Probing the Effects of NOx and SOx Impurities on Oxy-Fuel Combustion in Supercritical CO2: Shock Tube Experiments and Chemical Kinetic Modeling

2020 ◽  
Vol 142 (12) ◽  
Author(s):  
Ramees K. Rahman ◽  
Samuel Barak ◽  
K.R.V. (Raghu) Manikantachari ◽  
Erik Ninnemann ◽  
Ashvin Hosangadi ◽  
...  
Keyword(s):  
High Pressure ◽  
Natural Gas ◽  
Shock Tube ◽  
Combustion Chamber ◽  
Ignition Delay ◽  
Methane Combustion ◽  
Chemical Kinetic ◽  
Reaction Model ◽  
Effect Of Impurities ◽  
Base Mechanism

Abstract The direct-fired supercritical carbon dioxide cycles are one of the most promising power generation methods in terms of their efficiency and environmental friendliness. Two important challenges in implementing these cycles are the high pressure (300 bar) and high CO2 dilution (>80%) in the combustor. The design and development of supercritical oxy-combustors for natural gas require accurate reaction kinetic models to predict the combustion outcomes. The presence of a small amount of impurities in natural gas and other feed streams to oxy-combustors makes these predictions even more complex. During oxy-combustion, trace amounts of nitrogen present in the oxidizer is converted to NOx and gets into the combustion chamber along with the recirculated CO2. Similarly, natural gas can contain a trace amount of ammonia and sulfurous impurities that get converted to NOx and SOx and get back into the combustion chamber with recirculated CO2. In this work, a reaction model is developed for predicting the effect of impurities such as NOx and SOx on supercritical methane combustion. The base mechanism used in this work is GRI Mech 3.0. H2S combustion chemistry is obtained from Bongartz et al. while NOx chemistry is from Konnov. The reaction model is then optimized for a pressure range of 30–300 bar using high-pressure shock tube data from the literature. It is then validated with data obtained from the literature for methane combustion, H2S oxidation, and NOx effects on ignition delay. The effect of impurities on CH4 combustion up to 16 atm is validated using NOx-doped methane studies obtained from the literature. In order to validate the model for high-pressure conditions, experiments are conducted at the UCF shock tube facility using natural gas identical mixtures with N2O as an impurity at ∼100 bar. Current results show that there is a significant change in ignition delay with the presence of impurities. A comparison is made with experimental data using the developed model and predictions are found to be in good agreement. The model developed was used to study the effect of impurities on CO formation from sCO2 combustors. It was found that NOx helps in reducing CO formation while the presence of H2S results in the formation of more CO. The reaction mechanism developed herein can also be used as a base mechanism to develop reduced mechanisms for use in CFD simulations.

Capturing the Effects of NOx and SOx Impurities on Oxy-Combustion Under Supercritical CO2 Conditions for Coal-Derived Syngas and Natural Gas Mixtures

2020 ◽  
Author(s):  
Ramees K. Rahman ◽  
Samuel Barak ◽  
K. R. V. (Raghu) Manikantachari ◽  
Erik Ninnemann ◽  
Ashvin Hosangadi ◽  
...  
Keyword(s):  
High Pressure ◽  
Natural Gas ◽  
Shock Tube ◽  
Combustion Chamber ◽  
Ignition Delay ◽  
Methane Combustion ◽  
Reaction Model ◽  
Reduced Mechanism ◽  
Effect Of Impurities ◽  
Base Mechanism

Abstract Direct fired supercritical carbon dioxide cycles are one of the most promising power generation method in terms of their efficiency and environmental friendliness. Two most important challenges in implementing these cycles are the high pressure (300 bar) and high CO2 dilution (>80 %) in the combustor. The design and development of supercritical oxy-combustors for natural gas requires accurate reaction kinetic models to predict the combustion outcomes. The presence of small amount of impurities in natural gas and other feed streams to oxy-combustors makes these predictions even more complex. During oxy-combustion, trace amounts of nitrogen present in the oxidizer is converted to NOx and gets into the combustion chamber along with the recirculated CO2. Similarly, natural gas can contain trace amount of ammonia and sulfurous impurities which gets converted to NOx and SOx and gets back into the combustion chamber with recirculated CO2. In this work, a reaction model is developed for predicting the effect of impurities like NOx and SOx on supercritical methane combustion. The base mechanism used in this work is GRI 3.0. H2S combustion chemistry is obtained from Bongartz et al. while NOx chemistry is from Konnov et al. The reaction model is then optimized for a pressure range of 30–300 bar using high pressure shock tube data from literature. It is then validated with data obtained from literature for methane combustion, H2S oxidation and NOx effects on ignition delay. The effect of impurities on CH4 combustion up to 16 atm is validated using NOx doped methane studies obtained from literature. In order to validate the model for high pressure conditions, experiments are conducted in a high pressure (∼100 bar) shock tube facility at UCF for natural gas identical mixtures with N2O as impurity. Current results show that there is significant change in ignition delay with the presence of impurities. A comparison is made with experimental data using the developed model and predictions are found to be in good agreement. The model developed was used to study the effect of impurities on CO formation from sCO2 combustor. It was found that NOx helps in reducing CO formation while presence of H2S results in formation of more CO. The reaction mechanism developed herein can also be used as a base mechanism to develop reduced mechanism for use in CFD simulations.

