Distribution Patterns of Pentacyclic Triterpenoid Hydrocarbons in Low-Mature Source Rocks from Eastern China

2010 ◽  
Vol 72 (4) ◽  
pp. 399-408 ◽  
Author(s):  
HOU Dujie ◽  
ZHANG Linye ◽  
WANG Tieguan
Keyword(s):  
Eastern China ◽  
Distribution Patterns ◽  
Source Rocks ◽  
Pentacyclic Triterpenoid

Even and Odd Carbon Predominance Coexisting N-Alkanes in Paleogene Dark Shale in Jinhu Sag of Subei Basin

2013 ◽  
Vol 312 ◽  
pp. 871-875
Author(s):  
Ning Song ◽  
Mei Jun Li ◽  
Jin Chuan Zhang
Keyword(s):  
Organic Matter ◽  
Eastern China ◽  
Sedimentary Environment ◽  
Distribution Patterns ◽  
Depositional Environments ◽  
Source Rocks ◽  
Ancient Lake ◽  
High Gamma ◽  
Original Organic Matter ◽  
Β Carotene

Gas chromatograms of saturated hydrocarbons of shale rock extracts show three patterns of n-alkanets in the second member of Funning formation (E1f2) in Jinhu Sag of Subei basin, eastern China. Three patterns of n-alkanets are the odd-to-even carbon predominance, the even-to-odd carbon predominance, and the even and odd carbon predominance coexisting, respectively. In this paper, the characteristics of n-alkanet coexisting even and odd carbon predominance and its origin and sedimentary environment are investigated only. The short-chain n-alkanets and long-chain n-alkanets are characterized by pronounced odd carbon predominance, with the dominant carbon of nC15, nC17 and of nC25, nC27, nC29 and nC31. The mid-chain n-alkanets are dominated by even carbon predominance, with the dominant carbon of nC20 and nC22. The composition of biomarkers are characterized by phytane preference, high gamma cerate abundance, the presence of β-carotene and C24-tetracyclic terrapin, which indicate that the organic matter in source rocks deposited in an anoxic, hyper saline lacus trine environment. The biomarkers are no homogeneous, which shows that salinity and redo is not constant in pale-lacus trine. The n-alkanets are mainly derived from algae in the ancient lake and macro pyres on land or around the edges of the ancient lake. The n-alkanets distribution patterns of the dark shales studied are believed not to be dependent on the redo in the depositional environments or the salinity of the water body, but to be associated with original organic matter composition.

scholarly journals Relative sorption coefficient: Key to tracing petroleum migration and other subsurface fluids

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
L. Zhang ◽  
Y. Wang ◽  
M.-W. Li ◽  
Q.-Z. Yin ◽  
W. Zhang
Keyword(s):  
Sedimentary Basins ◽  
Distribution Patterns ◽  
Polar Compounds ◽  
Source Rocks ◽  
Polar Molecules ◽  
Sorption Coefficient ◽  
Petroleum Migration ◽  
New Findings ◽  
Novel Concept ◽  
Incorrect Information

AbstractThe accumulation and spatial distribution of economically important petroleum in sedimentary basins are primarily controlled by its migration from source rocks through permeable carrier beds to reservoirs. Tracing petroleum migration entails the use of molecular indices established according to sorption capacities of polar molecules in migrating petroleum. However, little is known about molecular sorption capacities in natural migration systems, rendering these indices unreliable. Here, we present a new approach based on a novel concept of relative sorption coefficient for quantitatively assessing sorption capacities of polar molecules during natural petroleum migration. Using this approach, we discovered previously unrecognized “stripping” and “impeding” effects that significantly reduce the sorption capacities of polar compounds. These discoveries provide new insights into the behaviors of polar compounds and can easily explain why traditional molecular indices yield incorrect information about petroleum migration. In light of these new findings, we established new molecular indices for tracing petroleum migration. We demonstrate via case studies that the newly established indices, unlike traditional molecular indices, are reliable and effective in tracing petroleum migration. Our approach can be applied to diverse basins around the world to reveal distribution patterns of petroleum, which would decrease environmental risks of exploration by reducing unsuccessful wells.

scholarly journals Distribution and controls of petroliferous plays in subtle traps within a Paleogene lacustrine sequence stratigraphic framework, Dongying Depression, Bohai Bay Basin, Eastern China

