The Strategy of the Belgian Nuclear Research Centre in the Area of High-Level Waste Form Compatibility Research

2007 ◽  
Author(s):  
Karel Lemmens ◽  
Christelle Cachoir ◽  
Elie Valcke ◽  
Karine Ferrand ◽  
Marc Aertsens ◽  
...  
Keyword(s):  
Nuclear Research ◽  
Waste Form ◽  
Research Centre ◽  
High Level Waste ◽  
Spent Fuel ◽  
National Agency ◽  
Waste Forms ◽  
In Situ Experiments ◽  
High Level

The Belgian Nuclear Research Centre (SCK•CEN) has a long-standing expertise in research concerning the compatibility of waste forms with the final disposal environment. For high level waste, most attention goes to two waste forms that are relevant for Belgium, namely (1) vitrified waste from the reprocessing of spent fuel, and (2) spent fuel as such, referring to the direct disposal scenario. The expertise lies especially in the study of the chemical interactions between the waste forms and the disposal environment. This is done by laboratory experiments, supported by modeling. The experiments vary from traditional leach tests, to more specific tests for the determination of particular parameters, and highly realistic experiments. This results in a description of the phenomena that are expected upon disposal of the waste forms, and in quantitative data that allow a conservative long-term prediction of the in situ life time of the waste form. The predictions are validated by in situ experiments in the underground research laboratory HADES. The final objective of these studies, is to estimate the contribution of the waste form to the overall safety of the disposal system, as part of the Safety and Feasibility Case, planned by the national agency ONDRAF/NIRAS. The recent change of the Belgian disposal concept from an engineered barrier system based on the use of bentonite clay to a system based on a concrete buffer has caused a reorientation of the research programme. The expertise in the area of clay-waste interaction will however be maintained, to develop experimental methodologies in collaboration with other countries, and as a potential support to the decision making in those countries where a clay based near field is still the reference. The paper explains the current R&D approach, and highlights some recent experimental set-ups available at SCK•CEN for this purpose, with some illustrating results.

scholarly journals Spent Fuel as a Waste Form - Data Needs to Allow Long Term Performance Assessment Under Repository Disposal Conditions.

1986 ◽  
Vol 84 ◽  
Author(s):  
V. M. Oversby
Keyword(s):  
Performance Assessment ◽  
Waste Form ◽  
High Level Waste ◽  
Detailed Knowledge ◽  
Spent Fuel ◽  
Expected Performance ◽  
High Level ◽  
Term Performance ◽  
Physical And Chemical ◽  
Waste Repositories

AbstractPerformance assessment calculations are required for high level waste repositories for a period of 10,000 years under NRC and EPA regulations. In addition, the Siting Guidelines (IOCFR960) require a comparison of sites following site characterization and prior to final site selection to be made over a 100,000 year period. In order to perform the required calculations, a detailed knowledge of the physical and chemical processes that affect waste form performance will be needed for each site. While bounding calculations might be sufficient to show compliance with the requirements of IOCFR60 and 40CFRI91, the site comparison for 100,000 years will need to be based on expected performance under site specific conditions. The only case where detailed knowledge of waste form characteristics in the repository would not be needed would be where radionuclide travel times to the accessible environment can be shown to exceed 100,000 years. This paper will review the factors that affect the release of radionuclides from spemt fuel under repository conditions, summarize our present state of knowledge, and suggest areas where more work is needed in order to support the performance assessment calculations.

Dry Storage of Spent Research Reactor Fuel in Castor BR3® Casks at Belgoprocess in Belgium

2001 ◽  
Author(s):  
Marnix Braeckeveldt ◽  
Luc Ooms ◽  
Gustaaf Geenen
Keyword(s):  
Radioactive Waste ◽  
Nuclear Research ◽  
High Level Waste ◽  
Spent Fuel ◽  
Fuel Rods ◽  
Dry Storage ◽  
Nuclear Site ◽  
Test Reactor ◽  
Intermediate Storage ◽  
High Level