scholarly journals Shock tube ignition delay times and methane time-histories measurements during excess CO2 diluted oxy-methane combustion

2016 ◽  
Vol 164 ◽  
pp. 152-163 ◽  
Author(s):  
Batikan Koroglu ◽  
Owen M. Pryor ◽  
Joseph Lopez ◽  
Leigh Nash ◽  
Subith S. Vasu
Keyword(s):  
Shock Tube ◽  
Ignition Delay ◽  
Methane Combustion ◽  
Ignition Delay Times ◽  
Delay Times ◽  
Time Histories

Ignition delay times of methane fuels at thrust chamber conditions in an ultra-high-pressure shock tube

2022 ◽  
Author(s):  
Michael Pierro ◽  
Andrew Laich ◽  
Justin J. Urso ◽  
Cory Kinney ◽  
Subith Vasu ◽  
...  
Keyword(s):  
High Pressure ◽  
Shock Tube ◽  
Ignition Delay ◽  
Pressure Shock ◽  
Thrust Chamber ◽  
Ultra High Pressure ◽  
Ignition Delay Times ◽  
Delay Times

Computational Studies of Glow Plug Ignition of Injected High Pressure Gas Jets

2015 ◽  
Author(s):  
Kang Pan ◽  
James S. Wallace
Keyword(s):  
Natural Gas ◽  
Combustion Chamber ◽  
Ignition Delay ◽  
Numerical Study ◽  
Pressure Rise ◽  
Air Gap ◽  
Time Difference ◽  
Glow Plug ◽  
Gas Ignition ◽  
Ignition And Combustion

A numerical study of ignition and combustion in a glow plug (GP) assisted direct-injection natural gas (DING) engine is presented in this paper. The glow plug is shielded and the shield design is an important part of the combustion system development. The results simulated by KIVA-3V indicated that the ignition delay (ID) predicted by an in-cylinder pressure rise was different from that based on a temperature rise, attributed to the additional time required to burn more fuel to obtain a detectable pressure rise in the combustion chamber. This time difference for the ignition delay estimation can be 0.5 ms, which is significant relative to an ignition delay value of less than 2 ms. To further evaluate the time difference between the two different methods of ignition delay determination, sensitivity studies were conducted by changing the glow plug temperature, and rotating the glow plug shield opening angle towards the fuel jets. The results indicated that the ID method time difference varied from 0.3 to 0.8 ms for different combustion chamber configurations. In addition, this study also investigated the influences of different glow plug shield parameters on the natural gas ignition and combustion characteristics, by modifying the air gap between the glow plug and its shield, and by changing the shield opening size. The computational results indicated that a bigger air gap inside the shield can delay gas ignition, and a smaller shield opening can block the flame propagation for some specific fuel injection angles.

Investigation of Flame Stabilization in a High-Pressure Multi-Jet Combustor by Laser Measurement Techniques

2014 ◽  
Author(s):  
Oliver Lammel ◽  
Tim Rödiger ◽  
Michael Stöhr ◽  
Holger Ax ◽  
Peter Kutne ◽  
...  
Keyword(s):  
High Pressure ◽  
Natural Gas ◽  
Combustion Chamber ◽  
Gas Turbine ◽  
Recirculation Zone ◽  
Flame Stabilization ◽  
Operating Conditions ◽  
Pollutant Emissions ◽  
Single Shot ◽  
Optical Access

