The Battle of CO2 Capture Technologies

2010 ◽  
Author(s):  
Ram G. Narula ◽  
Harvey Wen
Keyword(s):  
Climate Change ◽  
Power Generation ◽  
Co2 Capture ◽  
Flue Gas ◽  
Carbon Capture ◽  
Coal Gasification ◽  
Combined Cycle ◽  
Development Status ◽  
Combustion Technology ◽  
Carbon Dioxide Co2

Coal is an abundant, widespread, cheap energy source and contributes to 39% of the world’s electric power generation. Coal releases large amounts of carbon dioxide (CO2), which is believed to play a major role in global warming and climate change. To de-carbonize power generation, three distinct carbon capture technologies are in varying stages of development. These include pre-combustion carbon capture through the use of integrated coal gasification combined cycle (IGCC), post-combustion carbon capture from a pulverized-coal (PC)-fired power plant flue gas using monoethanolamine (MEA) or ammonia (NH3), and oxy-combustion technology. In the latter technology, oxygen is first separated from nitrogen in an air separator unit and used for combustion of coal in a conventional PC boiler. With oxy-combustion technology, the resulting flue gas is predominantly CO2, which makes CO2 capture easier than in the PC-MEA case. This paper discusses the development status as well as the advantages, limitations, performance and economics of each technology in regard to the capture and non-capture cases.

scholarly journals Development of a Low-NOx LBG Combustor for Coal Gasification Combined Cycle Power Generation Systems

1989 ◽  
Author(s):  
M. Sato ◽  
T. Abe ◽  
T. Ninomiya ◽  
T. Nakata ◽  
T. Yoshine ◽  
...  
Keyword(s):  
Power Generation ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Coal Gasification ◽  
Combined Cycle ◽  
Generation System ◽  
Combustion Technology ◽  
Power Generation System ◽  
Combustion Tests ◽  
Power Generation Systems

From the view point of future coal utilization technology for the thermal power generation systems, the coal gasification combined cycle system has drawn special interest recently. In the coal gasification combined cycle power generation system, it is necessary to develop a high temperature gas turbine combustor using a low-BTU gas (LBG) which has high thermal efficiency and low emissions. In Japan a development program of the coal gasification combined cycle power generation system has started in 1985 by the national government and Japanese electric companies. In this program, 1300°C class gas turbines will be developed. If the fuel gas cleaning system is a hot type, the coal gaseous fuel to be supplied to gas turbines will contain ammonia. Ammonia will be converted to nitric oxides in the combustion process in gas turbines. Therefore, low fuel-NOx combustion technology will be one of the most important research subjects. This paper describes low fuel-NOx combustion technology for 1300°C class gas turbine combustors using coal gaseous low-BTU fuel as well as combustion characteristics and carbon monoxide emission characteristics. Combustion tests were conducted using a full-scale combustor used for the 150 MW gas turbine at the atmospheric pressure. Furthermore, high pressure combustion tests were conducted using a half-scale combustor used for the 1 50 MW gas turbine.

Sequential Combustion in Ansaldo Energia Gas Turbines: The Technology Enabler for CO2-Free, Highly Efficient Power Production Based on Hydrogen

2020 ◽  
Author(s):  
Andrea Ciani ◽  
John P. Wood ◽  
Anders Wickström ◽  
Geir J. Rørtveit ◽  
Rosetta Steeneveldt ◽  
...  
Keyword(s):  
Power Generation ◽  
Free Energy ◽  
Gas Turbines ◽  
Carbon Capture ◽  
Power Plants ◽  
Carbon Capture And Storage ◽  
Combined Cycle ◽  
Fuel Flexibility ◽  
Combustion Technology ◽  
And Storage

