scholarly journals Hastelloy® N for Molten Salt Reactors Used for Power Generation

Author(s):  
Robert W. Swindeman ◽  
Weiju Ren ◽  
Michael Katcher ◽  
David E. Holcomb

Hastelloy® N alloy was developed in the 1950’s as ‘INOR 8’ by the Oak Ridge National Laboratory to resist molten salts used as a fuel and coolant in the early development of molten salt nuclear reactors for propulsion and power generation. China has recently expressed interest in Hastelloy N for use in prototype and demonstration components for a high-temperature, uranium-fueled, molten-salt cooled reactor for the production of electricity. An ASME Section III NH Code Case will be necessary to move Alloy N forward commercially. This paper discusses the guidelines for design data requirements necessary to satisfy the Boiler Code for elevated temperature nuclear applications where creep effects are significant. The historic tensile and creep properties data for Alloy N (N10003) were collected and re-analyzed in accordance with current ASME procedures. The collected data will be uploaded into the ASME Materials Properties Database to support the NH Code Case development. Paper published with permission.

Author(s):  
Virginie Vaubert ◽  
David P. Stinton ◽  
Chris Barra ◽  
Santosh Limaye

Advanced, coal-fueled, power generation systems utilizing pressurized fluidized bed combustion (PFBC) and integrated gasification combined cycle (IGCC) technologies are currently being developed for high-efficiency, low emissions, and low-cost power generation. In spite of the advantages of these promising technologies, the severe operating environment often leads to material degradation and loss of performance in the barrier filters used for particle entrapment. To address this problem, LoTEC Inc., and Oak Ridge National Laboratory are jointly designing and developing a monolithic cross-flow ceramic hot-gas filter. The filter concept involves a truly monolithic cross-flow design that is resistant to delamination, can be easily fabricated, and offers flexibility of geometry and material make-up. During Phase I of the program, a thermo-mechanical analysis was performed to determine how a cross-flow filter would respond both thermally and mechanically to a series of thermal and mechanical loads. The cross-flow filter mold was designed accordingly, and the materials selection was narrowed down to Ca0.5Sr0.5Zr4P6O24 (CS-50) and 2Al2O3−3SiO2 (mullite). A fabrication process was developed using gelcasting technology and monolithic cross-flow filters were fabricated. The program focuses on obtaining optimum filter permeability and testing the corrosion resistance of the candidate materials.


2019 ◽  
Vol 6 (1) ◽  
Author(s):  
T. J. Price ◽  
O. Chvala

Abstract This paper presents a review of xenon analyses literature related to molten salt reactors (MSRs). A brief primer of reactor xenon theory is presented for fluid fueled reactors. A review of xenon analysis literature is presented for both the work done by the Oak Ridge National Laboratory, and the later work in academia. A review of experimental work is presented. The paper concludes with describing some of the difficulties in establishing a priori xenon models and includes a commentary on the sensitive dependence of the molten salt reactor xenon behavior on the circulating void fraction.


Author(s):  
Brian C. Kelleher ◽  
Kieran P. Dolan ◽  
Paul Brooks ◽  
Mark H. Anderson ◽  
Kumar Sridharan

Li 2 BeF 4 , or flibe, is the primary candidate coolant for the fluoride-salt-cooled high-temperature nuclear reactor (FHR). Kilogram quantities of pure flibe are required for repeatable corrosion tests of modern reactor materials. This paper details fluoride salt purification by the hydrofluorination–hydrogen process, which was used to regenerate 57.4 kg of flibe originating from the secondary loop of the molten salt reactor experiment (MSRE) at Oak Ridge National Laboratory (ORNL). Additionally, it expounds upon necessary handling precautions required to produce high-quality flibe and includes technological advancements which ease the purification and analysis process. Flibe batches produced at the University of Wisconsin are the largest since the MSRE program, enabling new corrosion, radiation, and thermal hydraulic testing around the United States.


Author(s):  
Adrian S. Sabau ◽  
Wallace D. Porter ◽  
Shibayan Roy ◽  
Amit Shyam

To accelerate the introduction of new materials and components, the development of metal casting processes requires the teaming between different disciplines, as multi-physical phenomena have to be considered simultaneously for the process design and optimization for mechanical properties. The required models for physical phenomena as well as their validation status for metal casting are reviewed. The data on materials properties, model validation, and relevant microstructure for materials properties are highlighted. One vehicle to accelerate the development of new materials is through combined experimental-computational efforts. Integrated computational/experimental practices are reviewed; strengths and weaknesses are identified with respect to metal casting processes. Specifically, the examples are given for the knowledge base established at Oak Ridge National Laboratory and computer models for predicting casting defects and microstructure distribution in aluminum alloy components.


Author(s):  
A. Cammi ◽  
V. Di Marcello ◽  
C. Guerrieri ◽  
L. Luzzi

In this paper, the zero-power behavior of circulating fuel reactors (CFRs) has been investigated by means of a zero-dimensional neutron kinetics model that provides a simplified but useful approach to the simulation of the dynamics of this class of nuclear reactors. Among CFRs, the most promising is the molten salt reactor (MSR), which is one of the six innovative concepts of reactor proposed by the “Generation IV International Forum” for future nuclear energy supply. One of the key features of CFRs is represented by the fission material, which is dissolved in a liquid mixture that serves both as fuel and coolant. This causes a relevant coupling between neutronics and thermo-hydrodynamics, so that fuel velocity plays a relevant role in determining the dynamic performance of such systems. In the present study, a preliminary model has been developed that is based on the zero-power kinetics equations (i.e., reactivity feedbacks due to temperature change are neglected), modified in order to take into account the effects of the molten salt circulation on the drift of delayed neutron precursors. The system dynamic behavior has been analyzed using the theory of linear systems, and the transfer functions of the neutron density with respect to both reactivity and fuel velocity have been calculated. The developed model has been assessed on the basis of the available experimental data from the molten salt reactor experiment (MSRE) provided by the Oak Ridge National Laboratory. The results of the present work show that the developed simplified theoretical model is well descriptive of the MSRE zero-power dynamics, allowing a preliminary evaluation of the effects due to the circulation of the fuel salt on the neutronics of the system. Moreover, the model is of general validity for any kind of CFRs, and hence is applicable to study other MSR concepts in order to have some indications on the control strategy to be adopted in the MSR development envisaged by Generation IV.


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