Pilot-Scale Electrochemical Treatment of a 1,4-Dioxane Source Zone

Electrochemical disinfection of surface water using mixed metal oxide anodes was evaluated in a pilot-scale demonstration. Disinfection rates, chlorine generation, energy demand, and generation of disinfection by-products were monitored over the 190-day study. Particular attention was given to the generation of trihalomethanes (THMs) and haloacetic acids (HAAs) during the electrochemical treatment cycle. In addition, the potential for generation of THMs and HAAs during post-treatment storage of the water was assessed. The electrochemical treatment system resulted in a 2- to 3-log removal of total heterotrophic bacteria, with values below detection (<1 CFU/mL) often observed. Disinfection occurred with only very low levels of observed chlorine generation (<0.1 mg/L), suggesting that alternate disinfection mechanisms likely played a significant role in the observed removal of bacteria. THM and HAA concentrations after treatment were consistently well below regulatory levels. Results also showed that electrochemical treatment significantly reduced the formation of bromoform when the water received subsequent exposure to hypochlorite. Removal of naturally occurring bromide in the water by the electrochemical system may have been the cause (in part) for this observed mitigation of bromoform formation. The formation of calcium scale on the cathode surface over time was the primary operational challenge.

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Integrated electroenzymatic and electrochemical treatment of petrochemical wastewater using a pilot scale membraneless system

Process Biochemistry ◽

10.1016/j.procbio.2008.08.006 ◽

2008 ◽

Vol 43 (12) ◽

pp. 1371-1376 ◽

Cited By ~ 6

Author(s):

Seung-Hee Cho ◽

Hong-Joo Lee ◽

Seung-Hyeon Moon

Keyword(s):

Pilot Scale ◽

Electrochemical Treatment ◽

Petrochemical Wastewater

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Laboratory and Semi-Pilot Scale Study on the Electrochemical Treatment of Perfluoroalkyl Acids from Ion Exchange Still Bottoms

Water ◽

10.3390/w13202873 ◽

2021 ◽

Vol 13 (20) ◽

pp. 2873

Author(s):

Vanessa Y. Maldonado ◽

Michael F. Becker ◽

Michael G. Nickelsen ◽

Suzanne E. Witt

Keyword(s):

Ion Exchange ◽

Environmental Concern ◽

Degradation Kinetics ◽

Coulombic Efficiency ◽

Pilot Scale ◽

Electrochemical Treatment ◽

Laboratory Scale ◽

Perfluoroalkyl Acids ◽

Boron Doped Diamond ◽

High Concentrations

The ubiquitous presence of perfluoroalkyl acids (PFAAs) in the environment remains a serious environmental concern. In this study, the electrochemical oxidation (EO) of PFAAs from the waste of ion exchange (IX) still bottoms was assessed at the laboratory and semi-pilot scales, using full boron-doped diamond (BDD) electrochemical cells. Multiple current densities were evaluated at the laboratory scale and the optimum current density was used at the semi-pilot scale. The results at the laboratory scale showed >99% removal of total PFAAs with 50 mA/cm2 after 8 h of treatment. PFAAs treatment at the semi-pilot scale showed 0.8-fold slower pseudo-first-order degradation kinetics for total PFAAs removal compared to at the laboratory scale, and allowed for >94% PFAAs removal. Defluorination values, perchlorate (ClO4−) generation, coulombic efficiency (CE), and energy consumption were also assessed for both scales. Overall, the results of this study highlight the benefits of a tandem concentration/destruction (IX/EO) treatment approach and implications for the scalability of EO to treat high concentrations of PFAAs.

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Upscaling of foam forming technology for pilot scale

TAPPI Journal ◽

10.32964/tj18.8.461 ◽

2019 ◽

Vol 18 (8) ◽

Cited By ~ 1

Author(s):

JANI LEHMONEN ◽

TIMO RANTANEN ◽

KARITA KINNUNEN-RAUDASKOSKI

Keyword(s):

