Advanced Materials for Mercury™ 50 Gas Turbine Combustion System

Author(s):  
Jeffrey Price ◽  
Josh Kimmel ◽  
Xiaoqun Chen ◽  
Arun Bhattacharya ◽  
Anthony Fahme ◽  
...  

Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-00CH 11049, is improving the durability of gas turbine combustion systems while reducing life cycle costs. This project is part of the Advanced Materials in Advanced Industrial Gas Turbines program in DOE’s Office of Distributed Energy. The targeted engine is the Mercury™ 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems (ATS) program (DOE contract number DE-FC21-95MC31173). The ultimate goal of the program is to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for 4,000 hours. The program has focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 turbine and future Solar products. For liner and injector development, multiple concepts including high thermal resistance thermal barrier coatings (TBC), oxide dispersion strengthened (ODS) alloys, continuous fiber ceramic composites (CFCC), and monolithic ceramics were evaluated. An advanced TBC system for the combustor was down-selected for field evaluation. ODS alloys were down-selected for the fuel injector tip application. Preliminary component and sub-scale testing was conducted to determine material properties and demonstrate proof-of-concept. Full-scale rig and engine testing were used to validate engine performance prior to field evaluation. Field evaluation of ceramic matrix composite liners in the Centaur® 50 gas turbine engine [1–3] which was previously conducted under the DOE sponsored Ceramic Stationary Gas Turbine program (DE-AC02-92CE40960), is continuing under this program. This paper is a status review of the program, detailing the current progress of the development and field evaluations.

Author(s):  
Jeffrey Price

Solar Turbines Incorporated, under cooperative agreement number DEFC02-00CH11049, is improving the durability of advanced combustion systems while reducing life cycle costs. This project is part of the Advanced Materials in Advanced Industrial Gas Turbines program in DOE’s Office of Distributed Energy. The targeted development engine is the Mercury 50 gas turbine under development by Solar Turbines Incorporated under the DOE Advanced Turbine Systems (ATS) program (DOE contract number DE-FC21-95MC31173). The ultimate goal of the program is to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for 4,000 hours. The program focuses on a dual path development route to define an optimum mix of technologies for the Mercury 50 and future Solar gas turbine products. For linear and injector development, multiple concepts including high thermal resistance thermal barrier coatings (TBC), oxide dispersion strengthened (ODS) alloys, continuous fiber ceramic composites (CFCC), and monolithic ceramics are being evaluated before down selection to the most promising candidate materials for field evaluation. Preliminary component and sub-scale testing is being conducted to determine material properties and demonstrate proof-of-concept. Full-scale rig and engine testing will validate engine performance prior to field evaluation at a host site. Field testing of CFCC combustor liners in Centaur 50 engines at two field test sites is also being conducted under the Advanced Materials Program. This paper is a status review of the program, detailing the current progress.


Energies ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 389
Author(s):  
Jinfu Liu ◽  
Zhenhua Long ◽  
Mingliang Bai ◽  
Linhai Zhu ◽  
Daren Yu

As one of the core components of gas turbines, the combustion system operates in a high-temperature and high-pressure adverse environment, which makes it extremely prone to faults and catastrophic accidents. Therefore, it is necessary to monitor the combustion system to detect in a timely way whether its performance has deteriorated, to improve the safety and economy of gas turbine operation. However, the combustor outlet temperature is so high that conventional sensors cannot work in such a harsh environment for a long time. In practical application, temperature thermocouples distributed at the turbine outlet are used to monitor the exhaust gas temperature (EGT) to indirectly monitor the performance of the combustion system, but, the EGT is not only affected by faults but also influenced by many interference factors, such as ambient conditions, operating conditions, rotation and mixing of uneven hot gas, performance degradation of compressor, etc., which will reduce the sensitivity and reliability of fault detection. For this reason, many scholars have devoted themselves to the research of combustion system fault detection and proposed many excellent methods. However, few studies have compared these methods. This paper will introduce the main methods of combustion system fault detection and select current mainstream methods for analysis. And a circumferential temperature distribution model of gas turbine is established to simulate the EGT profile when a fault is coupled with interference factors, then use the simulation data to compare the detection results of selected methods. Besides, the comparison results are verified by the actual operation data of a gas turbine. Finally, through comparative research and mechanism analysis, the study points out a more suitable method for gas turbine combustion system fault detection and proposes possible development directions.