Abstract Today gas turbines and combined cycle power plants play an important role in power generation and in the light of increasing energy demand, their role is expected to grow alongside renewables. In addition, the volatility of renewables in generating and dispatching power entails a new focus on electricity security. This reinforces the importance of gas turbines in guaranteeing grid reliability by compensating for the intermittency of renewables. In order to achieve the Paris Agreement’s goals, power generation must be decarbonized. This is where hydrogen produced from renewables or with CCS (Carbon Capture and Storage) comes into play, allowing totally CO2-free combustion. Hydrogen features the unique capability to store energy for medium to long storage cycles and hence could be used to alleviate seasonal variations of renewable power generation. The importance of hydrogen for future power generation is expected to increase due to several factors: the push for CO2-free energy production is calling for various options, all resulting in the necessity of a broader fuel flexibility, in particular accommodating hydrogen as a future fuel feeding gas turbines and combined cycle power plants. Hydrogen from methane reforming is pursued, with particular interest within energy scenarios linked with carbon capture and storage, while the increased share of renewables requires the storage of energy for which hydrogen is the best candidate. Compared to natural gas the main challenge of hydrogen combustion is its increased reactivity resulting in a decrease of engine performance for conventional premix combustion systems. The sequential combustion technology used within Ansaldo Energia’s GT36 and GT26 gas turbines provides for extra freedom in optimizing the operation concept. This sequential combustion technology enables low emission combustion at high temperatures with particularly high fuel flexibility thanks to the complementarity between its first stage, stabilized by flame propagation and its second (sequential) stage, stabilized by auto-ignition. With this concept, gas turbines are envisaged to be able to provide reliable, dispatchable, CO2-free electric power. In this paper, an overview of hydrogen production (grey, blue, and green hydrogen), transport and storage are presented targeting a CO2-free energy system based on gas turbines. A detailed description of the test infrastructure, handling of highly reactive fuels is given with specific aspects of the large amounts of hydrogen used for the full engine pressure tests. Based on the results discussed at last year’s Turbo Expo (Bothien et al. GT2019-90798), further high pressure test results are reported, demonstrating how sequential combustion with novel operational concepts is able to achieve the lowest emissions, highest fuel and operational flexibility, for very high combustor exit temperatures (H-class) with unprecedented hydrogen contents.

Performance of a Multiple-Injection Dry Low NOx Combustor With Hydrogen-Rich Syngas Fuels

2012 ◽  
Vol 135 (1) ◽  
Author(s):  
Satoschi Dodo ◽  
Tomohiro Asai ◽  
Hiromi Koizumi ◽  
Hirokazu Takahashi ◽  
Shouhei Yoshida ◽  
...  
Keyword(s):  
Carbon Capture ◽  
Coal Gasification ◽  
Capture Rate ◽  
Flame Temperature ◽  
Perforated Plate ◽  
Combined Cycle ◽  
Flammability Limits ◽  
Stable Combustion ◽  
Injection Burner ◽  
Combustion Technology

An oxygen-blown integrated coal gasification combined cycle (IGCC) plant with precombustion carbon dioxide capture and storage (CCS) is one of the most promising means of zero-emission generation of power from coal. In an IGCC plant with CCS, hydrogen-rich syngas with a wide variation of hydrogen contents is supplied to a gas turbine. Such hydrogen-rich syngas poses a great challenge to a low NOx combustor based on premixed combustion technology, because its high flame speed, low ignition energy, and broad flammability limits can cause flashback and/or autoignition. On the contrary, a diffusion combustor suffers from the high flame temperature of syngas and the resulting high NOx emission. The authors applied a “multi-injection burner” concept to a preliminary burner for hydrogen-rich syngas simulating that from IGCC with CCS. In a preliminary experiment under atmospheric pressure, the multi-injection burner worked without any flashback or any blowout. A prototype multicluster combustor based on the results of that preliminary study was made to be a dry low NOx combustor for hydrogen-rich syngas of IGCC with CCS. It was tested in experiments, which were carried out under medium pressure (0.6 MPa) using test fuels simulating syngas from IGCC with a 0% carbon capture rate, a 30% carbon capture rate, and a 50% carbon capture rate. The test fuels contained hydrogen, methane, and nitrogen, and had a hydrogen content ranging from 40% to 65%.The following conclusions were drawn from the test results: (1) the tested combustor allows the stable combustion of fuels simulating 0%, 30%, and 50% CCS, (2) a convex perforated plate swirler is effective to suppress combustion oscillation, which allows NOx emissions to be less than 10 ppm through the variation of fuel simulating 0%, 30%, and 50% CCS, (3) the extended stable combustion region and enhanced entrainment and mixing due to the convex perforated plate improves the cooling of the combustor liner metal to be less than the liner metal temperature criterion.

