Characterizing Performance of a PEM Fuel Cell for a CMET Balloon

2011 ◽  
Author(s):  
Denise A. McKahn ◽  
Whitney McMackin
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Mass Density ◽  
Pem Fuel Cell ◽  
Pem Fuel Cells ◽  
Cell Polarization ◽  
Operating Conditions ◽  
Design Parameters ◽  
Design System ◽  
Power Densities

We present the design of a multi-cell, low temperature PEM fuel cell for controlled meteorological balloons. Critical system design parameters that distinguish this application are the lack of reactant humidification and cooling due to the low power production, high required power mass-density and relatively short flight durations. The cell is supplied with a pressure regulated and dead ended anode, and flow controlled cathode at variable air stoichiometry. The cell is not heated and allowed to operate with unregulated temperature. Our prototype cell was capable of achieving power densities of 43 mW/cm2/cell or 5.4 mW/g. The cell polarization performance of large format PEM fuel cell stacks is an order of magnitude greater than for miniature PEM fuel cells. These performance discrepancies are a result of cell design, system architecture, and reactant and thermal management, indicating that there are significant gains to be made in these domains. We then present design modifications intended to enable the miniature PEM fuel cell to achieve power densities of 13 mW/g, indicating that additional performance gains must be made with improvements in operating conditions targeting achievable power densities of standard PEM fuel cells.

scholarly journals Optimal Estimation of Proton Exchange Membrane Fuel Cells Parameter Based on Coyote Optimization Algorithm

2021 ◽  
Vol 11 (5) ◽  
pp. 2052
Author(s):  
Amlak Abaza ◽  
Ragab A. El-Sehiemy ◽  
Karar Mahmoud ◽  
Matti Lehtonen ◽  
Mohamed M. F. Darwish
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Optimization Algorithm ◽  
Distribution Systems ◽  
Proton Exchange Membrane ◽  
Pem Fuel Cell ◽  
Pem Fuel Cells ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Exchange Membrane

In recent years, the penetration of fuel cells in distribution systems is significantly increased worldwide. The fuel cell is considered an electrochemical energy conversion component. It has the ability to convert chemical to electrical energies as well as heat. The proton exchange membrane (PEM) fuel cell uses hydrogen and oxygen as fuel. It is a low-temperature type that uses a noble metal catalyst, such as platinum, at reaction sites. The optimal modeling of PEM fuel cells improves the cell performance in different applications of the smart microgrid. Extracting the optimal parameters of the model can be achieved using an efficient optimization technique. In this line, this paper proposes a novel swarm-based algorithm called coyote optimization algorithm (COA) for finding the optimal parameter of PEM fuel cell as well as PEM stack. The sum of square deviation between measured voltages and the optimal estimated voltages obtained from the COA algorithm is minimized. Two practical PEM fuel cells including 250 W stack and Ned Stack PS6 are modeled to validate the capability of the proposed algorithm under different operating conditions. The effectiveness of the proposed COA is demonstrated through the comparison with four optimizers considering the same conditions. The final estimated results and statistical analysis show a significant accuracy of the proposed method. These results emphasize the ability of COA to estimate the parameters of the PEM fuel cell model more precisely.

Analysis and Optimization of Transient Response of Polymer Electrolyte Fuel Cells

2015 ◽  
Vol 12 (1) ◽  
Author(s):  
A. Verma ◽  
R. Pitchumani
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Polymer Electrolyte ◽  
Transient Response ◽  
Single Channel ◽  
Rapid Change ◽  
Pem Fuel Cell ◽  
Pem Fuel Cells ◽  
Operating Parameters ◽  
Automotive Applications

Polymer electrolyte membrane (PEM) fuel cells are well suited for automotive applications compared to other types of fuel cells owing to their faster transient response and low-temperature operation. Due to rapid change in loads during automotive applications, study of dynamic behavior is of paramount importance. This study focuses on elucidating the transient response of a PEM fuel cell for specified changes in operating parameters, namely, voltage, pressure, and stoichiometry at the cathode and the anode. Transient numerical simulations are carried out for a single-channel PEM fuel cell to illustrate the response of power as the operating parameters are subjected to specified changes. These parameters are also optimized with an objective to match the power requirements of an automotive drive cycle over a certain period of time.

