Development and Testing of a Low NOx Hydrogen Combustion System for Heavy-Duty Gas Turbines

2013 ◽  
Vol 135 (2) ◽  
Author(s):  
William D. York ◽  
Willy S. Ziminsky ◽  
Ertan Yilmaz
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Small Scale ◽  
Nox Emissions ◽  
Combustion System ◽  
Fuel Injector ◽  
Hydrogen Fuel ◽  
Heavy Duty ◽  
High Hydrogen ◽  
Hydrogen Fuels

Interest in hydrogen as a primary fuel stream in heavy-duty gas turbine engines has increased as precombustion carbon capture and sequestration (CCS) has become a viable option for integrated gasification combined cycle (IGCC) power plants. The U.S. Department of Energy has funded the Advanced IGCC/Hydrogen Gas Turbine Program since 2005 with an aggressive plant-level NOx target of 2 ppm at 15% O2 for an advanced gas turbine cycle. Approaching this NOx level with highly reactive hydrogen fuel at the conditions required is a formidable challenge that requires novel combustion technology. This study begins by measuring entitlement NOx emissions from perfectly premixed combustion of the high-hydrogen fuels of interest. A new premixing fuel injector for high-hydrogen fuels was designed to balance reliable flashback-free operation, reasonable pressure drop, and low emissions. The concept relies on small-scale jet-in-crossflow mixing that is a departure from traditional swirl-based premixing concepts. Single nozzle rig experiments were conducted at pressures of 10 atm and 17 atm, with air preheat temperatures of about 650 K. With nitrogen-diluted hydrogen fuel, characteristic of carbon-free syngas, stable operation without flashback was conducted up to flame temperatures of approximately 1850 K. In addition to the effects of pressure, the impacts of nitrogen dilution levels and amounts of minor constituents in the fuel—carbon monoxide, carbon dioxide, and methane—on flame holding in the premixer are presented. The new fuel injector concept has been incorporated into a full-scale, multinozzle combustor can with an energy conversion rate of more than 10 MW at F-class conditions. The full-can testing was conducted at full gas turbine conditions and various fuel compositions of hydrogen, natural gas, and nitrogen. This combustion system has accumulated over 100 h of fired testing at full load with hydrogen comprising over 90% of the reactants by volume. NOx emissions (ppm) have been measured in the single digits with hydrogen-nitrogen fuel at target gas turbine pressure and temperatures. Results of the testing show that small-scale fuel-air mixing can deliver a reliable, low-NOx solution to hydrogen combustion in advanced gas turbines.

Development and Testing of a Low NOX Hydrogen Combustion System for Heavy Duty Gas Turbines

2012 ◽  
Author(s):  
William D. York ◽  
Willy S. Ziminsky ◽  
Ertan Yilmaz
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Small Scale ◽  
Nox Emissions ◽  
Combustion System ◽  
Fuel Injector ◽  
Hydrogen Fuel ◽  
Heavy Duty ◽  
High Hydrogen ◽  
Hydrogen Fuels

