Laminar Flame Characteristics of Partially Premixed Palm Methyl Ester Gas Flames

Author(s):  
Diego Romero ◽  
Ramkumar N. Parthasarathy ◽  
Subramanyam R. Gollahalli

Palm methyl ester (PME) is a renewable biofuel that is produced by the transesterification of palm oil; it is a popular alternative fuel used in the transportation sector. The objective of this investigation was to study the combustion characteristics of flames of pre-vaporized diesel and PME in a laminar flame environment at initial equivalence ratios of 2, 3 and 7 and to isolate the factors attributable to chemical structure of the fuel. The equivalence ratio was changed by altering the fuel flow rate, while maintaining the air flow rate constant. The global CO emission index of the PME flames was significantly lower than that of the diesel flames; however, the global NO emission index was comparable. The radiative fraction of heat release and the soot volume fraction were lower for the PME flames compared to the diesel flames. The peak temperatures were comparable at an equivalence ratio of 2, but at higher equivalence ratios, the peak temperatures in the PME flames were higher. The measurements highlight the differences in the combustion properties of biofuels and petroleum fuels and the coupling effects of equivalence ratio.

2014 ◽  
Vol 136 (3) ◽  
Author(s):  
D. Romero ◽  
R. N. Parthasarathy ◽  
S. R. Gollahalli

Palm methyl ester (PME) is a renewable biofuel that is produced by the transesterification of palm oil and is a popular alternative fuel used in the transportation sector, particularly in Asia. The objective of this investigation was to study the combustion characteristics of flames of prevaporized number 2 diesel and PME in a laminar flame environment at initial equivalence ratios of 2, 3, and 7 and to isolate the factors attributable to chemical structure of the fuel. The equivalence ratio was changed by altering the fuel flow rate, while maintaining the air flow rate constant. The global CO emission index of the PME flames was significantly lower than that of the diesel flames; however, the global NO emission index was comparable. The radiative fraction of heat release and the soot volume fraction were lower for the PME flames compared to those in the diesel flames. The peak temperatures were comparable in both flames at an equivalence ratio of 2, but at higher equivalence ratios, the peak temperatures in the PME flames were higher. The measurements highlight the differences in the combustion properties of biofuels and petroleum fuels and the coupling effects of equivalence ratio.


Author(s):  
Arun Balakrishnan ◽  
Ramkumar N. Parthasarathy ◽  
Subramanyam R. Gollahalli

Biofuels, such as palm methyl ester (PME), are attractive alternates to petroleum fuels. In order to isolate the effects of fuel chemistry on the combustion properties, laminar partially premixed pre-vaporized flames of blends of Jet-A and PME (volume concentrations of 25%, 50%, 75% PME) were studied. A stainless steel circular tube (ID of 9.5 mm) served as the burner. The liquid fuel was supplied with a syringe pump into a high temperature (390°C) air flow to vaporize it completely without coking. The fuel flow rate was maintained constant and the air flow rate adjusted to obtain burner-exit equivalence ratios of 2, 3 and 7. The global flame properties including flame length, CO and NO emission indices, radiative heat fraction and in-flame properties including gas concentration (CO, CO2, NO, O2), temperature and soot volume fraction were measured. The near-burner homogeneous gas-phase reaction zone increased in length with the addition of PME at all equivalence ratios. The concentration and global emission measurements highlight the non-monotonic variation of properties with the volume concentration of PME in the fuel. The fuel-bound oxygen of PME affected the combustion properties significantly.


2015 ◽  
Vol 138 (1) ◽  
Author(s):  
A. Balakrishnan ◽  
R. N. Parthasarathy ◽  
S. R. Gollahalli

