New sample stage for characterizing radioactive materials by X-ray powder diffraction: application on five actinide dioxides ThO2, UO2, NpO2, PuO2 and AmO2

A new sample stage for characterizing radioactive materials by X-ray powder diffraction was developed at the ATALANTE facility (CEA Marcoule, France) using a conventional (non-nuclearized) Bruker D8 goniometer mounted in Bragg–Brentano geometry. The setup consists of a removable, fully hermetic sample stage, with a 200 µm-thick beryllium window, that can be plugged onto a glove-box, allowing the sample to be introduced in an hermetic medium that also encapsulates the glove-box atmosphere throughout the analysis process. The whole setup is thus hermetically unplugged from the glove-box and positioned on the centre of the goniometer. No preliminary decontamination and/or decontainment of the sample is necessary. The device was developed to avoid an expensive and time-consuming nuclearization of the diffractometer while also keeping it easily accessible for maintenance. Ultimately, keeping the diffractometer out of a glove-box also limits the volume of the final nuclear wastes, and thus the removable sample stage is the only `active' part. X-ray diffraction results of two NIST standards LaB6 and α-Al2O3 as well as five actinide dioxides ThO2, UO2, NpO2, PuO2 and AmO2 are presented to show the efficiency of the setup.

Robustness Study of Electro-Nuclear Scenario under Disruption

As the future of nuclear power is uncertain, only choosing one development objective for the coming decades can be risky; while trying to achieve several possible objectives at the same time may lead to a deadlock due to contradiction among them. In this work, we study a simple scenario to illustrate the newly developed method of robustness study, which considers possible change of objectives. Starting from the current French fleet, two objectives are considered regarding the possible political choices for the future of nuclear power: A. Complete substitution of Pressurized Water Reactors by Sodium-cooled Fast Reactors in 2180; B. Minimization of all potential nuclear wastes without SFR deployment in 2180. To study the robustness of strategies, the disruption of objective is considered: the objective to be pursued is possibly changed abruptly from A into B at unknown time. To minimize the consequence of such uncertainty, the first option is to identify a robust static strategy, which shows the best performance for both objectives A and B in the predisruption situation. The second option is to adapt a trajectory which pursues initially objective A, for objective B in case of the disruption. To identify and to analyze the adaptively robust strategies, outcomes of possible adaptations upon a given trajectory are compared with the robust static optimum. The temporality of adaptive robustness is analyzed by investigating different adaptation times.

CN linked covalent organic framework for the efficient adsorption of iodine in vapor and solution

Volatile nuclear wastes, such as iodine, have received worldwide attention because it poses risks to public safety and pollutes the environment.