Out Line of the Osaki CoolGen Project

2017 ◽  
Author(s):  
Keiichi Ishida
Keyword(s):  
Power Generation ◽  
Fuel Cell ◽  
Co2 Emissions ◽  
Co2 Capture ◽  
Power Plants ◽  
Coal Gasification ◽  
Combined Cycle ◽  
Second Step ◽  
Low Carbon ◽  
Development Organization

Coal is a valuable primary energy source that has excellent supply stability and economic efficiency. Japan has extremely low energy self-sufficiency and coal-fired power generation is positioned as an important base load power supply. One urgent issue we face is to find realistic countermeasures that greatly reduce CO2 emissions from coal-fired power plants which produce a large volume of CO2 emissions. Therefore, we have launched the Osaki CoolGen Project since April 2012 as an “Integrated Coal Gasification Fuel Cell Combined Cycle (IGFC) Demonstration Project” subsidized by the Ministry of Economy, Trade and Industry (until 2015 FY) and New Energy and Industrial Technology Development Organization (from 2016 FY). This project aims to realize innovative low-carbon coal-fired power generation that combines an IGFC, an extremely efficient coal-fired power generation technology with high-performance CO2 capture technology for the purpose of dramatically reducing CO2 emissions from coal-fired power generation. This project consists of three steps. The first step will implement demonstration tests of the oxygen-blown Integrated coal Gasification Combined Cycle (IGCC) which is the base technology for IGFC. Toward the start of demonstration testing in March 2017, construction was started in March 2013 and commissioning was started in April 2016. In the second step, we plan to carry out demonstration tests of the oxygen-blown IGCC with CO2 capture equipment. In the third step, we plan to demonstrate an IGFC system combining the demonstration plant of the second step with a fuel cell.

Analysis of IGFC With Exergy Recuperation and Carbon Dioxide Separation Unit

2012 ◽  
Author(s):  
Masako Kawabata ◽  
Osamu Kurata ◽  
Norihiko Iki ◽  
Chihiro Fushimi ◽  
Atsushi Tsutsumi
Keyword(s):  
Power Generation ◽  
Co2 Capture ◽  
Coal Gasification ◽  
Combined Cycle ◽  
Generation System ◽  
Separation Unit ◽  
Exhaust Heat ◽  
Power Generation System ◽  
Efficient Power ◽  
Process Simulator

Integrated Coal Gasification Fuel Cell Combined Cycle (IGFC) is expected to be the most efficient power generation system in coal fired power generation systems [1,2]. However, more energy efficient power generation system has to be developed to decrease CO2 emission in the middle and long term. Thus, the authors have proposed Advanced Integrated Coal Gasification Combined Cycle (A-IGCC) and Advanced IGFC (A-IGFC) systems, which utilize exhaust heat from solid oxide fuel cells (SOFC) and / or a gas turbine as a heat source of gasification (exergy recuperation) [3]. Previously A-IGCC [4] and A-IGFC [5] without CO2 capture option were analyzed with the process simulator HYSYS®.Plant (Aspen technology Inc.) to calculate thermal efficiencies of the proposed systems. Then IGCC and A-IGCC with CO2 capture option [6, 7] were analyzed with Amine process simulator AMSIM(DBR), a module in PRO/II® (Invensys Process Systems Japan, Inc) combined with HYSYS®.Plant model. It shows in the results of thermal efficiency with CO2 capture option that the penalty of A-IGCC case is larger than that of IGCC case, indicating somewhat scope for increase of exergy recuperation in A-IGCC case [6]. This study deals in the analyses of A-IGFC with CO2 separation unit.

scholarly journals Coal Gaseous Fueled, Low Fuel-NOx Gas Turbine Combustor

1990 ◽  
Author(s):  
M. Sato ◽  
T. Ninomiya ◽  
T. Nakata ◽  
T. Yoshine ◽  
M. Yamada ◽  
...  
Keyword(s):  
Power Generation ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Coal Gasification ◽  
Combustion Method ◽  
Combined Cycle ◽  
Gas Turbine Combustor ◽  
Lean Combustion ◽  
Combustion Technology ◽  
Fuel Nox

