scholarly journals Combustion Characteristics of 0.5 MW Class Oxy-Fuel FGR (Flue Gas Recirculation) Boiler for CO2 Capture

Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4333
Author(s):  
Joon Ahn ◽  
Hyouck-Ju Kim

A 0.5 MW class oxy-fuel boiler was developed to capture CO2 from exhaust gas. We adopted natural gas as the fuel for industrial boilers and identified characteristics different from those of pulverized coal, which has been studied for power plants. We also examined oxy-fuel combustion without flue gas recirculation (FGR), which is not commonly adopted in power plant boilers. Oxy-fuel combustion involves a stretched flame that uniformly heats the combustion chamber. In oxy-natural-gas FGR combustion, water vapor was included in the recirculated gas and the flame was stabilized when the oxygen concentration of the oxidizer was 32% or more. While flame delay was observed at a partial load for oxy-natural-gas FGR combustion, it was not observed for other combustion modes. In oxy-fuel combustion, the flow rate and flame fullness decrease but, except for the upstream region, the temperature near the wall is distributed not lower than that for air combustion because of the effect of gas radiation. For this combustion, while the heat flux is lower than other modes in the upstream region, it is more than 60% larger in the downstream region. When oxy-fuel and FGR combustion were employed in industrial boilers, more than 90% of CO2 was obtained, enabling capture, sequestration, and boiler performance while satisfying exhaust gas regulations.

Author(s):  
Maria Elena Diego ◽  
Jean-Michel Bellas ◽  
Mohamed Pourkashanian

Post-combustion CO2 capture from natural gas combined cycle (NGCC) power plants is challenging due to the large flow of flue gas with low CO2 content (∼3–4%vol.) that needs to be processed in the capture stage. A number of alternatives have been proposed to solve this issue and reduce the costs of the associated CO2 capture plant. This work focuses on the selective exhaust gas recirculation (S-EGR) configuration, which uses a membrane to selectively recirculate CO2 back to the inlet of the compressor of the turbine, thereby greatly increasing the CO2 content of the flue gas sent to the capture system. For this purpose, a parallel S-EGR NGCC system (53% S-EGR ratio) coupled to an amine capture plant using MEA 30%wt. was simulated using gCCS (gPROMS). It was benchmarked against an unabated NGCC system, a conventional NGCC coupled with an amine capture plant (NGCC+CCS), and an EGR NGCC power plant (39% EGR ratio) using amine scrubbing as the downstream capture technology. The results obtained indicate that the net power efficiency of the parallel S-EGR system can be up to 49.3% depending on the specific consumption of the auxiliary S-EGR systems, compared to the 49.0% and 49.8% values obtained for the NGCC+CCS and EGR systems, respectively. A preliminary economic study was also carried out to quantify the potential of the parallel S-EGR configuration. This high-level analysis shows that the cost of electricity for the parallel S-EGR system varies from 82.1–90.0 $/MWhe for the scenarios considered, with the cost of CO2 avoided being in the range of 79.7–105.1 $/tonne CO2. The results obtained indicate that there are potential advantages of the parallel S-EGR system in comparison to the NGCC+CCS configuration in some scenarios. However, further benefits with respect to the EGR configuration will depend on future advancements and cost reductions achieved on membrane-based systems.


Author(s):  
Stefan Fischer ◽  
David Kluß ◽  
Franz Joos

Flue gas recirculation in combined cycle power plants using hydrocarbon fuels is a promising technology for increasing the efficiency of the post combustion carbon capture and storage process. However, the operation with flue gas recirculation significantly changes the combustion behavior within the gas turbine. In this paper the effects of external flue gas recirculation on the combustion behavior of a generic gas turbine combustor was experimentally investigated. While prior studies have been performed with natural gas, the focus of this paper lies on the investigation of the combustion behavior of alternative fuel gases at atmospheric conditions, namely typical biogas mixtures and syngas. The flue gas recirculation ratio and the fuel mass flow were varied to establish the operating region of stable flammability. In addition to the experimental investigations, a numerical study of the combustive reactivity under flue gas recirculation conditions was performed. Finally, a prediction of blowout limits was performed using a perfectly stirred reactor approach and the experimental natural gas lean extinction data as a reference. The extinction limits under normal (non-vitiated) and flue gas recirculation conditions can be predicted well for all the fuels investigated.