Palm methyl ester (PME) is an attractive alternate biofuel produced by the transesterification of palm oil with methanol. This paper is a sequel to our earlier papers on the comparison of the flame structure and emission characteristics of neat PME with those of petroleum-derived fuels (No. 2 diesel and neat Jet A). Blends of prevaporized Jet A fuel and PME (25%, 50%, and 75% by volume) were studied in a laminar flame environment at burner-exit equivalence ratios of 2, 3, and 7. The global combustion characteristics including flame length, CO and NO emission indices, radiative heat fraction, and in-flame profiles of species concentration (CO, CO2, NO, and O2), temperature, and soot volume concentration were measured. The global CO emission index decreased significantly with the PME content in the blend at an equivalence ratio of 7; a 30% reduction was observed with the addition of 25% PME by volume, and a further reduction of 25% was observed with the addition of another 25% PME. The global NO emission index of the neat PME flame was 35% lower than that of the Jet A flame at an equivalence ratio of 2. The near-burner homogeneous gas-phase reaction zone increased in length with the addition of PME at all equivalence ratios. The concentration measurements highlighted the nonmonotonic variation of properties with the volume concentration of PME in the fuel blend. The fuel-bound oxygen and hydrogen of PME affected the combustion properties significantly.


2011 ◽  
Vol 2011 ◽  
pp. 1-13 ◽  
Author(s):  
N. Dhamale ◽  
R. N. Parthasarathy ◽  
S. R. Gollahalli

Canola methyl ester (CME) is a biofuel that is a renewable alternative energy resource and is produced by the transesterification of canola oil. The objective of this study was to document the effects of turbulence on the combustion characteristics of blends of CME and No 2 diesel fuel in a partially-premixed flame environment. The experiments were conducted with mixtures of pre-vaporized fuel and air at an initial equivalence ratio of 7 and three burner exit Reynolds numbers, 2700, 3600, and 4500. Three blends with 25, 50, and 75% volume concentration of CME were studied. The soot volume fraction was highest for the pure diesel flames and did not change significantly with Reynolds number due to the mutually compensating effects of increased carbon input rate and increased air entrainment as the Reynolds number was increased. The global NOx emission index was highest and the CO emission index was the lowest for the pure CME flame, and varied non-monotonically with biofuel content in the blend The mean temperature and the NOx concentration at three-quarter flame height were generally correlated, indicating that the thermal mechanism of NOx formation was dominant in the turbulent biofuel flames also.


Author(s):  
H. Sapmaz ◽  
C. Ghenai

Laser-Induced Incandescence (LII) is used in this study to measure soot volume fractions in steady and flickering ethylene diffusion flames burning at atmospheric pressure. Better understanding of flickering flame behavior also promises to improve understanding of turbulent combustion systems. A very-high-speed solenoid valve is used to force the fuel flow rate with frequencies between 10 Hz and 200 Hz with the same mean fuel flow rate of steady flame. Periodic flame flickers are captured by two-dimensional phase-locked emission and LII images for eight phases (0°–360°) covering each period. LII spectra scan for minimizing C2 swan band emission and broadband molecular florescence, a calibration procedure using extinction measurements, and corrections for laser extinction and LII signal trapping are carried out towards developing reliable LII for quantitative applications. A comparison between the steady and pulsed flames results and the effect of the oscillation frequency on soot volume fraction for the pulsed flames are presented.


2020 ◽  
Vol 10 (10) ◽  
pp. 3416
Author(s):  
Bui Van Ga ◽  
Pham Quoc Thai

Combustion characteristics and harmful emissions with emphasized soot emission in the new concept of a biogas-dimethyl ether (DME) hybrid dual-fuel engine were analyzed. The effects of DME content, biogas compositions and diesel injection were examined. At any biogas composition, a rise in DME content in the fuel mixture leads to an increase in indicative engine cycle work (Wi) and NOx but a decrease in CO and soot volume fraction (fv). The effects of DME on Wi and soot volume fraction are more significant for poor biogas than for rich biogas, contrary to its effect tendency on CO and NOx concentrations. With a given operating condition and DME content, the biogas compositions slightly affect the performance and emission of a biogas-DME hybrid dual-fuel engine. At a fixed global equivalence ratio, the reduction of diesel injection leads to an increase in Wi and NOx concentration but a decrease in CO and soot volume fraction. The lower the diesel injection is, the more significant the effects of DME content on the combustion properties and pollutant emissions are. At a given operating condition and the same global equivalence ratio, the biogas-DME PCCI combustion mode is more advantageous than biogas-DME dual-fuel combustion mode. The substitution of diesel pilot ignition by DME pilot ignition in a biogas-DME hybrid dual engine is the optimal solution for both performance improvement and pollution emissions reduction.