Abstract The BR3 reactor (10.5 MWe) at the Nuclear Research Center SCK•CEN was the first PWR plant installed in Europe and has been shut down in 1987. The BR3 reactor is from 1989 in a decommissioning stage and most of the spent fuel is presently still stored in the deactivation pool of the BR3 plant and has to be evacuated. The BR3 was used as a test-reactor for new fuel types and assemblies (Mixed Oxide (MOX) fuel, fuel rods containing burnable poison (Gd2O3) and other types of fuels). Some fuel rods, having undergone a destructive analysis, are stored in different laboratories at the SCK•CEN. In total, the BR3 spent fuel comprises the equivalent of almost 200 fuel assemblies corresponding to some 5000 fuel rods. Beside the spent BR3 fuel, a limited number of spent fuel rods, with equivalent characteristics as the BR3 fuel but irradiated in research reactors outside Belgium and stored in other buildings at the SCK•CEN nuclear site, were added to the inventory of spent fuel to be evacuated. Various options such as reprocessing and intermediate storage awaiting final disposal were evaluated against criteria as available techniques, safety, waste production and overall costs. Finally the option of an AFR (away-from-reactor) intermediate dry storage of the BR3 and other spent fuel in seven CASTOR BR3® casks was adopted. As the SCK•CEN declared this spent fuel as radioactive waste, NIRAS/ONDRAF, the Belgian radioactive waste management agency became directly involved and the decision was taken to construct a small building at the Belgoprocess nuclear site for storing the CASTOR BR3® casks. Loading at the SCK•CEN followed by transport to Belgoprocess and storage is scheduled to take place at the end of 2001. The CASTOR BR3® cask weighing some 25 tonnes, consists of a monolithic body and has two independent lids with metal seals guaranteeing the long term leak-tightness of the cask. The CASTOR BR3® cask is designed for transport and the intermediate storage of at least 50 years. Although a defect of the leaktightness of a CASTOR BR3® cask is very unlikely to occur, an intervention scenario had to be developed. As no pool is present at the Belgoprocess nuclear site to unload the fuel, an innovative procedure is developed that consists of transferring the basket, containing the spent fuel, into another CASTOR BR3® cask. This operation can be performed in the hot cell of the existing storage building for high level waste at the Belgoprocess site.

Characterization of Mechanical Strengths for Simulated High-Level Waste Forms

1989 ◽  
Vol 176 ◽  
Author(s):  
Hiroshi Igarashi ◽  
Takeshi Takahashi
Keyword(s):  
Fracture Toughness ◽  
Glass Ceramic ◽  
Bending Strength ◽  
Liquid Waste ◽  
High Level Waste ◽  
Spent Fuel ◽  
High Level Liquid Waste ◽  
Waste Forms ◽  
High Level ◽  
Mechanical Strengths

ABSTRACTWaste forms have been developed and characterized at PNC (Power Reactor and Nuclear Fuel Development Corporation)to immobilize high-level liquid waste generated from the reprocessing of nuclear spent fuel.Mechanical strength tests were excecuted on simulated solidified highlevel waste forms which were borosilicate glass and diopside glass-ceramic. Commercial glass was tested for comparison. Measured strengths were three-point bending strength,uniaxial compressive strength,impact strength by falling weight method,and Vickers hardness. Fracture toughness and fracture surface energy were also measured by both notch-beam and indentation technique.The results show that mechanical strengths of waste glass form are similar and that the glass ceramic form has the higher fracture toughness.

In-Situ Testing of Nuclear Waste Glasses in a Clay Laboratory - Results After Two Years Corrosion

1989 ◽  
Vol 176 ◽  
Author(s):  
P. Van Iseghem ◽  
W. Timmermans ◽  
B. Neerdael
Keyword(s):  
Analytical Data ◽  
Waste Form ◽  
Laboratory Simulation ◽  
High Level Waste ◽  
In Situ Experiment ◽  
Boom Clay ◽  
Major Mechanism ◽  
Mechanism Of Interaction ◽  
High Level

ABSTRACTThe first retrieval of an in-situ experiment on the interaction waste form - clay host in the underground laboratory under the Mol site has been finished successfully. The test consisted in a two years exposure of various candidate simulated waste glasses at 90°C to Boom clay. The retrieval was done by overcoring. The experimental data showed satisfactorily correspondence between in-situ and laboratory simulation tests both for mass loss and surface analytical data, supporting the validity of the in-situ test as it was performed. The thickness of waste form dissolved within two years varies between 40 and 325 μm (case of the high-level waste glasses), depending on the composition. Matrix dissolution is expected to be the major mechanism of interaction.