Author(s):  
Dieter Winkler ◽  
Simon Reimer ◽  
Pascal Mu¨ller ◽  
Timothy Griffin

The efficiency and economics of carbon dioxide capture in gas turbine combined cycle power plants can be significantly improved by introducing Flue Gas Recirculation (FGR) to increase the CO2 concentration in the flue gas and reduce the volume of the flue gas treated in the CO2 capture plant [1], [2]. The maximum possible level of FGR is limited to that corresponding to stoichiometric conditions in the combustor. Reduced excess oxygen, however, leads to negative effects on overall fuel reactivity and thus increased CO emissions. Combustion tests have been carried out in a generic burner under typical gas turbine conditions with methane, synthetic natural gas (mixtures of methane and ethane) and natural gas from the Swiss net to investigate the effect of different C2+ contents in the fuel on CO burnout. To locate the flame front and to measure emissions for different residence times a traversable gas probe was designed and employed. Increasing the FGR ratio led to lower reactivity indicated by a movement of the flame front downstream. Thus, sufficient flame burnout—indicated by low emissions of unburned components (CO, UHC)—required a longer residence time in the combustion chamber. Adding C2+ or H2 to the fuel moved the flame zone back upstream and reduced the burnout time. Tests were performed for the various fuel compositions at different FGR ratios and oxidant preheat temperatures. For all conditions the addition of ethane (6 and 16% vol.) or hydrogen (20% vol.) to methane shows comparable trends. Addition of hydrogen to (synthetic) natural gas which already contains C2+ has less of a beneficial effect on reactivity and CO burnout than the addition of hydrogen to pure methane. A simple ideal reactor network based on plug flow reactors with internal hot gas recirculation was used to model combustion in the generic combustor. The purpose of such a simple model is to generate a design basis for future tests with varying operating conditions. The model was able to reproduce the trends found in the experimental investigation, for example the level of H2 required to offset the effect of oxygen depletion due to simulated FGR.


Author(s):  
Maria Elena Diego ◽  
Jean-Michel Bellas ◽  
Mohamed Pourkashanian

Postcombustion CO2 capture from natural gas combined cycle (NGCC) power plants is challenging due to the large flow of flue gas with low CO2 content (∼3–4 vol %) that needs to be processed in the capture stage. A number of alternatives have been proposed to solve this issue and reduce the costs of the associated CO2 capture plant. This work focuses on the selective exhaust gas recirculation (S-EGR) configuration, which uses a membrane to selectively recirculate CO2 back to the inlet of the compressor of the turbine, thereby greatly increasing the CO2 content of the flue gas sent to the capture system. For this purpose, a parallel S-EGR NGCC system (53% S-EGR ratio) coupled to an amine capture plant (ACP) using monoethanolamine (MEA) 30 wt % was simulated using gCCS (gPROMS). It was benchmarked against an unabated NGCC system, a conventional NGCC coupled with an ACP (NGCC + carbon capture and storage (CCS)), and an EGR NGCC power plant (39% EGR ratio) using amine scrubbing as the downstream capture technology. The results obtained indicate that the net power efficiency of the parallel S-EGR system can be up to 49.3% depending on the specific consumption of the auxiliary S-EGR systems, compared to the 49.0% and 49.8% values obtained for the NGCC + CCS and EGR systems, respectively. A preliminary economic study was also carried out to quantify the potential of the parallel S-EGR configuration. This high-level analysis shows that the cost of electricity (COE) for the parallel S-EGR system varies from 82.1 to 90.0 $/MWhe for the scenarios considered, with the cost of CO2 avoided (COA) being in the range of 79.7–105.1 $/ton CO2. The results obtained indicate that there are potential advantages of the parallel S-EGR system in comparison to the NGCC + CCS configuration in some scenarios. However, further benefits with respect to the EGR configuration will depend on future advancements and cost reductions achieved on membrane-based systems.


Fuel ◽  
2021 ◽  
Vol 297 ◽  
pp. 120775
Author(s):  
Mohsen Abdelaal ◽  
Medhat El-Riedy ◽  
Ahmed M. El-Nahas ◽  
Fathy R. El-Wahsh