Interest in hydrogen as a primary fuel stream in heavy-duty gas turbine engines has increased as pre-combustion carbon capture and sequestration (CCS) has become a viable option for integrated gasification combined cycle (IGCC) power plants. The US Department of Energy has funded the Advanced IGCC/Hydrogen Gas Turbine Program since 2005 with an aggressive plant-level NOx target of 2 ppm @ 15% O2 for an advanced gas turbine cycle. Approaching this NOx level with highly-reactive hydrogen fuel at the conditions required is a formidable challenge that requires novel combustion technology. This study begins by measuring entitlement NOx emissions from perfectly-premixed combustion of the high-hydrogen fuels of interest. A new premixing fuel injector for high-hydrogen fuels was designed to balance reliable, flashback-free operation, reasonable pressure drop, and low emissions. The concept relies on distributed, small-scale jet-in-crossflow mixing that is a departure from traditional swirl-based premixing concepts. Single nozzle rig experiments were conducted at pressures of 10 atm and 17 atm, with air preheat temperatures of about 650K. With nitrogen-diluted hydrogen fuel, characteristic of carbon-free syngas, stable operation without flashback was conducted up to flame temperatures of approximately 1850K. In addition to the effects of operating pressure, the impact of minor constituents in the fuel — carbon monoxide, carbon dioxide, and methane — on flame holding in the premixer is presented. The new fuel injector concept has been incorporated into a full-scale, multi-nozzle combustor can with an energy conversion rate of more than 10 MW at F-class conditions. The full-can testing was conducted at full gas turbine conditions and various fuel compositions of hydrogen, natural gas, and nitrogen. This combustion system has accumulated over 100 hours of fired testing at full-load with hydrogen comprising over 90 percent of the reactants by volume. NOx emissions (ppm) have been measured in the single digits with hydrogen-nitrogen fuel at target gas turbine pressure and temperatures. Results of the testing show that small-scale fuel-air mixing can deliver a reliable, low-NOx solution to hydrogen combustion in advanced gas turbines.

scholarly journals Development of a Catalytic Combustor for a Heavy-Duty Utility Gas Turbine

1996 ◽  
Author(s):  
Ralph A. Dalla Betta ◽  
James C. Schlatter ◽  
Sarento G. Nickolas ◽  
Martin B. Cutrone ◽  
Kenneth W. Beebe ◽  
...  
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Catalytic Combustion ◽  
Full Scale ◽  
Inlet Temperature ◽  
Nox Emissions ◽  
Combustion System ◽  
Catalytic Reactor ◽  
Heavy Duty ◽  
Catalytic Combustor

The most effective technologies currently available for controlling NOx emissions from heavy-duty industrial gas turbines are either diluent injection in the combustor reaction zone, or lean premixed Dry Low NOx (DLN) combustion. For ultra low emissions requirements, these must be combined with selective catalytic reduction (SCR) DeNOx systems in the gas turbine exhaust. An alternative technology for achieving comparable emissions levels with the potential for lower capital investment and operating cost is catalytic combustion of lean premixed fuel and air within the gas turbine. The design of a catalytic combustion system using natural gas fuel has been prepared for the GE model MS9OOIE gas turbine. This machine has a turbine inlet temperature to the first rotating stage of over 1100°C and produces approximately 105 MW electrical output in simple cycle operation. The 508 mm diameter catalytic combustor designed for this gas turbine was operated at full-scale conditions in tests conducted in 1992 and 1994. The combustor was operated for twelve hours during the 1994 test and demonstrated very low NOx emissions from the catalytic reactor. The total exhaust NOx level was approximately 12–15 ppmv and was produced almost entirely in the preburner ahead of the reactor. A small quantity of steam injected into the preburner reduced the NOx emissions to 5–6 ppmv. Development of the combustion system has continued with the objectives of reducing CO and UHC emissions, understanding the parameters affecting reactor stability and spatial non-uniformities which were observed at low inlet temperature, and improving the structural integrity of the reactor system to a level required for commercial operation of gas turbines. Design modifications were completed and combustion hardware was fabricated for additional full-scale tests of the catalytic combustion system in March 1995 and January 1996. This paper presents a discussion of the combustor design, the catalytic reactor design and the results of full-scale testing of the improved combustor at MS9OOIE cycle conditions in the March 1995 and January 1996 tests. Major improvements in performance were achieved with CO and UHC emissions of 10 ppmv and 0 ppmv at base load conditions. This ongoing program will lead to two additional full-scale combustion system tests in 1996. The results of these tests will be available for discussion at the June 1996 Conference in Birmingham.