From the view point of future coal utilization technology for the thermal power generation systems, the coal gasification combined cycle system has drawn special interest recently. In the coal gasification combined cycle power generation system, it is necessary to develop a high temperature gas turbine combustor using a low–BTU gas (LBG) which has high thermal efficiency and low emissions. In Japan a development program on the coal gasification combined cycle power generation system has started in 1985 by the national government and Japanese electric companies. In this program, is planned to develop the 1300 °C class gas turbines. However, in the case of using a hot type fuel gas cleaning system, the coal gas fuel to be supplied to gas turbines will contain ammonia. Ammonia will be converted to nitric oxides in the combustion process in gas turbines. Therefore, low fuel–NOx combustion technology is one of the most important research subjects. This paper describes low fuel–NOx combustion technology for 1300 °C class gas turbine combustor using low BTU coal gas fuel. Authors have showed that the rich–lean combustion method is effective to decrease fuel–NOx (1). In general in rich–lean combustion method, the fuel–NOx decreases, as the primary zone becomes richer. But flameholding becomes very difficult in even rich primary zone. For this reason this combustor was designed to have a flameholder with pilot flame. Combustion tests were conducted by using a full scale combustor used in 150 MW gas turbine at the atmospheric pressure condition.

Compare and Analyze of the Definition and Development of Distributed Generation in China and Abroad

2014 ◽  
Vol 953-954 ◽  
pp. 925-928 ◽  
Author(s):  
Bi Bin Huang
Keyword(s):  
Climate Change ◽  
Power Generation ◽  
Energy Conservation ◽  
Distributed Generation ◽  
Basic Characteristic ◽  
Large Scale ◽  
General Definition ◽  
Development Status ◽  
Incentive Policy ◽  
Definition Of

As the positive and important supplement to large-scale power generation, distributed generation (DG) will become key measure to promote energy conservation and solve the problems of climate change in China. Due to absence of universal authoritative definition of DG, this paper summarizes the basic characteristic of DG based on the definitions in typical countries (or organizations) and carried out general definition of DG considering our national conditions and power grid features. From the views of resource, incentive policy and industry, this paper analyzed the fundamental for DG development and compared the development status in typical countries.

Comparison of Preanode and Postanode Carbon Dioxide Separation for IGFC Systems

2010 ◽  
Vol 132 (6) ◽  
Author(s):  
Eric Liese
Keyword(s):  
Fuel Cell ◽  
Power Density ◽  
Co2 Capture ◽  
Coal Gasification ◽  
Combined Cycle ◽  
Energy Technology ◽  
Integrated Gasification Combined Cycle ◽  
Lower Efficiency ◽  
Integrated Gasification ◽  
Cold Gas

This paper examines the arrangement of a solid oxide fuel cell (SOFC) within a coal gasification cycle, this combination generally being called an integrated gasification fuel cell cycle. This work relies on a previous study performed by the National Energy Technology Laboratory (NETL) that details thermodynamic simulations of integrated gasification combined cycle (IGCC) systems and considers various gasifier types and includes cases for 90% CO2 capture (2007, “Cost and Performance Baseline for Fossil Energy Plants, Vol. 1: Bituminous Coal and Natural Gas to Electricity,” National Energy Technology Laboratory Report No. DOE/NETL-2007/1281). All systems in this study assume a Conoco Philips gasifier and cold-gas clean up conditions for the coal gasification system (Cases 3 and 4 in the NETL IGCC report). Four system arrangements, cases, are examined. Cases 1 and 2 remove the CO2 after the SOFC anode. Case 3 assumes steam addition, a water-gas-shift (WGS) catalyst, and a Selexol process to remove the CO2 in the gas cleanup section, sending a hydrogen-rich gas to the fuel cell anode. Case 4 assumes Selexol in the cold-gas cleanup section as in Case 3; however, there is no steam addition, and the WGS takes places in the SOFC and after the anode. Results demonstrate significant efficiency advantages compared with IGCC with CO2 capture. The hydrogen-rich case (Case 3) has better net electric efficiency compared with typical postanode CO2 capture cases (Cases 1 and 2), with a simpler arrangement but at a lower SOFC power density, or a lower efficiency at the same power density. Case 4 gives an efficiency similar to Case 3 but also at a lower SOFC power density. Carbon deposition concerns are also discussed.

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