Artificial Neural Network Modeling of PEM Fuel Cells

2005 ◽  
Vol 2 (4) ◽  
pp. 226-233 ◽  
Author(s):  
Shaoduan Ou ◽  
Luke E. K. Achenie
Keyword(s):  
Neural Network ◽  
Artificial Neural Network ◽  
Fuel Cells ◽  
Fuel Cell ◽  
Back Propagation ◽  
Pem Fuel Cell ◽  
Pem Fuel Cells ◽  
Optimal Operating ◽  
Cell Systems ◽  
Artificial Neural

Artificial neural network (ANN) approaches for modeling of proton exchange membrane (PEM) fuel cells have been investigated in this study. This type of data-driven approach is capable of inferring functional relationships among process variables (i.e., cell voltage, current density, feed concentration, airflow rate, etc.) in fuel cell systems. In our simulations, ANN models have shown to be accurate for modeling of fuel cell systems. Specifically, different approaches for ANN, including back-propagation feed-forward networks, and radial basis function networks, were considered. The back-propagation approach with the momentum term gave the best results. A study on the effect of Pt loading on the performance of a PEM fuel cell was conducted, and the simulated results show good agreement with the experimental data. Using the ANN model, an optimization model for determining optimal operating points of a PEM fuel cell has been developed. Results show the ability of the optimizer to capture the optimal operating point. The overall goal is to improve fuel cell system performance through numerical simulations and minimize the trial and error associated with laboratory experiments.

PEM Fuel Cell Research Direction for Automotive Application

2005 ◽  
Author(s):  
John Fagley ◽  
Jason Conley ◽  
David Masten
Keyword(s):  
Fuel Cell ◽  
Pem Fuel Cell ◽  
Pem Fuel Cells ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Department Of Energy ◽  
Limiting Current ◽  
Automotive Application ◽  
Commercial Application ◽  
Related Research

In recent years, there has been an increasing amount of PEM (proton exchange membrane) fuel cell-related research conducted and subsequently published by universities and public institutions. While a good deal of this research has been useful for understanding the underlying fundamental aspects of fuel cell components and operation, much of it is not as useful for a group working on automotive applications as it could be. The reason for this is that in order to be put to practical use in an automotive application, the system being studied must meet certain constraints; satisfying targets for projected system costs, system efficiency, volumetric and gravimetric power densities (packaging), and operating conditions. For example, numerous recent publications show studies with PEM fuel cells designed and built such that limiting current density is achieved at 0.9 A/cm2 or lower, and voltages of 600 mV can only be achieved at current densities less than 0.6 A/cm2. This type of performance is sufficiently below what is required for commercial application, that any conclusions drawn from these works are difficult to extrapolate to a system of commercial automotive interest. The purpose of this article is to show, through use of engineering calculations and cost projections, what operating conditions and performance are required in a commercial automotive fuel cell application. In addition, best known (public domain) performance and corresponding conditions are given, along with Department of Energy Freedom Car targets, which can be used for state-of-the-art benchmarking. Also, reference is made to a university publication where performance (500 mV at 1.5 A/cm2) close to automotive application targets was achieved, and important aspects of their components and flow field geometry are highlighted. It is our hope that through this publication, further PEM fuel-cell related research can be directed toward the region of greatest interest for commercial, automotive application.

scholarly journals Effects of hydrogen relative humidity on the performance of an air-breathing PEM fuel cell

2019 ◽  
Vol 30 (4) ◽  
pp. 2077-2097 ◽  
Author(s):  
Zhenxiao Chen ◽  
Derek Ingham ◽  
Mohammed Ismail ◽  
Lin Ma ◽  
Kevin J. Hughes ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Heat Transfer Coefficient ◽  
Fuel Cells ◽  
Fuel Cell ◽  
Relative Humidity ◽  
Pem Fuel Cell ◽  
Pem Fuel Cells ◽  
Air Breathing ◽  
Content Type ◽  
The Heat Transfer Coefficient

