ablation. The forward scattering of large Ga nanospheres measured using dark-field microscopy is determined by the coherent interaction between dipole and quadrupole resonances while it becomes governed by the dipole resonance when evanescent wave excitation is employed. We demonstrate that the scattering spectrum and pattern of quadrupole of large Ga NS can be resolved by using a cross-polarized analyzer in the collection channel. The experimental observations agree well with the numerical simulation based on the complex refractive index of liquid Ga.

Determination of carbon isotopes in carbonates (calcite, dolomite, magnesite, siderite) by femtosecond laser ablation multi-collector ICP-MS

This study reports a method for in situ determination of stable carbon (δ13C ‰) isotope compositions for calcite, dolomite, magnesite and siderite by femtosecond laser ablation multi-collector inductively coupled plasma...

Femtosecond-Laser-Ablation Dynamics in Silicon Revealed by Transient Reflectivity Change

The dynamics of ablation in monocrystalline silicon, from electron-hole plasma generation to material expansion, upon irradiation by a single femtosecond laser pulse (1030 nm, 300 fs pulse duration) at a wide range of fluences is investigated using a time-resolved microscopy technique. The reflectivity evolution obtained from dynamic images in combination with a theoretical Drude model and a Two-Temperature model provides new insights on material excitation and ablation process. For all fluences, the reflectivity increased to a temporary stable state after hundreds of femtoseconds. This behavior was predicted using a temperature-dependent refractive index in the Drude model. The increase in velocity of plasma generation with increasing fluence was theoretically predicted by the Two-Temperature model. Two ablation regimes at high fluences (>0.86 J/cm2) were identified through the measured transient reflectivity and ablation crater profile. The simulation shows that the fluence triggering the second ablation regime produces a boiling temperature (silicon, 2628 K).

Effects of Drilling Technology on Mini-Implant Primary Stability: A Comparison of the Mechanical Drilling and Femtosecond Laser Ablation

Objectives: Primary stability is a fundamental prerequisite in predicting the prognosis of a mini-implant (MI) as a skeletal anchorage. This study aims to evaluate the influence of implant site preparation technology on the primary stability of MI.Methods: A total of 108 bovine cortical bone samples were fabricated to three thicknesses (0.5, 1.0, and 1.5 mm). For each thickness group, the samples were divided into three subgroups: I (without site preparation), II (site preparation with a mechanical drill), and III (site preparation with femtosecond laser ablation). After MI insertion into these samples, the pull out strength of MI was measured by lateral pull out tests.Results: For the 0.5 mm thickness samples, the lateral pull-out strength was 9.9±2.7 N in subgroup I, 6.7±2.1 N in subgroup II, and 15.2±2.6 N in subgroup III. For the 1.0 mm thickness samples, the lateral pull-out strength was 39.3±2.5N in subgroup I, 38.2±2.7N in subgroup II, and 46.3±1.7 N in subgroup III. For the 1.5 mm thickness samples, the lateral pull-out strength was 73.9±4.8 N in subgroup I, 70.1±2.8 N in subgroup II, 75.0±2.2 N in subgroup III. No signs of carbonization or substantial cracking were visible in any of the bone samples.Conclusion: Site preparation with laser ablation significantly improved the lateral pull-out strength over mechanical preparation and control (no site preparation) in thinner cortical bone samples (1.0 and 0.5 mm). Such improvement in lateral pull-out strength decreases as the samples become thicker and diminishes in thick (1.5 mm) cortical bone samples.

Nitrogen-doped graphene quantum dots synthesized by femtosecond laser ablation in liquid from laser induced graphene

In this work, graphene quantum dots (GQDs) synthesized by femtosecond laser ablation in liquid (LAL) using laser-induced graphene (LIG) as the carbon source. Nitrogen-doped graphene quantum dots (N-GQDs) were successfully synthesized by adding ammonia water to the graphene suspension. The GQDs/N-GQDs structure consist of a graphitic core with oxygen and nitrogen functionalities and particle size less than 10 nm, as demonstrated by X-ray photoelectron spectroscopy, Fourier infrared spectrometer spectroscopy and transmission electron microscopy. The absorption peak and PL spectrum and quantum yield of the N-GQDs were significantly enhanced compared with the undoped GQDs. Further, the possible mechanism of synthesis GQDs is discussed. Furthermore, the N-GQDs were used as a fluorescent probe for detection of Fe3+ ions. The N-GQDs may extend the application of graphene-based materials to bioimaging, sensor and, photoelectronic.

Deposition of GaN nanoparticles on the surface of a copper film under the action of electrostatic field during the femtosecond laser ablation synthesis in ammonia environment

In this article, we show the possibility for obtaining and deposition of gallium nitride nanoparticles under the action of femtosecond laser radiation. Using the developed setup for thermal vacuum deposition of copper on silicon plates, we obtained the thin-film substrates following by the deposition of gallium nitride on them. The gallium nitride was formed by applying the femtosecond laser radiation to the gallium targets in ammonia medium. The controlled collection of ablation products following by their removal from the processing area by means of electrostatic field was used in the setup in order to efficiently collect gallium nitride nanoparticles. The formation of gallium nitride nanoparticles is verified by the results of X-ray diffraction analysis.

Effects of static and dynamic femtosecond laser modifications of Ti/Zr multilayer thin films

The experimental study of the static and dynamic femtosecond laser ablation of the multilayer 15x(Ti/Zr)/Si system is reported. The layer-by-layer selective laser ablation mechanism was studied by analysis of the surface morphology and elemental composition in static single pulse irradiation in a range of pulse energy from 10 to 17 $$\upmu $$ μ J. The selective ablations, as number of concentric circles in modified spots are increased with the pulse energy. The boundary between the circles was shown a change in the depth, comparable to the thickness of the individual layers. Changes in the elemental composition at the edges are associated with the removal of the layer by layer. The dynamic multipulse irradiation was observed via the production of lines with laser-induced periodic surface structures (LIPSS) at different laser parameters (scan velocities and laser polarization). The spatial periodicity of the formed LIPSS depends on changes in the effective number of pulses and laser polarization, as well as the nature of the material. For better interpretation of the experimental results, simulations have been conducted to explore the thermal response of the multiple layered structure 15x(Ti/Zr) after static single pulse irradiation. Graphic Abstract