In this contribution, comprehensive optical and laser based measurements in a generic multi-jet combustor at gas turbine relevant conditions are presented. The flame position and shape, flow field, temperatures and species concentrations of turbulent premixed natural gas and hydrogen flames were investigated in a high-pressure test rig with optical access. The needs of modern highly efficient gas turbine combustion systems, i.e., fuel flexibility, load flexibility with increased part load capability, and high turbine inlet temperatures, have to be addressed by novel or improved burner concepts. One promising design is the enhanced FLOX® burner, which can achieve low pollutant emissions in a very wide range of operating conditions. In principle, this kind of gas turbine combustor consists of several nozzles without swirl, which discharge axial high momentum jets through orifices arranged on a circle. The geometry provides a pronounced inner recirculation zone in the combustion chamber. Flame stabilization takes place in a shear layer around the jet flow, where fresh gas is mixed with hot exhaust gas. Flashback resistance is obtained through the absence of low velocity zones, which favors this concept for multi-fuel applications, e.g. fuels with medium to high hydrogen content. The understanding of flame stabilization mechanisms of jet flames for different fuels is the key to identify and control the main parameters in the design process of combustors based on an enhanced FLOX® burner concept. Both experimental analysis and numerical simulations can contribute and complement each other in this task. They need a detailed and relevant data base, with well-known boundary conditions. For this purpose, a high-pressure burner assembly was designed with a generic 3-nozzle combustor in a rectangular combustion chamber with optical access. The nozzles are linearly arranged in z direction to allow for jet-jet interaction of the middle jet. This line is off-centered in y direction to develop a distinct recirculation zone. This arrangement approximates a sector of a full FLOX® gas turbine burner. The experiments were conducted at a pressure of 8 bar with preheated and premixed natural gas/air and hydrogen/air flows and jet velocities of 120 m/s. For the visualization of the flame, OH* chemiluminescence imaging was performed. 1D laser Raman scattering was applied and evaluated on an average and single shot basis in order to simultaneously and quantitatively determine the major species concentrations, the mixture fraction and the temperature. Flow velocities were measured using particle image velocimetry at different section planes through the combustion chamber.

scholarly journals Alternative Fuels Based on Biomass: An Experimental and Modeling Study of Ethanol Cofiring to Natural Gas

2015 ◽  
Vol 137 (9) ◽  
Author(s):  
Marina Braun-Unkhoff ◽  
Jens Dembowski ◽  
Jürgen Herzler ◽  
Jürgen Karle ◽  
Clemens Naumann ◽  
...  
Keyword(s):  
Power Generation ◽  
Natural Gas ◽  
Gas Turbine ◽  
Kinetic Modeling ◽  
Ignition Delay ◽  
Chemical Kinetic ◽  
Parameter Range ◽  
Ignition Delay Times ◽  
Combustion Properties ◽  
Delay Times

In response to the limited resources of fossil fuels as well as to their combustion contributing to global warming through CO2 emissions, it is currently discussed to which extent future energy demands can be satisfied by using biomass and biogenic by-products, e.g., by cofiring. However, new concepts and new unconventional fuels for electric power generation require a re-investigation of at least the gas turbine burner if not the gas turbine itself to ensure a safe operation and a maximum range in tolerating fuel variations and combustion conditions. Within this context, alcohols, in particular, ethanol, are of high interest as alternative fuel. Presently, the use of ethanol for power generation—in decentralized (microgas turbines) or centralized gas turbine units, neat, or cofired with gaseous fuels like natural gas (NG) and biogas—is discussed. Chemical kinetic modeling has become an important tool for interpreting and understanding the combustion phenomena observed, for example, focusing on heat release (burning velocities) and reactivity (ignition delay times). Furthermore, a chemical kinetic reaction model validated by relevant experiments performed within a large parameter range allows a more sophisticated computer assisted design of burners as well as of combustion chambers, when used within computational fluid dynamics (CFD) codes. Therefore, a detailed experimental and modeling study of ethanol cofiring to NG will be presented focusing on two major combustion properties within a relevant parameter range: (i) ignition delay times measured in a shock tube device, at ambient (p = 1 bar) and elevated (p = 4 bar) pressures, for lean (φ = 0.5) and stoichiometric fuel–air mixtures, and (ii) laminar flame speed data at several preheat temperatures, also for ambient and elevated pressure, gathered from literature. Chemical kinetic modeling will be used for an in-depth characterization of ignition delays and flame speeds at technical relevant conditions. An extensive database will be presented identifying the characteristic differences of the combustion properties of NG, ethanol, and ethanol cofired to NG.

Sign in / Sign up

Export Citation Format

Share Document