Purpose The purpose of this paper is to investigate the effects of hydrogen humidity on the performance of air-breathing proton exchange membrane (PEM) fuel cells. Design/methodology/approach An efficient mathematical model for air-breathing PEM fuel cells has been built in MATLAB. The sensitivity of the fuel cell performance to the heat transfer coefficient is investigated first. The effect of hydrogen humidity is also studied. In addition, under different hydrogen humidities, the most appropriate thickness of the gas diffusion layer (GDL) is investigated. Findings The heat transfer coefficient dictates the performance limiting mode of the air-breathing PEM fuel cell, the modelled air-breathing fuel cell is limited by the dry-out of the membrane at high current densities. The performance of the fuel cell is mainly influenced by the hydrogen humidity. Besides, an optimal cathode GDL and relatively thinner anode GDL are favoured to achieve a good performance of the fuel cell. Practical implications The current study improves the understanding of the effect of the hydrogen humidity in air-breathing fuel cells and this new model can be used to investigate different component properties in real designs. Originality/value The hydrogen relative humidity and the GDL thickness can be controlled to improve the performance of air-breathing fuel cells.

Optimization of the Operating Parameters of a Proton Exchange Membrane Fuel Cell for Maximum Power Density

2005 ◽  
Vol 2 (2) ◽  
pp. 121-135 ◽  
Author(s):  
A. Mawardi ◽  
F. Yang ◽  
R. Pitchumani
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Power Density ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Operating Conditions ◽  
Optimum Operating ◽  
Design Parameters ◽  
Membrane Thickness ◽  
Exchange Membrane

The performance of fuel cells can be significantly improved by using optimum operating conditions that maximize the power density subject to constraints. Despite its significance, relatively scant work is reported in the open literature on the model-assisted optimization of fuel cells. In this paper, a methodology for model-based optimization is presented by considering a one-dimensional nonisothermal description of a fuel cell operating on reformate feed. The numerical model is coupled with a continuous search simulated annealing optimization scheme to determine the optimum solutions for selected process constraints. Optimization results are presented over a range of fuel cell design parameters to assess the effects of membrane thickness, electrode thickness, constraint values, and CO concentration on the optimum operating conditions.

Alloys that form conductive and passivating oxides for proton exchange membrane fuel cell bipolar plates

2004 ◽  
Vol 19 (6) ◽  
pp. 1723-1729 ◽  
Author(s):  
Neil Aukland ◽  
Abdellah Boudina ◽  
David S. Eddy ◽  
Joseph V. Mantese ◽  
Margarita P. Thompson ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Proton Exchange Membrane ◽  
Oxide Films ◽  
Pem Fuel Cell ◽  
Pem Fuel Cells ◽  
Proton Exchange ◽  
Bipolar Plates ◽  
Concentrated Solutions ◽  
Exchange Membrane

During the operation of proton exchange membrane (PEM) fuel cells, a high-resistance oxide is often formed on the cathode surface of base metal bipolar plates. Over time, this corrosion mechanism leads to a drop in fuel cell efficiency and potentially to complete failure. To address this problem, we have developed alloys capable of forming oxides that are both conductive and chemically stable under PEM fuel cell operating conditions. Five alloys of titanium with tantalum or niobium were investigated. The oxides were formed on the alloys by cyclic voltammetry in solutions mimicking the cathode- and anode-side environment of a PEM fuel cell. The oxides of all tested alloys had lower surface resistance than the oxide of pure titanium. We also investigated the chemical durability of Ti–Nb and Ti–Ta alloys in more concentrated solutions beyond those typically found in PEM fuel cells. The oxide films formed on Ti–Nb and Ti–Ta alloys remained conductive and chemically stable in these concentrated solutions. The stability of the oxide films was evaluated; Ti alloys having 3% Ta and Nb were identified as potential candidates for bipolar plate materials.