Author(s):  
Waseem Nazeer ◽  
Kenneth Smith ◽  
Patrick Sheppard ◽  
Robert Cheng ◽  
David Littlejohn

The continued development of a low swirl injector for ultra-low NOx gas turbine applications is described. An injector prototype for natural gas operation has been designed, fabricated and tested. The target application is an annular gas turbine combustion system requiring twelve injectors. High pressure rig test results for a single injector prototype are presented. On natural gas, ultra-low NOx emissions were achieved along with low CO. A turndown of approximately 100°F in flame temperature was possible before CO emissions increased significantly. Subsequently, a set of injectors was evaluated at atmospheric pressure using a production annular combustor. Rig testing again demonstrated the ultra-low NOx capability of the injectors on natural gas. An engine test of the injectors will be required to establish the transient performance of the combustion system and to assess any combustor pressure oscillation issues.


Author(s):  
G. J. Kelsall ◽  
M. A. Smith ◽  
H. Todd ◽  
M. J. Burrows

Advanced coal based power generation systems such as the British Coal Topping Cycle offer the potential for high efficiency electricity generation with minimum environmental impact. An important component of the Topping Cycle programme is the development of a gas turbine combustion system to burn low calorific value (3.5–4.0 MJ/m3 wet gross) coal derived fuel gas, at a turbine inlet temperature of 1260°C, with minimum pollutant emissions. The paper gives an overview of the British Coal approach to the provision of a gas turbine combustion system for the British Coal Topping Cycle, which includes both experimental and modelling aspects. The first phase of this programme is described, including the design and operation of a low-NOx turbine combustor, operating at an outlet temperature of 1360°C and burning a synthetic low calorific value (LCV) fuel gas, containing 0 to 1000 ppmv of ammonia. Test results up to a pressure of 8 bar are presented and the requirements for further combustor development outlined.


Author(s):  
Hasan Karim ◽  
Jayaprakash Natarajan ◽  
Venkat Narra ◽  
Jun Cai ◽  
Shreekrishna Rao ◽  
...  

Driven by global warming, a relentless march towards increased fuel efficiency has resulted in increased firing temperature for HA-class engines without an increase in baseload emissions. Moreover, emissions compliance for CO, NOx, and unburned hydrocarbons are desired over increased range in gas turbine load. In addition, exceptional gas turbine operational flexibility is desired to address potential intermittency due to the penetration of renewables in the electrical grid. Staged/sequential combustion is a state of the technology to provide operational flexibility and reduced emissions in power generation gas turbines. GE Power’s 7HA-class gas turbine combustion system combines GE’s proven DLN-2.6+ combustion technology, that has run reliably for over 1.3 million fired hours across more than eighty 9FA.03, 9F.05 & 7FA gas turbine engines, with an axially fuel staged system (AFS). Axially staging combustion to two zones allows for increased firing temperature at baseload (while maintaining the same NOx level) by operating the later/second stage hotter than the first/primary stage. During low load operation as the gas turbine firing temperature is reduced, percentage fuel split in the staged fuel system can either be reduced significantly or turned off and thereby keeping the overall combustion system into emissions compliance over a wider range of firing temperatures. This paper presents both the development testing of the staged combustion in the FA and HA class gas turbine combustion system rigs at GE Power’s Gas Turbine Technology Laboratory and the validation testing of staged combustion system for the 7HA.01 engine completed during Spring 2016 at GE Power’s engine test facility in Greenville, SC. The paper also discusses the significant simplification of operational principle and flexibility of startup, loading and baseload operation of the 7HA combustion system. Discussion of engine test results will show how axial fuel staging was utilized to demonstrate emissions compliance ( NOx (15% O2) < 25 ppm; CO < 9 ppm), operation from 14% load to 100% load with low combustion dynamics and also to enable wide wobbe capability, which is a normalized measure of fuel flexibility.