Author(s):  
Jochen R. Kalb ◽  
Thomas Sattelmayer

The technological objective of this work is the development of a lean-premixed burner for natural gas. Sub-ppm NOx emissions can be accomplished by shifting the lean blowout limit (LBO) to slightly lower adiabatic flame temperatures than the LBO of current standard burners. This can be achieved with a novel burner concept utilizing periodic flue gas recirculation: Hot flue gas is admixed to the injected premixed fresh mixture with a mass flow rate of comparable magnitude, in order to achieve self-ignition. The subsequent combustion of the diluted mixture again delivers flue gas. A fraction of the combustion products is then admixed to the next stream of fresh mixture. This process pattern is to be continued in a cyclically closed topology, in order to achieve stable combustion of e.g. natural gas in a temperature regime of very low NOx production. The principal ignition behavior and NOx production characteristics of one sequence of the periodic process was modeled by an idealized adiabatic system with instantaneous admixture of partially or completely burnt flue gas to one stream of fresh reactants. With the CHEMKIN-II package a reactor network consisting of one perfectly stirred reactor (PSR, providing ignition in the first place) and two plug flow reactors (PFR) has been used. The effect of varying burnout and the influence of the fraction of admixed flue gas have been evaluated. The simulations have been conducted with the reaction mechanism of Miller and Bowman and the GRI-Mech 3.0 mechanism. The results show that the high radical content of partially combusted products leads to a massive decrease of the time required for the formation of the radical pool. As a consequence, self-ignition times of 1 ms are achieved even at adiabatic flame temperatures of 1600 K and less, if the flue gas content is about 50%–60% of the reacting flow after mixing is complete. Interestingly, the effect of radicals on ignition is strong, outweighs the temperature deficiency and thus allows stable operation at very low NOx emissions.


Author(s):  
Florian Beenken ◽  
Franz Joos

In near future electrical power generation will still be supplied by fossil fuels. To reach the targets of the conference on climate change in Paris 2015 one method proposed is the CO2 sequestration and usage or alternatively storage. Compared to coal-fired power station the amount of CO2 in the exhaust gas of gas turbine power station is much less and therefore more difficult to remove. To enhance the efficiency of the CO2-sequestration process enrichment of the CO2 in the exhaust gas could be a solution. This can be achieved by exhaust gas recirculation or by burning with pure O2 instead of air avoiding a lot of N2 in the exhaust gas, called Oxyfuel process. The work concerns to investigations of a reheat gas turbine operating with flue gas recirculation as well as with Oxyfuel operation. The thermodynamic process has been modeled in detail considering the additional demand of cooling of the combustors and the turbines at Oxyfuel process. Additional combustion experiments have been carried out with flue gas recirculation as well as with Oxyfuel conditions burning Natural Gas with O2 in a CO2 environment to investigate the flame stability and extinction limit. The thermophysical properties, like specific heat capacity and sound velocity, are strongly altered by the high content of CO2 and H2O in the fluid of the turbine as well as of the compressor. For example during Oxyfuel conditions the pressure ratio is expected to decrease to about 78% of air operation. The influence of flue gas recirculation and Oxyfuel process to the gas composition as well as to the heat transfer and exit conditions are discussed.


Author(s):  
Frank Sander ◽  
Richard Carroni ◽  
Stefan Rofka ◽  
Eribert Benz

The rigorous reduction of greenhouse gas emissions in the upcoming decades is only achievable with contribution from the following strategies: production efficiency, demand reduction of energy and carbon dioxide (CO2) capture from fossil fueled power plants. Since fossil fueled power plants contribute largely to the overall global greenhouse gas emissions (> 25% [1]), it is worthwhile to capture and store the produced CO2 from those power generation processes. For natural-gas-fired power plants, post-combustion CO2 capture is the most mature technology for low emissions power plants. The capture of CO2 is achieved by chemical absorption of CO2 from the exhaust gas of the power plant. Compared to coal fired power plants, an advantage of applying CO2 capture to a natural-gas-fired combined cycle power plant (CCPP) is that the reference cycle (without CO2 capture) achieves a high net efficiency. This far outweighs the drawback of the lower CO2 concentration in the exhaust. Flue Gas Recirculation (FGR) means that flue gas after the HRSG is partially cooled down and then fed back to the GT intake. In this context FGR is beneficial because the concentration of CO2 can be significantly increased, the volumetric flow to the CO2 capture unit will be reduced, and the overall performance of the CCPP with CO2 capture is increased. In this work the impact of FGR on both the Gas Turbine (GT) and the Combined Cycle Power Plant (CCPP) is investigated and analyzed. In addition, the impact of FGR for a CCPP with and without CO2 capture is investigated. The fraction of flue gas that is recirculated back to the GT, need further to be cooled, before it is mixed with ambient air. Sensitivity studies on flue gas recirculation ratio and temperature are conducted. Both parameters affect the GT with respect to change in composition of working fluid, the relative humidity at the compressor inlet, and the impact on overall performance on both GT and CCPP. The conditions at the inlet of the compressor also determine how the GT and water/steam cycle are impacted separately due to FGR. For the combustion system the air/fuel-ratio (AFR) is an important parameter to show the impact of FGR on the combustion process. The AFR indicates how close the combustion process operates to stoichiometric (or technical) limit for complete combustion. The lower the AFR, the closer operates the combustion process to the stoichiometric limit. Furthermore, the impact on existing operational limitations and the operational behavior in general are investigated and discussed in context of an operation concept for a GT with FGR.


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