Development of a Small-Scale Catalytic Gas Turbine Combustor

1982 ◽  
Vol 104 (1) ◽  
pp. 52-57 ◽  
Author(s):  
S. J. Anderson ◽  
M. A. Friedman ◽  
W. V. Krill ◽  
J. P. Kesselring
Keyword(s):  
Steady State ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Combustion Efficiency ◽  
Small Scale ◽  
Time Interval ◽  
Nox Emissions ◽  
Fuel Injector ◽  
Gas Turbine Combustor ◽  
Opposed Jet

Catalytically supported thermal combustion can provide low NOx emissions with gaseous and distillate fuels while maintaining high combustion efficiency. For stationary gas turbines, catalytic combustion may be the only emerging technology that can cost effectively meet recent federal regulations for NOx emissions. Under EPA sponsorship, a small-scale, catalytic gas turbine combustor was developed to evaluate transient and steady state combustor performance. The combustor consisted of a multiple air-atomizing fuel injector, an opposed jet igniter, and a graded-cell monolithic reactor. System startup, including opposed jet ignition and catalyst stabilization, was achieved in 250 seconds. This time interval is comparable to conventional gas turbines. Steady state operation was performed at 0.505 MPa (5 atmospheres) pressure and 15.3 m/s (50 ft/s) reference velocities. Thermal NOx emissions were measured below 10 ppmv, while fuel NOx conversion ranged from 75 to 95 percent. At catalyst bed temperatures greater than 1422K (2100°F), total CO and UHC emissions were less than 50 ppmv indicating combustion efficiency greater than 99.9 percent. Compared with conventional gas turbine combustors, the catalytic reactor operates only within a relatively narrow range of fuel/air ratios. As a result, modified combustor air distribution or fuel staging will be required to achieve the wide turndown required in large stationary systems.

Development of a Catalytic Combustor for a Heavy-Duty Utility Gas Turbine

1997 ◽  
Vol 119 (4) ◽  
pp. 844-851 ◽  
Author(s):  
R. A. Dalla Betta ◽  
J. C. Schlatter ◽  
S. G. Nickolas ◽  
M. B. Cutrone ◽  
K. W. Beebe ◽  
...  
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Catalytic Combustion ◽  
Full Scale ◽  
Inlet Temperature ◽  
Nox Emissions ◽  
Combustion System ◽  
Catalytic Reactor ◽  
Heavy Duty ◽  
Catalytic Combustor

The most effective technologies currently available for controlling NOx emissions from heavy-duty industrial gas turbines are diluent injection in the combustor reaction zone, and lean premixed Dry Low NOx (DLN) combustion. For ultralow emissions requirements, these must be combined with selective catalytic reduction (SCR) DeNOx systems in the gas turbine exhaust. An alternative technology for achieving comparable emissions levels with the potential for lower capital investment and operating cost is catalytic combustion of lean premixed fuel and air within the gas turbine. The design of a catalytic combustion system using natural gas fuel has been prepared for the GE model MS9OO1E gas turbine. This machine has a turbine inlet temperature to the first rotating stage of over 1100°C and produces approximately 105 MW electrical output in simple cycle operation. The 508-mm-dia catalytic combustor designed for this gas turbine was operated at full-scale conditions in tests conducted in 1992 and 1994. The combustor was operated for twelve hours during the 1994 test and demonstrated very low NOx emissions from the catalytic reactor. The total exhaust NOx level was approximately 12–15 ppmv and was produced almost entirely in the preburner ahead of the reactor. A small quantity of steam injected into the preburner reduced the NOx emissions to 5–6 ppmv. Development of the combustion system has continued with the objectives of reducing CO and UHC emissions, understanding the parameters affecting reactor stability and spatial nonuniformities that were observed at low inlet temperature, and improving the structural integrity of the reactor system to a level required for commercial operation of gas turbines. Design modifications were completed and combustion hardware was fabricated for additional full-scale tests of the catalytic combustion system in March 1995 and January 1996. This paper presents a discussion of the combustor design, the catalytic reactor design, and the results of full-scale testing of the improved combustor at MS9OO1E cycle conditions in the March 1995 and January 1996 tests. Major improvements in performance were achieved with CO and UHC emissions of 10 ppmv and 0 ppmv at baseload conditions. This ongoing program will lead to two additional full-scale combustion system tests in 1996. The results of these tests will be available for discussion at the June 1996 Conference in Birmingham.