Author(s):  
William D. York ◽  
Willy S. Ziminsky ◽  
Ertan Yilmaz

Interest in hydrogen as a primary fuel stream in heavy-duty gas turbine engines has increased as precombustion carbon capture and sequestration (CCS) has become a viable option for integrated gasification combined cycle (IGCC) power plants. The U.S. Department of Energy has funded the Advanced IGCC/Hydrogen Gas Turbine Program since 2005 with an aggressive plant-level NOx target of 2 ppm at 15% O2 for an advanced gas turbine cycle. Approaching this NOx level with highly reactive hydrogen fuel at the conditions required is a formidable challenge that requires novel combustion technology. This study begins by measuring entitlement NOx emissions from perfectly premixed combustion of the high-hydrogen fuels of interest. A new premixing fuel injector for high-hydrogen fuels was designed to balance reliable flashback-free operation, reasonable pressure drop, and low emissions. The concept relies on small-scale jet-in-crossflow mixing that is a departure from traditional swirl-based premixing concepts. Single nozzle rig experiments were conducted at pressures of 10 atm and 17 atm, with air preheat temperatures of about 650 K. With nitrogen-diluted hydrogen fuel, characteristic of carbon-free syngas, stable operation without flashback was conducted up to flame temperatures of approximately 1850 K. In addition to the effects of pressure, the impacts of nitrogen dilution levels and amounts of minor constituents in the fuel—carbon monoxide, carbon dioxide, and methane—on flame holding in the premixer are presented. The new fuel injector concept has been incorporated into a full-scale, multinozzle combustor can with an energy conversion rate of more than 10 MW at F-class conditions. The full-can testing was conducted at full gas turbine conditions and various fuel compositions of hydrogen, natural gas, and nitrogen. This combustion system has accumulated over 100 h of fired testing at full load with hydrogen comprising over 90% of the reactants by volume. NOx emissions (ppm) have been measured in the single digits with hydrogen-nitrogen fuel at target gas turbine pressure and temperatures. Results of the testing show that small-scale fuel-air mixing can deliver a reliable, low-NOx solution to hydrogen combustion in advanced gas turbines.


Author(s):  
William D. York ◽  
Willy S. Ziminsky ◽  
Ertan Yilmaz

Interest in hydrogen as a primary fuel stream in heavy-duty gas turbine engines has increased as pre-combustion carbon capture and sequestration (CCS) has become a viable option for integrated gasification combined cycle (IGCC) power plants. The US Department of Energy has funded the Advanced IGCC/Hydrogen Gas Turbine Program since 2005 with an aggressive plant-level NOx target of 2 ppm @ 15% O2 for an advanced gas turbine cycle. Approaching this NOx level with highly-reactive hydrogen fuel at the conditions required is a formidable challenge that requires novel combustion technology. This study begins by measuring entitlement NOx emissions from perfectly-premixed combustion of the high-hydrogen fuels of interest. A new premixing fuel injector for high-hydrogen fuels was designed to balance reliable, flashback-free operation, reasonable pressure drop, and low emissions. The concept relies on distributed, small-scale jet-in-crossflow mixing that is a departure from traditional swirl-based premixing concepts. Single nozzle rig experiments were conducted at pressures of 10 atm and 17 atm, with air preheat temperatures of about 650K. With nitrogen-diluted hydrogen fuel, characteristic of carbon-free syngas, stable operation without flashback was conducted up to flame temperatures of approximately 1850K. In addition to the effects of operating pressure, the impact of minor constituents in the fuel — carbon monoxide, carbon dioxide, and methane — on flame holding in the premixer is presented. The new fuel injector concept has been incorporated into a full-scale, multi-nozzle combustor can with an energy conversion rate of more than 10 MW at F-class conditions. The full-can testing was conducted at full gas turbine conditions and various fuel compositions of hydrogen, natural gas, and nitrogen. This combustion system has accumulated over 100 hours of fired testing at full-load with hydrogen comprising over 90 percent of the reactants by volume. NOx emissions (ppm) have been measured in the single digits with hydrogen-nitrogen fuel at target gas turbine pressure and temperatures. Results of the testing show that small-scale fuel-air mixing can deliver a reliable, low-NOx solution to hydrogen combustion in advanced gas turbines.