The IAEA Coordinated Research Programme on the Performance of High-Level Waste Forms and Packages Under Repository Conditions

1992 ◽  
Vol 294 ◽  
Author(s):  
Vladimir S. Tsyplenkov
Keyword(s):  
Near Field ◽  
Research Programme ◽  
High Level Waste ◽  
Future Research ◽  
Spent Fuel ◽  
Waste Forms ◽  
Safety Assessments ◽  
High Level ◽  
Coordination Meeting

ABSTRACTThe IAEA initiated, in 1991, a Coordinated Research Programme (CRP), with the aim of promoting the exchange of information on the results obtained by different countries in the performance of high-level waste forms and waste packages under conditions relevant to final repository. These studies are being undertaken to obtain reliable data as input to safety assessments and environmental impact analyses, for final disposal purposes. The CRP includes studies on waste forms that are presently of interest worldwide: borosilicate glass, Synroc and spent fuel.Ten laboratories leading in investigation of high-level waste form performance have already joined the programme. The results of their studies and plans for future research were presented at the first Research Coordination Meeting, held in Karlsruhe, Germany, in November 1991. The technical contributions concentrated on effecting an understanding of dissolution mechanisms of waste forms under simulated repository conditions. A quantitative interpretation of the chemical processes in the near field is considered a prerequisite for long-term predictions and for the formulation of a "source term" for performance assessment studies.

scholarly journals Solubility Limits. on Radionuclide Dissolution

1984 ◽  
Vol 44 ◽  
Author(s):  
Jerry F. Kerrisk
Keyword(s):  
Yucca Mountain ◽  
Waste Form ◽  
High Level Waste ◽  
Spent Fuel ◽  
Dissolution Rates ◽  
Diffusion Limited ◽  
Dissolution Model ◽  
High Level

AbstractThis paper examines the effects of solubility in limiting dissolution rates of a number of important radionuclides from spent fuel and high-level waste. Two simple dissolution models were used for calculations that would be characteristic of a Yucca Mountain repository. A saturation-limited dissolution model, in which the water flowing through the repository is assumed to be saturated with each waste element, is very conservative in that it overestimates dissolution rates. A diffusion-limited dissolution model, in which element-dissolution rates are limited by diffusion of waste elements into water flowing past the waste, is more realistic, but it is subject to some uncertainty at this time. Dissolution rates of some elements (Pu, Am, Sn, Th, Zr, Sm) are always limited by solubility. Dissolution rates of other elements (Cs, Tc, Np, Sr, C, I) are never solubility limited; their release would be limited by dissolution of the bulk waste form. Still other elements (U, Cm, Ni, Ra) show solubility-limited dissolution under some conditions.

Geopolymers as Candidates for the Immobilisation of Low- and Intermediate-Level Waste

2006 ◽  
Vol 985 ◽  
Author(s):  
Eric Vance ◽  
Eric Vance ◽  
Satoshi Kiyama ◽  
Zaynab Aly ◽  
Patrick Yee
Keyword(s):  
Amorphous Material ◽  
Intermediate Level ◽  
Waste Form ◽  
High Level Waste ◽  
Waste Forms ◽  
Phosphate Compound ◽  
Waste Loading ◽  
Saturation Effects ◽  
High Level ◽  
B Test

AbstractGeopolymers should be serious waste form candidates for intermediate level waste (ILW), insofar as they are more durable than Portland cement and can pass the PCT-B test for high-level waste. Thus an alkaline ILW could be considered to be satisfactorily immobilised in a geopolymer formulation. However a simulated Hanford tank waste was found to fail the PCT-B criterion even for a waste loading as low as 5 wt%, very probably due to the formation of a soluble sodium phosphate compound(s). This suggests that it could be worth developing a “mixed” GP waste form in which the amorphous material can immobilise cations and a zeolitic component to immobilise anions. The PCT -B test is demonstrably subject to significant saturation effects, especially for relatively soluble waste forms.

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