Premixed Pilot Flames for Improved Emissions and Flexibility in a Heavy Duty Gas Turbine Combustion System

2015 ◽  
Author(s):  
William D. York ◽  
Bryan W. Romig ◽  
Michael J. Hughes ◽  
Derrick W. Simons ◽  
Joseph V. Citeno
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Hydrogen Gas ◽  
Operating Conditions ◽  
Nox Emissions ◽  
Combustion System ◽  
Heavy Duty ◽  
Low Load ◽  
Gas Turbine Combustion ◽  
Base Load

Operators of heavy duty gas turbines desire more flexibility of operation in compliance with increasingly stringent emissions regulations. Delivering low NOx at base load operation, while at the same time meeting aggressive startup, shutdown, and part load requirements for NOx, CO, and unburned hydrocarbons is a challenge that requires novel solutions in the framework of lean premixed combustion systems. The DLN2.6+ combustion system, first offered by the General Electric Company (GE) in 2005 on the 9F series gas turbines for the 50 Hz market, has a proven track record of low emissions, flexibility, and reliability. In 2010, GE launched a program to incorporate the DLN2.6+ into the 7F gas turbine model. The primary driver for the introduction of this combustion system into the 60 Hz market was to enable customers to capitalize on opportunities to use shale gas, which may have a greater Wobbe range and higher reactivity than traditional natural gas. The 7F version of the DLN2.6+ features premixed pilot flames on the five outer swirl-stabilized premixing fuel nozzles (“swozzles”). The premixed pilots have their roots in the multitube mixer technology developed by GE in the US Department of Energy Hydrogen Gas Turbine Program. A fraction of air is extracted prior to entering the combustor and sent to small tubes around the tip of the fuel nozzle centerbody. A dedicated pilot fuel circuit delivers the gas fuel to the pilot tubes, where it is injected into the air stream and given sufficient length to mix. Since the pilot flames are premixed, they contribute lower NOx emissions than a diffusion pilot, but can still provide enhanced main circuit flame stability at low-load conditions. The pilot equivalence ratio can be optimized for the specific operating conditions of the gas turbine. This paper presents the development and validation testing of the premixed pilots, which were tested on E-class and F-class gas turbine combustion system rigs at GE Power & Water’s Gas Turbine Technology Lab. A 25% reduction in NOx emissions at nominal firing temperature was demonstrated over a diffusion flame pilot, translating into more than 80% reduction in CO emissions if increased flame temperature is employed to hold constant NOx. On the new 7F DLN2.6+, the premixed pilots have enabled modifications to the system to reduce base load NOx emissions while maintaining similar gas turbine low-load performance and bringing a significant reduction in the combustor exit temperature at which LBO occurs, highlighting the stability the pilot system brings to the combustor without the NOx penalty of a diffusion pilot. The new combustion system is scheduled to enter commercial operation on GE 7F series gas turbines in 2015.

Study of a Rich/Lean Staged Combustion Concept for Hydrogen at Gas Turbine Relevant Conditions

2013 ◽  
Author(s):  
Felipe Bolaños ◽  
Dieter Winkler ◽  
Felipe Piringer ◽  
Timothy Griffin ◽  
Rolf Bombach ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Carbon Capture ◽  
Flame Temperature ◽  
Nox Emissions ◽  
Hydrogen Fuel ◽  
Auto Ignition ◽  
Wide Range ◽  
The Rich