Author(s):  
William D. York ◽  
Bryan W. Romig ◽  
Michael J. Hughes ◽  
Derrick W. Simons ◽  
Joseph V. Citeno

Operators of heavy duty gas turbines desire more flexibility of operation in compliance with increasingly stringent emissions regulations. Delivering low NOx at base load operation, while at the same time meeting aggressive startup, shutdown, and part load requirements for NOx, CO, and unburned hydrocarbons is a challenge that requires novel solutions in the framework of lean premixed combustion systems. The DLN2.6+ combustion system, first offered by the General Electric Company (GE) in 2005 on the 9F series gas turbines for the 50 Hz market, has a proven track record of low emissions, flexibility, and reliability. In 2010, GE launched a program to incorporate the DLN2.6+ into the 7F gas turbine model. The primary driver for the introduction of this combustion system into the 60 Hz market was to enable customers to capitalize on opportunities to use shale gas, which may have a greater Wobbe range and higher reactivity than traditional natural gas. The 7F version of the DLN2.6+ features premixed pilot flames on the five outer swirl-stabilized premixing fuel nozzles (“swozzles”). The premixed pilots have their roots in the multitube mixer technology developed by GE in the US Department of Energy Hydrogen Gas Turbine Program. A fraction of air is extracted prior to entering the combustor and sent to small tubes around the tip of the fuel nozzle centerbody. A dedicated pilot fuel circuit delivers the gas fuel to the pilot tubes, where it is injected into the air stream and given sufficient length to mix. Since the pilot flames are premixed, they contribute lower NOx emissions than a diffusion pilot, but can still provide enhanced main circuit flame stability at low-load conditions. The pilot equivalence ratio can be optimized for the specific operating conditions of the gas turbine. This paper presents the development and validation testing of the premixed pilots, which were tested on E-class and F-class gas turbine combustion system rigs at GE Power & Water’s Gas Turbine Technology Lab. A 25% reduction in NOx emissions at nominal firing temperature was demonstrated over a diffusion flame pilot, translating into more than 80% reduction in CO emissions if increased flame temperature is employed to hold constant NOx. On the new 7F DLN2.6+, the premixed pilots have enabled modifications to the system to reduce base load NOx emissions while maintaining similar gas turbine low-load performance and bringing a significant reduction in the combustor exit temperature at which LBO occurs, highlighting the stability the pilot system brings to the combustor without the NOx penalty of a diffusion pilot. The new combustion system is scheduled to enter commercial operation on GE 7F series gas turbines in 2015.


Author(s):  
Paul Pixner ◽  
Werner Krebs ◽  
Bernd Prade

One of the greatest challenges in modern gas turbine engineering is to optimize the combustion system for the reduction of emissions. For better understanding of combustion systems and hence having the possibility of systematic innovation of gas turbine combustion systems, a permanent improvement of design tools is essential. Demonstrated here is the use of an advanced combustion model — the INTRINSIC LOW DIMENSIONAL MANIFOLD (ILDM) approach — in Computational Flow Dynamics (CFD) analysis. In the past, chemical kinetic models used in CFD-calculations were based on empirical parameters and so called “global mechanisms” which are in fact “local” models and can be used only when modeling one operating point of the gas turbine combustion system. The scope of the integration of the ILDM approach into CFD is the use of a generalized approach for modeling chemical kinetics in CFD. Turbulence-chemistry interaction is considered by a presumed Probability Density Function (PDF) approach. The benefit of this method is a realistic prediction of all relevant flame characteristics e.g. piloting of premixed flames. This offers the possibility to integrate the whole combustion modeling tool in an overall emission prevention strategy. This work here will present the results of applying this new approach to an atmosperic test rig and first validation results.


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