Production Efficiency ◽

Strength Loss ◽

Pilot Scale ◽

Foam Density ◽

Forming Process ◽

Production Scale ◽

Forming Technology ◽

Wet Pressing ◽

Foam Forming ◽

Board Industry

The need for production cost savings and changes in the global paper and board industry during recent years have been constants. Changes in the global paper and board industry during past years have increased the need for more cost-efficient processes and production technologies. It is known that in paper and board production, foam typically leads to problems in the process rather than improvements in production efficiency. Foam forming technology, where foam is used as a carrier phase and a flowing medium, exploits the properties of dispersive foam. In this study, the possibility of applying foam forming technology to paper applications was investigated using a pilot scale paper forming environment modified for foam forming from conventional water forming. According to the results, the shape of jet-to-wire ratios was the same in both forming methods, but in the case of foam forming, the achieved scale of jet-to-wire ratio and MD/CD-ratio were wider and not behaving sensitively to shear changes in the forming section as a water forming process would. This kind of behavior would be beneficial when upscaling foam technology to the production scale. The dryness results after the forming section indicated the improvement in dewatering, especially when foam density was at the lowest level (i.e., air content was at the highest level). In addition, the dryness results after the pressing section indicated a faster increase in the dryness level as a function of foam density, with all density levels compared to the corresponding water formed sheets. According to the study, the bonding level of water- and foam-laid structures were at the same level when the highest wet pressing value was applied. The results of the study show that the strength loss often associated with foam forming can be compensated for successfully through wet pressing.

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Application of a Pilot-Scale Pulsed Electrocoagulation system to OCC-Based Paper Mill Effluent

TAPPI Journal ◽

10.32964/tj8.3.14 ◽

2009 ◽

Vol 8 (3) ◽

pp. 14-20 ◽

Cited By ~ 2

Author(s):

YUAN-SHING PERNG ◽

EUGENE I-CHEN WANG ◽

SHIH-TSUNG YU ◽

AN-YI CHANG

Keyword(s):

Water Quality ◽

Quality Indicators ◽

Paper Mill ◽

Pilot Scale ◽

Operating Conditions ◽

Optimal Dosage ◽

Water Quality Indicators ◽

Paper Mill Effluent ◽

Treated Effluent ◽

True Color

Trends toward closure of white water recirculation loops in papermaking often lead to a need for system modifications. We conducted a pilot-scale study using pulsed electrocoagulation technology to treat the effluent of an old corrugated containerboard (OCC)-based paper mill in order to evaluate its treatment performance. The operating variables were a current density of 0–240 A/m2, a hydraulic retention time (HRT) of 8–16 min, and a coagulant (anionic polyacrylamide) dosage of 0–22 mg/L. Water quality indicators investigated were electrical con-ductivity, suspended solids (SS), chemical oxygen demand (COD), and true color. The results were encouraging. Under the operating conditions without coagulant addition, the highest removals for conductivity, SS, COD, and true color were 39.8%, 85.7%, 70.5%, and 97.1%, respectively (with an HRT of 16 min). The use of a coagulant enhanced the removal of both conductivity and COD. With an optimal dosage of 20 mg/L and a shortened HRT of 10 min, the highest removal achieved for the four water quality indicators were 37.7%, 88.7%, 74.2%, and 91.7%, respectively. The water qualities thus attained should be adequate to allow reuse of a substantial portion of the treated effluent as process water makeup in papermaking.

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Pilot-scale combustion studies with kraft lignin in a powder burner and a CFB boiler

TAPPI Journal ◽

10.32964/tj9.6.24 ◽

2010 ◽

Vol 9 (6) ◽

pp. 24-30 ◽

Cited By ~ 2

Author(s):

NIKLAS BERGLIN ◽

PER TOMANI ◽

HASSAN SALMAN ◽

SOLVIE HERSTAD SVÄRD ◽

LARS-ERIK ÅMAND

Keyword(s):

Circulating Fluidized Bed ◽

Black Liquor ◽

Chloride Content ◽

Pilot Scale ◽

High Energy ◽

Kraft Lignin ◽

High Energy Density ◽

Alkali Chloride ◽

Cfb Boiler ◽

Solid Biofuel

Processes have been developed to produce a solid biofuel with high energy density and low ash content from kraft lignin precipitated from black liquor. Pilot-scale tests of the lignin biofuel were carried out with a 150 kW powder burner and a 12 MW circulating fluidized bed (CFB) boiler. Lignin powder could be fired in a powder burner with good combustion performance after some trimming of the air flows to reduce swirl. Lignin dried to 10% moisture content was easy to feed smoothly and had less bridging tendencies in the feeding system than did wood/bark powder. In the CFB boiler, lignin was easily handled and cofired together with bark. Although the filter cake was broken into smaller pieces and fines, the combustion was not disturbed. When cofiring lignin with bark, the sulfur emission increased compared with bark firing only, but most of the sulfur was captured by calcium in the bark ash. Conventional sulfur capture also occurred with addition of limestone to the bed. The sulfur content in the lignin had a significantly positive effect on reducing the alkali chloride content in the deposits, thus reducing the high temperature corrosion risk.

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