2019 ◽  
Vol 17 (1) ◽  
pp. 1-22 ◽  
Author(s):  
Ji-Chang Zhu ◽  
Cai-Neng Zou ◽  
You-Liang Feng ◽  
Shu Jiang ◽  
Wei-An Wu ◽  
...  
Keyword(s):  
Eastern China ◽  
Source Rocks ◽  
Normal Faults ◽  
Dynamic Factor ◽  
Bohai Bay ◽  
Sequence Stratigraphic ◽  
Dongying Depression ◽  
Stratigraphic Framework ◽  
Incised Channel ◽  
Sand Bodies

AbstractThe characteristics of petroliferous plays in subtle traps within a sequence stratigraphic framework in the Dongying Depression are investigated in this study. Sand bodies within lowstand systems tracts (LSTs) of sequences, comprising incised-channel fills, sublacustrine fans, deltas in LSTs, controlled by syndepositional normal faults, and sand bodies within transgressive systems tracts (TSTs) to early highstand systems tracts (HSTs), consisting of beach bars, and turbidites, controlled by the prodelta slope, paleorelief, and syndepositional normal faults, are good subtle reservoirs. Mudstones and shale of deep lake subfacies in TSTs to early HSTs of sequences are source and cap rocks. Abnormal overpressure is the dominant dynamic factor for hydrocarbon migration from source rock to the subtle traps. Normal faults, sand bodies, and unconformities function as conduit systems. Sand bodies distributed in the abnormal overpressure source rocks within LSTs to early HSTs are petroliferous plays in lithologic traps. The petroliferous plays in stratigraphic traps are controlled by unconformities at margins of the Depression.

Geochemical migration of impurity trace elements and resultant fractal distribution patterns in source rocks

1994 ◽  
Vol 26 (4) ◽  
pp. 419-435 ◽  
Author(s):  
Yongzhang Zhou ◽  
Edward H. Chown ◽  
Guangzhi Tu ◽  
Jayanta Guha ◽  
Huangzhang Lu
Keyword(s):  
Trace Elements ◽  
Distribution Patterns ◽  
Source Rocks ◽  
Fractal Distribution

Hydrocarbon generation and evolution of the source rocks of the lower Es3 and upper Es4 members of the Shahejie Formation in the Niuzhuang Sub-sag, Jiyang Depression, Bohai Bay Basin, eastern China

2018 ◽  
Vol 6 (4) ◽  
pp. SN11-SN21
Author(s):  
Zhenkai Huang ◽  
Maowen Li ◽  
Quanyou Liu ◽  
Xiaomin Xie ◽  
Peng Liu ◽  
...  
Keyword(s):  
Activation Energy ◽  
Eastern China ◽  
Source Rocks ◽  
Bohai Bay ◽  
Hydrocarbon Generation ◽  
Bohai Bay Basin ◽  
Jiyang Depression ◽  
Generation Threshold ◽  
Oil Generation ◽  
Shahejie Formation

Systematic organic petrology and geochemistry analyses have been conducted in the source rocks of the lower Es3 and upper Es4 members of the Shahejie Formation in the Niuzhuang Sub-sag, Jiyang Depression, Bohai Bay Basin, eastern China. The results indicate that the main organic types of shale and nongypsum mudstone in the lower Es3 and upper Es4 member are I-II1 kerogen, and the predominant ([Formula: see text]) activation energy frequencies range from 57 to [Formula: see text]. The similar distribution characteristics in the two source rocks indicate that they have a similar hydrocarbon maturation process. An extensive pyrolysis analysis indicates that the source rocks of the upper Es4 member do not have an obvious double peak hydrocarbon generation model. Previous studies indicate that the hydrocarbon index peak at a depth of 2500–2700 m is affected by migrating hydrocarbon. Major differences are not observed in the hydrocarbon generation and evolution process of the shale and nongypsum mudstone. The primary oil generation threshold of the lower Es3 and upper Es4 members is approximately 3200 m, and the oil generation peak is approximately 3500 m. The activation energy distribution of the gypsum mudstone of the upper Es4 member is wider than that of the shale and nongypsum mudstone, and lower activation energies account for a larger proportion of the activation energies. The above factors may lead to a shallower oil generation threshold for gypsum mudstone compared with that for shale and nongypsum mudstone.