scholarly journals Transparent PEM Fuel Cells for Direct Visualisation Experiments

2009 ◽  
Author(s):  
M. I. Rosli ◽  
M. Pourkashanian ◽  
D. B. Ingham ◽  
L. Ma ◽  
D. Borman ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Pem Fuel Cell ◽  
Pem Fuel Cells ◽  
Field Pattern ◽  
Cell Design ◽  
Serpentine Flow Field ◽  
Initial Work ◽  
Water Behavior ◽  
Visual Results

This paper reviews some of the previous research works on direct visualisation inside PEM fuel cells via a transparent single cell for the water behaviour investigation. Several papers which have employed the method have been selected and summarised and a comparison between the design of the cell, materials, methods and visual results are presented. The important aspects, advantages of the method and a summary on the previous work are discussed. Some initial work on transparent PEM fuel cell design using a single serpentine flow-field pattern is described. The results show that the direct visualisation via transparent PEM fuel cells could be one potential technique for investigating the water behavior inside the channels and a very promising way forward to provide useful data for validation in PEM fuel cell modelling and simulation.

Effects of Operating Parameters and Loading Modes on the Dynamic Cell Performance of PEM Fuel Cells

2012 ◽  
Vol 532-533 ◽  
pp. 135-139
Author(s):  
Han Chieh Chiu ◽  
Jer Huan Jang ◽  
Wei Mon Yan ◽  
Chun I Lee ◽  
Chang Chung Yang
Keyword(s):  
Fuel Cell ◽  
Pem Fuel Cell ◽  
Pem Fuel Cells ◽  
Operating Conditions ◽  
Cell Performance ◽  
Optimal Conditions ◽  
Cell Temperature ◽  
Dynamic Loadings ◽  
Dynamic Cell ◽  
Loading Modes

This paper experimentally investigates the dynamic response of a single fuel cell under various dynamic loadings with different operating conditions. Three kinds of loadings are applied to the PEM fuel cell and they are simulated NEDC mode, simulated 10/15 mode, and modified mode. The operating conditions are set at different cell temperatures, humidification temperatures, and stoichiometric rates during each test to study the effects of these parameters on the cell performance of a PEM fuel cell. The cell performance is found increased with increasing cell temperature in the range of 45-65°C. On the other hand, there exist optimal conditions for the humidification temperature and the stoichiometric rate at 70°C/60°C and 1.5/2.0 on the anode and cathode sides, respectively.

scholarly journals Experimental characterization of a PEM fuel cell for marine power generation

2022 ◽  
Vol 334 ◽  
pp. 05002
Author(s):  
Andrea Pietra ◽  
Marco Gianni ◽  
Nicola Zuliani ◽  
Stefano Malabotti ◽  
Rodolfo Taccani
Keyword(s):  
Power Generation ◽  
Fuel Cells ◽  
Energy Storage ◽  
Fuel Cell ◽  
Storage System ◽  
Pem Fuel Cell ◽  
Energy Storage System ◽  
Pem Fuel Cells ◽  
Power Converter ◽  
Plant Design

This study is focused on the possible application of hydrogen-fed PEM fuel cells on board ships. For this purpose, a test plant including a 100 kW generator suitable for marine application and a power converter including a supercapacitor-based energy storage system has been designed, built and experimentally characterised. The plant design integrates standard industrial components suitable for marine applications that include the technologies with the highest degree of maturity currently available on the market. Fuel Cell generator and power converter have been specifically designed by manufacturers to fit the specific plant needs. The experimental characterisation of the plant has been focused on the evaluation of the efficiency of the single components and of the overall system. Results shows a PEM fuel cell efficiency of 48% (when all auxiliaries are included) and an overall plant efficiency, including power conditioning, of about 45%. From load variation response tests, the fuel cell response time was maximum 2 seconds without supercapacitors and increased up to 20 seconds with supercapacitors connected, reducing the stress on the fuel cell generator. Experimental results confirm that PEM fuel cells, when supported by a suitably sized energy storage system, represent a viable technical solution for zero-emission power generation on board ships.

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