The combustion of hydrogen-rich fuels (> 80 % vol. H2), relevant for gas turbine cycles with “pre-combustion” carbon capture, creates great challenges in the application of standard lean premix combustion technology. The significant higher flame speed and drastically reduced auto-ignition delay time of hydrogen compared to those of natural gas, which is normally burned in gas turbines, increase the risk of higher NOX emissions and material damage due to flashback. Combustion concepts for gas turbines operating on hydrogen fuel need to be adapted to assure safe and low-emission combustion. A rich/lean (R/L) combustion concept with integrated heat transfer that addresses the challenges of hydrogen combustion has been investigated. A sub-scale, staged burner with full optical access has been designed and tested at gas turbine relevant conditions (flame temperature of 1750 K, preheat temperature of 400 °C and a pressure of 8 bar). Results of the burner tests have confirmed the capability of the rich/lean staged concept to reduce the NOx emissions for undiluted hydrogen fuel. The NOx emissions were reduced from 165 ppm measured without staging (fuel pre-conversion) to 23 ppm for an R/L design having a fuel-rich hydrogen pre-conversion of 50 % at a constant power of 8.7 kW. In the realized R/L concept the products of the first rich stage, which is ignited by a Pt/Pd catalyst (under a laminar flow, Re ≈ 1900) are combusted in a diffusion-flame-like lean stage (turbulent flow Re ≈ 18500) without any flashback risk. The optical accessibility of the reactor has allowed insight into the combustion processes of both stages. Applying OH-LIF and OH*-chemiluminescence optical techniques, it was shown that mainly homogeneous reactions at rich conditions take place in the first stage, questioning the importance of a catalyst in the system, and opening a wide range of optimization possibilities. The promising results obtained in this study suggest that such a rich/lean staged burner with integrated heat transfer could help to develop a new generation of gas turbine burners for safe and clean combustion of H2-rich fuels.

Advanced Materials for Mercury™ 50 Gas Turbine Combustion System

2006 ◽  
Author(s):  
Jeffrey Price ◽  
Josh Kimmel ◽  
Xiaoqun Chen ◽  
Arun Bhattacharya ◽  
Anthony Fahme ◽  
...  
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Ceramic Matrix Composite ◽  
Field Evaluation ◽  
Ceramic Composites ◽  
Advanced Materials ◽  
Combustion System ◽  
Fuel Injector ◽  
Ods Alloys ◽  
Gas Turbine Combustion

Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-00CH 11049, is improving the durability of gas turbine combustion systems while reducing life cycle costs. This project is part of the Advanced Materials in Advanced Industrial Gas Turbines program in DOE’s Office of Distributed Energy. The targeted engine is the Mercury™ 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems (ATS) program (DOE contract number DE-FC21-95MC31173). The ultimate goal of the program is to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for 4,000 hours. The program has focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 turbine and future Solar products. For liner and injector development, multiple concepts including high thermal resistance thermal barrier coatings (TBC), oxide dispersion strengthened (ODS) alloys, continuous fiber ceramic composites (CFCC), and monolithic ceramics were evaluated. An advanced TBC system for the combustor was down-selected for field evaluation. ODS alloys were down-selected for the fuel injector tip application. Preliminary component and sub-scale testing was conducted to determine material properties and demonstrate proof-of-concept. Full-scale rig and engine testing were used to validate engine performance prior to field evaluation. Field evaluation of ceramic matrix composite liners in the Centaur® 50 gas turbine engine [1–3] which was previously conducted under the DOE sponsored Ceramic Stationary Gas Turbine program (DE-AC02-92CE40960), is continuing under this program. This paper is a status review of the program, detailing the current progress of the development and field evaluations.

