scholarly journals Evaluation of Reduced Kinetics in Simulation of Gasified Biomass Gas Combustion

Author(s):  
Xiaoxiang Zhang ◽  
Nur Farizan Munjat ◽  
Jeevan Jayasuriya ◽  
Reza Fakhrai ◽  
Torsten Fransson

It is essentially important to use appropriate chemical kinetic models in the simulation process of gas turbine combustion. To integrate the detailed kinetics into complex combustion simulations has proven to be a computationally expensive task with tens to thousands of elementary reaction steps. It has been suggested that an appropriate simplified kinetics which are computationally efficient could be used instead. Therefore reduced kinetics are often used in CFD simulation of gas turbine combustion. At the same time, simplified kinetics for specific fuels and operation conditions need to be carefully selected to fulfill the accuracy requirements. The applicability of several simplified kinetics for premixed Gasified Biomass Gas (GBG) and air combustion are evaluated in this paper. The current work is motivated by the growing demand of gasified biomass gas (GBG) fueled combustion. Even though simplified kinetic schemes developed for hydrocarbon combustions are published by various researchers, there is little research has been found in literature to evaluate the ability of the simplified chemical kinetics for the GBG combustion. The numerical Simulation tool “CANTERA” is used in the current study for the comparison of both detailed and simplified chemical kinetics. A simulated gas mixture of CO/H2/CH4/CO2/N2 is used for the current evaluation, since the fluctuation of GBG components may have an unpredictable influence on the simulation results. The laminar flame speed has an important influence with flame stability, extinction limits and turbulent flame speed, here it is chosen as an indicator for validation. The simulation results are compared with the experimental data from the previous study [1] which is done by our colleagues. Water vapour which has shown a dilution effect in the experimental study are also put into concern for further validation. As the results indicate, the reduced kinetics which are developed for hydrocarbon or hydrogen combustion need to be highly optimized before using them for GBG combustion. Further optimization of the reduced kinetics is done for GBG and moderate results are achieved using the optimized kinetics compared with the detailed combustion kinetics.

Author(s):  
Marissa Brower ◽  
Eric Petersen ◽  
Wayne Metcalfe ◽  
Henry J. Curran ◽  
Marc Füri ◽  
...  

Applications of natural gas and hydrogen co-firing have received increased attention in the gas turbine market, which aims at higher flexibility due to concerns over the availability of fuels. While much work has been done in the development of a fuels database and corresponding chemical kinetics mechanism for natural gas mixtures, there are nonetheless few if any data for mixtures with high levels of hydrogen at conditions of interest to gas turbines. The focus of the present paper is on gas turbine engines with primary and secondary reaction zones as represented in the Alstom and Rolls Royce product portfolio. The present effort includes a parametric study, a gas turbine model study, and turbulent flame speed predictions. Using a highly optimized chemical kinetics mechanism, ignition delay times and laminar burning velocities were calculated for fuels from pure methane to pure hydrogen and with natural gas/hydrogen mixtures. A wide range of engine-relevant conditions were studied: pressures from 1 to 30 atm, flame temperatures from 1600 to 2200 K, primary combustor inlet temperature from 300 to 900 K, and secondary combustor inlet temperatures from 900 to 1400 K. Hydrogen addition was found to increase the reactivity of hydrocarbon fuels at all conditions by increasing the laminar flame speed and decreasing the ignition delay time. Predictions of turbulent flame speeds from the laminar flame speeds show that hydrogen addition affects the reactivity more when turbulence is considered. This combined effort of industrial and university partners brings together the know-how of applied, as well as experimental and theoretical disciplines.


Author(s):  
Philippe Versailles ◽  
Antoine Durocher ◽  
Gilles Bourque ◽  
Jeffrey M. Bergthorson

The adiabatic, unstrained, laminar flame speed, SL, is a fundamental combustion property, and a premier target for the development and validation of thermochemical mechanisms. It is one of the leading parameters determining the turbulent flame speed, the flame position in burners and combustors, and the occurrence of transient phenomena, such as flashback and blowout. At pressures relevant to gas turbine engines, SL is generally extracted from the continuous expansion of a spherical reaction front in a combustion bomb. However, independent measurements obtained in different types of apparatuses are required to fully constrain thermochemical mechanisms. Here, a jet-wall, stagnation burner designed for operation at gas turbine relevant conditions is presented, and used to assess the reactivity of premixed, lean-to-rich, methane–air flames at pressures up to 16 atm. One-dimensional (1D) profiles of axial velocity are obtained on the centerline axis of the burner using particle tracking velocimetry, and compared to quasi-1D flame simulations performed with a selection of thermochemical mechanisms available in the literature. Significant discrepancies are observed between the numerical and experimental data, and among the predictions of the mechanisms. This motivates further chemical modeling efforts, and implies that designers in industry must carefully select the mechanisms employed for the development of gas turbine combustors.


