Lean Blowout Limit and NOx-Production of a Premixed Sub-ppm NOx Burner With Periodic Flue Gas Recirculation

2004 ◽  
Author(s):  
Jochen R. Kalb ◽  
Thomas Sattelmayer
Keyword(s):  
Natural Gas ◽  
Flue Gas ◽  
Gas Content ◽  
Stable Operation ◽  
Reacting Flow ◽  
Nox Emissions ◽  
Lean Blowout ◽  
Fresh Mixture ◽  
Flue Gas Recirculation ◽  
Gas Recirculation

The technological objective of this work is the development of a lean-premixed burner for natural gas. Sub-ppm NOx emissions can be accomplished by shifting the lean blowout limit (LBO) to slightly lower adiabatic flame temperatures than the LBO of current standard burners. This can be achieved with a novel burner concept utilizing periodic flue gas recirculation: Hot flue gas is admixed to the injected premixed fresh mixture with a mass flow rate of comparable magnitude, in order to achieve self-ignition. The subsequent combustion of the diluted mixture again delivers flue gas. A fraction of the combustion products is then admixed to the next stream of fresh mixture. This process pattern is to be continued in a cyclically closed topology, in order to achieve stable combustion of e.g. natural gas in a temperature regime of very low NOx production. The principal ignition behavior and NOx production characteristics of one sequence of the periodic process was modeled by an idealized adiabatic system with instantaneous admixture of partially or completely burnt flue gas to one stream of fresh reactants. With the CHEMKIN-II package a reactor network consisting of one perfectly stirred reactor (PSR, providing ignition in the first place) and two plug flow reactors (PFR) has been used. The effect of varying burnout and the influence of the fraction of admixed flue gas have been evaluated. The simulations have been conducted with the reaction mechanism of Miller and Bowman and the GRI-Mech 3.0 mechanism. The results show that the high radical content of partially combusted products leads to a massive decrease of the time required for the formation of the radical pool. As a consequence, self-ignition times of 1 ms are achieved even at adiabatic flame temperatures of 1600 K and less, if the flue gas content is about 50%–60% of the reacting flow after mixing is complete. Interestingly, the effect of radicals on ignition is strong, outweighs the temperature deficiency and thus allows stable operation at very low NOx emissions.

Lean Blowout Limit and NOx Production of a Premixed Sub-ppm NOx Burner With Periodic Recirculation of Combustion Products

2004 ◽  
Vol 128 (2) ◽  
pp. 247-254 ◽  
Author(s):  
Jochen R. Kalb ◽  
Thomas Sattelmayer
Keyword(s):  
Natural Gas ◽  
Flue Gas ◽  
Combustion Products ◽  
Gas Content ◽  
Stable Operation ◽  
Reacting Flow ◽  
Nox Emissions ◽  
Current Standard ◽  
Lean Blowout ◽  
Fresh Mixture

The technological objective of this work is the development of a lean-premixed burner for natural gas. Sub-ppm NOx emissions can be accomplished by shifting the lean blowout limit (LBO) to slightly lower adiabatic flame temperatures than the LBO of current standard burners. This can be achieved with a novel burner concept utilizing spatially periodic recirculation of combustion products: Hot combustion products are admixed to the injected premixed fresh mixture with a mass flow rate of comparable magnitude, in order to achieve self-ignition. The subsequent combustion of the diluted mixture again delivers products. A fraction of these combustion products is then admixed to the next stream of fresh mixture. This process pattern is to be continued in a cyclically closed topology, in order to achieve stable combustion of, for example, natural gas in a temperature regime of very low NOx production. The principal ignition behavior and NOx production characteristics of one sequence of the periodic process was modeled by an idealized adiabatic system with instantaneous admixture of partially or completely burnt combustion products to one stream of fresh reactants. With the CHEMKIN-II package, a reactor network consisting of one perfectly stirred reactor (PSR, providing ignition in the first place) and two plug flow reactors (PFR) has been used. The effect of varying burnout and the influence of the fraction of admixed flue gas has been evaluated. The simulations have been conducted with the reaction mechanism of Miller and Bowman and the GRI-Mech 3.0 mechanism. The results show that the high radical content of partially combusted products leads to a massive decrease of the time required for the formation of the radical pool. As a consequence, self-ignition times of 1 ms are achieved even at adiabatic flame temperatures of 1600 K and less, if the flue gas content is about 50–60% of the reacting flow after mixing is complete. Interestingly, the effect of radicals on ignition is strong, outweighs the temperature deficiency and thus allows stable operation at very low NOx emissions.