An integrated organic–inorganic geochemical characterization of Paleogene sediments in No.1 Structural Belt of the Nanpu Sag, Bohai Bay Basin, eastern China: implications for the origin of organic matter

2020 ◽  
Vol 21 (1) ◽  
pp. geochem2019-060
Author(s):  
Yu Guo ◽  
Wenzhe Gang ◽  
Gang Gao ◽  
Shangru Yang ◽  
Chong Jiang ◽  
...  
Keyword(s):  
Organic Matter ◽  
Higher Plants ◽  
Eastern China ◽  
Source Rocks ◽  
Bohai Bay ◽  
Type Ii ◽  
Lacustrine Environment ◽  
Anoxic Conditions ◽  
Supplementary Material ◽  
Nanpu Sag

Paleogene sediments, especially the third member of the Dongying Formation (Ed3) and the first and third members of the Shahejie Formation (Es1 and Es3), have been regarded as the most important source rocks in the Nanpu Sag. Organic and inorganic analyses, including Rock-Eval pyrolysis, gas chromatography-mass spectrometry, and element geochemistry, in 91 mudstone samples, were used to reconstruct the palaeoenvironmental conditions, such as palaeoclimate, palaeo-salinity and palaeo-redox conditions, and to recognize the origin of organic matter. The results show that Es3 has a higher TOC content than Es1 and Ed3. Hydrocarbon genetic potential (S1 + S2) of the samples indicate fair to good hydrocarbon potential. The kerogen type of Ed3 and Es1 source rocks are Type II1–II2, while Es3 source rocks are dominated by Type II2–III kerogens. Biomarkers and inorganic geochemical indicatives of source rocks, such as Pr/Ph, V/(V + Ni) and Cu/Zn, indicate a lacustrine environment with fresh to brackish water under suboxic to anoxic conditions during deposition. Ed3 source rocks are characterized by low G/C30H (gamacerane/C30hopane) (<0.1), TT/C30H (tricyclic terpane/C30hopane) and S/H (serane/hopane), high Pr/Ph (pristane/phytane) and C24TeT/C23TT (C24tetracyclic terpane/C23tricyclic terpane), indicating mixed input of both algae and terrestrial higher plants, dominated by terrestrial higher plants. Es1 source rocks display medium G/C30H, TT/C30H, S/H, Pr/Ph and C24TeT/C23TT, indicative of a mixed input of both algae and terrestrial higher plants. Es3 source rocks are characterized by high G/C30H (>0.1), TT/C30H and S/H, low Pr/Ph and C24TeT/C23TT, typical of a mixed input of algae and terrestrial higher plants, with algal dominance. Ed3, Es1 and Es3 source rocks were mostly deposited in semi-arid to humid-warm climate conditions, with an average temperature higher than 15°C. This study suggests that suitable temperatures, a fresh to brackish lacustrine environment and suboxic to anoxic conditions could result in a high organic matter concentration and preservation, thus providing prerequisites for the formation of high-quality source rocks.Supplementary material: Tables S1–S3 are available at https://doi.org/10.6084/m9.figshare.c.5227684

scholarly journals Geochemical characteristics and origin of hydrocarbons in the Mesoproterozoic reservoirs in the Liaoxi Depression, NE China

2019 ◽  
Vol 38 (2) ◽  
pp. 333-347 ◽  
Author(s):  
Youjun Tang ◽  
Meijun Li ◽  
Qiuge Zhu ◽  
Daxiang He ◽  
Xingchao Jiang ◽  
...  
Keyword(s):  
Molecular Marker ◽  
Source Rock ◽  
Middle Jurassic ◽  
Distribution Patterns ◽  
Geochemical Characteristics ◽  
Oil Reservoirs ◽  
Source Rocks ◽  
Ne China ◽  
Normal Alkanes ◽  
Petroleum Generation

Oil reservoirs have been discovered in the Mesoproterozoic strata in the Liaoxi Depression, NE China. In order to determine the source of oil shows of the Mesoproterozoic Gaoyuzhuang Formation and their organic geochemical characteristics, eight source rocks and reservoir cores from the Mesoproterozoic Gaoyuzhuang Formation and four source rocks from the overlying Middle Jurassic Haifanggou Formation were geochemically analysed. The distribution patterns of normal alkanes, acyclic isoprenoids, hopanes, steranes and triaromatic steroids of the Mesoproterozoic hydrocarbons from Well N-1 are consistent with those of source rock extracts from the Mesoproterozoic Gaoyuzhuang Formation in the Well L-1. The molecular marker compositions of source rock extracts from the overlying Middle Jurassic Haifanggou Formation are distinctively different from those of the Mesoproterozoic hydrocarbons. The results suggest that the Mesoproterozoic source rocks have significant petroleum generation potential. The Mesoproterozoic paleo-reservoir may be prospecting exploration targets in the Liaoxi Depression, NE China.

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