Author(s):  
Marissa Brower ◽  
Eric L. Petersen ◽  
Wayne Metcalfe ◽  
Henry J. Curran ◽  
Marc Füri ◽  
...  

Applications of natural gas and hydrogen co-firing have received increased attention in the gas turbine market, which aims at higher flexibility due to concerns over the availability of fuels. While much work has been done in the development of a fuels database and corresponding chemical kinetics mechanism for natural gas mixtures, there are nonetheless few if any data for mixtures with high levels of hydrogen at conditions of interest to gas turbines. The focus of the present paper is on gas turbine engines with primary and secondary reaction zones as represented in the Alstom and Rolls Royce product portfolio. The present effort includes a parametric study, a gas turbine model study, and turbulent flame speed predictions. Using a highly optimized chemical kinetics mechanism, ignition delay times and laminar burning velocities were calculated for fuels from pure methane to pure hydrogen and with natural gas/hydrogen mixtures. A wide range of engine-relevant conditions were studied: pressures from 1 to 30 atm, flame temperatures from 1600 to 2200 K, primary combustor inlet temperature from 300 to 900 K, and secondary combustor inlet temperatures from 900 to 1400 K. Hydrogen addition was found to increase the reactivity of hydrocarbon fuels at all conditions by increasing the laminar flame speed and decreasing the ignition delay time. Predictions of turbulent flame speeds from the laminar flame speeds show that hydrogen addition affects the reactivity more when turbulence is considered. This combined effort of industrial and university partners brings together the know-how of applied as well as experimental and theoretical disciplines.


Author(s):  
Philippe Versailles ◽  
Antoine Durocher ◽  
Gilles Bourque ◽  
Jeffrey M. Bergthorson

The adiabatic, unstrained, laminar flame speed, SL, is a fundamental combustion property, and a premier target for the development and validation of thermochemical mechanisms. It is one of the leading parameters determining the turbulent flame speed, the flame position in burners and combustors, and the occurrence of transient processes, such as flashback and blowout. At pressures relevant to gas turbine engines, SL is generally extracted from the continuous expansion of a spherical reaction front in a combustion bomb. However, independent measurements obtained in different types of apparatuses are required to fully constrain thermochemical mechanisms. Here, a jet-wall, stagnation burner designed for operation at gas turbine relevant conditions is presented, and used to assess the reactivity of premixed, lean-to-rich, methane-air flames at pressures up to 16 atm. One-dimensional (1D) profiles of axial velocity are obtained on the centreline axis of the jet-wall burner using Particle Tracking Velocimetry, and compared to quasi-1D flame simulations performed with a selection of thermochemical mechanisms available in the literature. Significant discrepancies are observed between the numerical and experimental data, and among the predictions of the mechanisms. This motivates further chemical modeling efforts, and implies that designers in industry must carefully select the mechanisms employed for the development of gas turbine combustors.


Author(s):  
George Mallouppas ◽  
Graham Goldin ◽  
Yongzhe Zhang ◽  
Piyush Thakre ◽  
Jim Rogerson

Abstract Three Flamelet Generated Manifold reaction source term closure options and two different reactor types are examined with Large Eddy Simulation of an industrial gas turbine combustor operating at 3 bar. This work presents the results for the SGT-100 Dry Low Emission (DLE) gas turbine provided by Siemens Industrial Turbomachinery Ltd. The related experimental study was performed at the German Aerospace Centre, DLR, Stuttgart, Germany. The FGM model approximates the thermo-chemistry in a turbulent flame as that in a simple 0D constant pressure ignition reactors and 1D strained opposed-flow premixed reactors, parametrized by mixture fraction, progress variable, enthalpy and pressure. The first objective of this work is to compare the flame shape and position predicted by these two FGM reactor types. The Kinetic Rate (KR) model, studied in this work, uses the chemical rate from the FGM with assumed shapes, which are a Beta function for mixture fraction and delta functions for reaction progress variable and enthalpy. Another model investigated is the Turbulent Flame-Speed Closure (TFC) model with Zimont turbulent flame speed, which propagates premixed flame fronts at specified turbulent flame speeds. The Thickened Flame Model (TFM), which artificially thickens the flame to sufficiently resolve the internal flame structure on the computational grid, is also explored. Therefore, a second objective of this paper is to compare KR, TFC and TFM with the available experimental data.