Effects of Flue Gas Recirculation on NOx Emissions from Gas-Fired Utility Boilers

2021 ◽  
pp. 319-337
Author(s):  
Nikola Tanasić ◽  
Mirjana Stamenić ◽  
Vladimir Tanasić
Keyword(s):  
Flue Gas ◽  
Nox Emissions ◽  
Flue Gas Recirculation ◽  
Utility Boilers ◽  
Gas Recirculation

On the Influence of Fuel Mixing and Flue Gas Recirculation on the Emissions of a Fuel Flexible Gas Turbine Combustor

2015 ◽  
Author(s):  
Stefan Fischer ◽  
David Kluß ◽  
Franz Joos
Keyword(s):  
Nitric Oxide ◽  
Flue Gas ◽  
Nox Emissions ◽  
Combined Effects ◽  
Fuel Gas ◽  
Flue Gas Recirculation ◽  
Mixing Behavior ◽  
Nitric Oxide Emissions ◽  
Fuel Mixing ◽  
Gas Recirculation

The main benefits of operating a combustor under flue gas recirculation conditions are the increase in efficiency of the post combustion carbon capture and storage process and the potential to reduce NOX emissions while keeping the thermal load of the gas turbine constant. The latter is primarily caused by the change in thermodynamic properties of the combustive mixture with increasing vitiation. As a result, the dominant NOX formation pathways change with increasing FGR ratio. In a partially premixed combustor, the formation of NOX emissions can also be influenced by the fuel mixing behavior. Different setups lead to combustive mixtures with different degrees of homogeneity as well as influencing the distribution of the mixture within the combustion chamber. In this paper the combined effects of the variation of mixture homogeneity and the flue gas recirculation ratio on the NOX emissions and the stability range is experimentally investigated for different fuel gases. The experiments are performed on the atmospheric laboratory test rig, which is equipped with a partially premixed combustor. The burner is equipped with modular fuel gas nozzles allowing for the variation of the fuel mixing behavior. Exhaust gas measurements are performed to evaluate the influence of the parameters on the emissions profile of the combustor and to compare the results to a theoretical study. The results of this study show that the level of nitric oxide emissions as well as the potential to decrease said emissions with FGR operation is dependent on the mixing behavior of the combustor. Furthermore, the combined effects of fuel gas nozzle and FGR operation lead to a proposal of an operational strategy for the combustor which combines the advantages of low nitric oxide emissions and a broad range of stability.

scholarly journals The Effects of Coke Parameters and Circulating Flue Gas Characteristics on NOx Emission during Flue Gas Recirculation Sintering Process

Energies ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3828 ◽  
Author(s):  
Juntao Han ◽  
Guofeng Lou ◽  
Sizong Zhang ◽  
Zhi Wen ◽  
Xunliang Liu ◽  
...  
Keyword(s):  
Flue Gas ◽  
Coke Consumption ◽  
Reduction Rate ◽  
Combustion Efficiency ◽  
Nox Emission ◽  
Nox Emissions ◽  
Content Increase ◽  
Gas Treatment ◽  
Flue Gas Recirculation ◽  
Gas Recirculation

The new process of flue gas recirculation, which reduces coke consumption and reducing NOx emissions, is now extensively used. Compared with traditional sintering, the characteristics of circulating flue gas and coke parameters significantly affect the combustion atmosphere and coke combustion efficiency. Based on the actual complex process of sintering machine, this study proposes a relatively comprehensive one-dimensional, unsteady mathematical model for flue gas recirculation research. The model encompasses NOx pollutant generation and reduction, as well as SO2 generation and adsorption. We focus on the effects of cyclic flue gas characteristics on the sintering-bed temperature and NOx emissions, which are rarely studied, and provide a theoretical basis for NOx emission reduction. Simulation results show that during sintering, the fuel NOx is reduced by 50% and 10% when passing through the surface of coke particles and CO, respectively. During flue gas recirculation sintering, the increase in circulating gas O2 content, temperature, and supply-gas volume cause increased combustion efficiency of coke, reducing atmosphere, and NOx content in the circulating area; the temperature of the material layer also increases significantly and the sintering endpoint advances. During cyclic sintering, the small coke size and increased coke content increase the char-N release rate while promoting sufficient contact of NOx with the coke surface. Consequently, the NOx reduction rate increases. Compared with the conventional sintering, the designed flue gas recirculation condition saves 3.75% of coke consumption, i.e., for 1.2 kg of solid fuel per ton of sinter, the amount of flue gas treatment is reduced by 21.64% and NOx emissions is reduced by 23.59%. Moreover, without changing the existing sintering equipment, sintering capacity increases by about 5.56%.

scholarly journals Combustion Characteristics of 0.5 MW Class Oxy-Fuel FGR (Flue Gas Recirculation) Boiler for CO2 Capture

Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4333
Author(s):  
Joon Ahn ◽  
Hyouck-Ju Kim
Keyword(s):  
Natural Gas ◽  
Flue Gas ◽  
Power Plants ◽  
Fuel Combustion ◽  
Upstream Region ◽  
Exhaust Gas ◽  
Flue Gas Recirculation ◽  
Partial Load ◽  
Industrial Boilers ◽  
Gas Recirculation

A 0.5 MW class oxy-fuel boiler was developed to capture CO2 from exhaust gas. We adopted natural gas as the fuel for industrial boilers and identified characteristics different from those of pulverized coal, which has been studied for power plants. We also examined oxy-fuel combustion without flue gas recirculation (FGR), which is not commonly adopted in power plant boilers. Oxy-fuel combustion involves a stretched flame that uniformly heats the combustion chamber. In oxy-natural-gas FGR combustion, water vapor was included in the recirculated gas and the flame was stabilized when the oxygen concentration of the oxidizer was 32% or more. While flame delay was observed at a partial load for oxy-natural-gas FGR combustion, it was not observed for other combustion modes. In oxy-fuel combustion, the flow rate and flame fullness decrease but, except for the upstream region, the temperature near the wall is distributed not lower than that for air combustion because of the effect of gas radiation. For this combustion, while the heat flux is lower than other modes in the upstream region, it is more than 60% larger in the downstream region. When oxy-fuel and FGR combustion were employed in industrial boilers, more than 90% of CO2 was obtained, enabling capture, sequestration, and boiler performance while satisfying exhaust gas regulations.

Experimental Investigation of a Fuel Flexible Generic Gas Turbine Combustor With External Flue Gas Recirculation

2014 ◽  
Author(s):  
Stefan Fischer ◽  
David Kluß ◽  
Franz Joos
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Flue Gas ◽  
Power Plants ◽  
Numerical Study ◽  
Combined Cycle ◽  
Gas Turbine Combustor ◽  
Combustion Behavior ◽  
Flue Gas Recirculation ◽  
Gas Recirculation

Flue gas recirculation in combined cycle power plants using hydrocarbon fuels is a promising technology for increasing the efficiency of the post combustion carbon capture and storage process. However, the operation with flue gas recirculation significantly changes the combustion behavior within the gas turbine. In this paper the effects of external flue gas recirculation on the combustion behavior of a generic gas turbine combustor was experimentally investigated. While prior studies have been performed with natural gas, the focus of this paper lies on the investigation of the combustion behavior of alternative fuel gases at atmospheric conditions, namely typical biogas mixtures and syngas. The flue gas recirculation ratio and the fuel mass flow were varied to establish the operating region of stable flammability. In addition to the experimental investigations, a numerical study of the combustive reactivity under flue gas recirculation conditions was performed. Finally, a prediction of blowout limits was performed using a perfectly stirred reactor approach and the experimental natural gas lean extinction data as a reference. The extinction limits under normal (non-vitiated) and flue gas recirculation conditions can be predicted well for all the fuels investigated.

scholarly journals Numerical Analysis of Turbulent Combustion in a Model Swirl Gas Turbine Combustor

2016 ◽  
Vol 2016 ◽  
pp. 1-12 ◽  
Author(s):  
Ali Cemal Benim ◽  
Sohail Iqbal ◽  
Franz Joos ◽  
Alexander Wiedermann
Keyword(s):  
Experimental Data ◽  
Natural Gas ◽  
Gas Turbine ◽  
Turbulence Model ◽  
Flue Gas ◽  
Numerical Study ◽  
Mixture Fraction ◽  
Gas Turbine Combustor ◽  
Flue Gas Recirculation ◽  
Gas Recirculation

Turbulent reacting flows in a generic swirl gas turbine combustor are investigated numerically. Turbulence is modelled by a URANS formulation in combination with the SST turbulence model, as the basic modelling approach. For comparison, URANS is applied also in combination with the RSM turbulence model to one of the investigated cases. For this case, LES is also used for turbulence modelling. For modelling turbulence-chemistry interaction, a laminar flamelet model is used, which is based on the mixture fraction and the reaction progress variable. This model is implemented in the open source CFD code OpenFOAM, which has been used as the basis for the present investigation. For validation purposes, predictions are compared with the measurements for a natural gas flame with external flue gas recirculation. A good agreement with the experimental data is observed. Subsequently, the numerical study is extended to syngas, for comparing its combustion behavior with that of natural gas. Here, the analysis is carried out for cases without external flue gas recirculation. The computational model is observed to provide a fair prediction of the experimental data and predict the increased flashback propensity of syngas.

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