Dry, Low Emissions for the ‘H’ Heavy-Duty Industrial Gas Turbines: Full-Scale Combustion System Rig Test Results

2003 ◽  
Author(s):  
Geoff Myers ◽  
Dan Tegel ◽  
Markus Feigl ◽  
Fred Setzer ◽  
William Bechtel ◽  
...  
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Pressure Ratio ◽  
Combined Cycle ◽  
Full Scale ◽  
Combustion System ◽  
Heavy Duty ◽  
Test Program ◽  
Industrial Gas Turbines ◽  
Inlet Conditions

The lean, premixed DLN2.5H combustion system was designed to deliver low NOx emissions from 50% to 100% load in both the Frame 7H (60 Hz) and Frame 9H (50 Hz) heavy-duty industrial gas turbines. The H machines employ steam cooling in the gas turbine, a 23:1 pressure ratio, and are fired at 1440 C (2600 F) to deliver over-all thermal efficiency for the combined-cycle system near 60%. The DLN2.5H combustor is a modular can-type design, with 14 identical chambers used on the 9H machine, and 12 used on the smaller 7H. On a 9H combined-cycle power plant, both the gas turbine and steam turbine are fired using the 14-chamber DLN2.5H combustion system. An extensive full-scale, full-pressure rig test program developed the fuel-staged dry, low emissions combustion system over a period of more than five years. Rig testing required test stand inlet conditions of over 50 kg/s at 500 C and 28 bar, while firing at up to 1440 C, to simulate combustor operation at base load. The combustion test rig simulated gas path geometry from the discharge of the annular tri-passage diffuser through the can-type combustion liner and transition piece, to the inlet of the first stage turbine nozzle. The present paper describes the combustion system, and reports emissions performance and operability results over the gas turbine load and ambient temperature operating range, as measured during the rig test program.

scholarly journals Conceptual Studies of a Fuel-Flexible Low-Swirl Combustion System for the Gas Turbine in Clean Coal Power Plants

2010 ◽  
Author(s):  
Kenneth O. Smith ◽  
Peter L. Therkelsen ◽  
David Littlejohn ◽  
Sy Ali ◽  
Robert K. Cheng
Keyword(s):  
Gas Turbine ◽  
Gas Turbines ◽  
Power Plants ◽  
Fuel Injection ◽  
Pollutant Emissions ◽  
Injection System ◽  
Combustion System ◽  
High Hydrogen ◽  
Swirl Combustion ◽  
Auto Ignition

This paper reports the results of preliminary analyses that show the feasibility of developing a fuel flexible (natural gas, syngas and high-hydrogen fuel) combustion system for IGCC gas turbines. Of particular interest is the use of Lawrence Berkeley National Laboratory’s DLN low swirl combustion technology as the basis for the IGCC turbine combustor. Conceptual designs of the combustion system and the requirements for the fuel handling and delivery circuits are discussed. The analyses show the feasibility of a multi-fuel, utility-sized, LSI-based, gas turbine engine. A conceptual design of the fuel injection system shows that dual parallel fuel circuits can provide range of gas turbine operation in a configuration consistent with low pollutant emissions. Additionally, several issues and challenges associated with the development of such a system, such as flashback and auto-ignition of the high-hydrogen fuels, are outlined.

Evaluation of Arabian Super Light Crude Oil for Use in a F-Class DLN Combustion System

2014 ◽  
Author(s):  
Jeffrey Goldmeer ◽  
Richard Symonds ◽  
Paul Glaser ◽  
Bassam Mohammad ◽  
Zac Nagel ◽  
...  
Keyword(s):  
Power Generation ◽  
Natural Gas ◽  
Crude Oil ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Oil Prices ◽  
Combustion System ◽  
Heavy Duty ◽  
Global Trends ◽  
Heavy Liquids

Global trends in natural gas and distillate oil prices and availability continue to influence decisions on power generation fuel choice. In some regions, heavy liquids are being selected as gas turbine fuels. One particular crude oil, Arabian Super Light (ASL), has the potential to be used as a primary or back-up fuel in F-class heavy duty gas turbines. This paper presents the results of a set of tests performed on ASL to determine the potential of using it in a Dry Low NOx (DLN) combustion system for operation in an F-class gas turbine.

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