Author(s):  
Ehsan Abbasi-Atibeh ◽  
Sandeep Jella ◽  
Jeffrey M. Bergthorson

Sensitivity to stretch and differential diffusion of chemical species are known to influence premixed flame propagation, even in the turbulent environment where mass diffusion can be greatly enhanced. In this context, it is convenient to characterize flames by their Lewis number (Le), a ratio of thermal-to-mass diffusion. The work reported in this paper describes a study of flame stabilization characteristics when the Le is varied. The test data is comprised of Le ≪ 1 (Hydrogen), Le ≈ 1 (Methane), and Le > 1 (Propane) flames stabilized at various turbulence levels. The experiments were carried out in a Hot exhaust Opposed-flow Turbulent Flame Rig (HOTFR), which consists of two axially-opposed, symmetric turbulent round jets. The stagnation plane between the two jets allows the aerodynamic stabilization of a flame, and clearly identifies fuel influences on turbulent flames. Furthermore, high-speed Particle Image Velocimetry (PIV), using oil droplet seeding, allowed simultaneous recordings of velocity (mean and rms) and flame surface position. These experiments, along with data processing tools developed through this study, illustrated that in the mixtures with Le ≪ 1, turbulent flame speed increases considerably compared to the laminar flame speed due to differential diffusion effects, where higher burning rates compensate for the steepening average velocity gradient, and keeps these flames almost stationary as bulk flow velocity increases. These experiments are suitable for validating the ability of turbulent combustion models to predict lifted, aerodynamically-stabilized flames. In the final part of this paper, we model the three fuels at two turbulence intensities using the FGM model in a RANS context. Computations reveal that the qualitative flame stabilization trends reproduce the effects of turbulence intensity, however, more accurate predictions are required to capture the influences of fuel variations and differential diffusion.


Author(s):  
Alireza Kalantari ◽  
Nicolas Auwaijan ◽  
Vincent McDonell

Abstract Lean-premixed combustion is commonly used in gas turbines to achieve low pollutant emissions, in particular nitrogen oxides. But use of hydrogen-rich fuels in premixed systems can potentially lead to flashback. Adding significant amounts of hydrogen to fuel mixtures substantially impacts the operating range of the combustor. Hence, to incorporate high hydrogen content fuels into gas turbine power generation systems, flashback limits need to be determined at relevant conditions. The present work compares two boundary layer flashback prediction methods developed for turbulent premixed jet flames. The Damköhler model was developed at University of California Irvine (UCI) and evaluated against flashback data from literature including actual engines. The second model was developed at Paul Scherrer Institut (PSI) using data obtained at gas turbine premixer conditions and is based on turbulent flame speed. Despite different overall approaches used, both models characterize flashback in terms of similar parameters. The Damköhler model takes into account the effect of thermal coupling and predicts flashback limits within a reasonable range. But the turbulent flame speed model provides a good agreement for a cooled burner, but shows less agreement for uncooled burner conditions. The impact of hydrogen addition (0 to 100% by volume) to methane or carbon monoxide is also investigated at different operating conditions and flashback prediction trends are consistent with the existing data at atmospheric pressure.


2014 ◽  
Vol 39 (35) ◽  
pp. 20242-20254 ◽  
Author(s):  
Yu-Chun Lin ◽  
Peter Jansohn ◽  
Konstantinos Boulouchos

2000 ◽  
Vol 124 (1) ◽  
pp. 58-65 ◽  
Author(s):  
W. Polifke ◽  
P. Flohr ◽  
M. Brandt

In many practical applications, so-called premixed burners do not achieve perfect premixing of fuel and air. Instead, fuel injection pressure is limited, the permissible burner pressure drop is small and mixing lengths are curtailed to reduce the danger of flashback. Furthermore, internal or external piloting is frequently employed to improve combustion stability, while part-load operation often requires burner staging, where neighboring burners operate with unequal fuel/air equivalence ratios. In this report, an extension of the turbulent flame speed closure (TFC) model for highly turbulent premixed combustion is presented, which allows application of the model to the case of inhomogeneously premixed combustion. The extension is quite straightforward, i.e., the dependence of model parameters on mixture fraction is accounted for by providing appropriate lookup tables or functional relationships to the model. The model parameters determined in this way are adiabatic flame temperature, laminar flame speed and critical gradient. The model has been validated against a test case from the open literature and applied to an externally piloted industrial gas turbine burner with good success.


2012 ◽  
Vol 13 (5) ◽  
pp. 464-481 ◽  
Author(s):  
Udo Gerke ◽  
Konstantinos Boulouchos

The mixture formation and combustion process of a hydrogen direct-injection internal combustion engine is computed using a modified version of a commercial three-dimensional computational fluid dynamics code. The aim of the work is the evaluation of hydrogen laminar flame speed correlations and turbulent flame speed closures with respect to combustion of premixed and stratified mixtures at various levels of air-to-fuel equivalence ratio. Heat-release rates derived from in-cylinder pressure traces are used for the validation of the combustion simulations. A turbulent combustion model with closures for a turbulent flame speed is investigated. The value of the computed heat-release rates mainly depends on the quality of laminar burning velocities and standard of turbulence quantities provided to the combustion model. Combustion simulations performed with experimentally derived laminar flame speed data give better results than those using laminar flame speeds obtained from a kinetic scheme. However, experimental data of hydrogen laminar flame speeds found in the literature are limited regarding the range of pressures, temperatures and air-to-fuel equivalence ratios, and do not comply with the demand of high-pressure engine-relevant conditions.


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