Author(s):  
Fengshan Liu ◽  
Kevin A. Thomson ◽  
Gregory J. Smallwood

Investigation of the effect of oxygen addition to fuel on the visible flame appearance and soot formation characteristics of laminar diffusion flames is important to gain comprehensive understanding of gas-phase combustion chemistry and its interaction with soot chemistry. This paper reports experimental results of oxygen addition to fuel on the visible flame height and soot volume fraction distributions in axisymmetric coflow laminar ethylene and propane diffusion flames at atmospheric flames. The carbon flow rate was maintained constant in all the experiments. Although many experimental studies have been conducted in the literature in this topic, the present investigation aimed at providing spatially resolved soot volume fraction distributions over the entire range of oxygen addition from no oxygen addition up to the point of flashback while keeping the carbon mass flow rate constant. The level of oxygen added to fuel right before flashback is about 45% (the percentage of oxygen addition is always by volume in this study) of the fuel flow rate in the ethylene flame and 300% of the fuel flow rate in the propane flame. As the added oxygen amount to ethylene increases, the visible flame height first increases. When the added oxygen flow rate is about 13% of the fuel flow rate, the flame becomes smoking, i.e., soot escapes from the flame tip. When the oxygen flow rate reaches about 42% of the fuel flow rate, the flame stops smoking. When oxygen was added to propane, the visible flame height linearly decreases with increasing the amount of oxygen. These very different effects of oxygen addition to ethylene and propane indicate that oxygen plays a drastically different role in the chemical pathways leading to soot formation in ethylene and propane flames. Distributions of soot volume fractions in these flames were measured using a 2D light attenuation technique coupled with the Abel inversion. The present study provides valuable experimental data for validating soot models.


2013 ◽  
Author(s):  
Cory D. Morton ◽  
Victor H. Tran ◽  
Ramkumar N. Parthasarathy ◽  
Subramanyam R. Gollahalli

The combustion characteristics of spray flames of canola methyl ester (CME) and blends with diesel fuel within a re-radiating environment were studied. The combustion chamber was lined with refractory bricks that were preheated to about 725 K (1305 °R). The flow rates of the fuels provided a constant heat release rate of about 7.33 kW (25,000 BTU/hr) at atmospheric pressure. Measurements of flame temperature, in-flame concentrations, global emissions, flame radiation and soot volume fraction were taken. The global CO emission index was significantly lower in the biofuel blend spray flames compared to that of the diesel spray flame. The global NO emission index was comparable for all spray flames, which agreed with peak flame temperature and in-flame NO concentration measurements. The radiative fraction of heat release was also comparable for all spray flames.


2014 ◽  
Author(s):  
Michael S. Richichi ◽  
Ramkumar N. Parthasarathy ◽  
Subramanyam R. Gollahalli

Palm Methyl Ester (PME) is an attractive alternate fuel to petroleum diesel because it can be produced from a renewable source, is close to being carbon-neutral in the environment, and has many properties similar to those of petroleum fuels. Although a few engine studies have been completed using PME, basic studies on the combustion of PME sprays are limited. Hence, the objective of this investigation was to study the combustion characteristics of spray flames of PME and diesel at three equivalence ratios: 0.4, 0.6 and 0.8. The liquid fuel was atomized and combusted with air in a heated environment; the coflow air temperature was maintained at 65% of the midpoint of the boiling point range of the fuels. The equivalence ratio was changed by altering the fuel flow rate, while maintaining the atomizing and coflow air flow rates constant, thus maintaining the gas velocity field invariant. The PME flames were shorter and less luminous than the diesel flames and had significant near-burner homogeneous-gas-phase reaction zones. The global CO emission index of the PME flames was higher than that of diesel flames at equivalence ratios of 0.4 and 0.6. The NO emission index of the PME flames was almost twice that of the diesel flames. The in-flame concentration profiles highlighted the effects of the significant fuel-bound oxygen content in PME.


Author(s):  
H. Sapmaz ◽  
C. Ghenai

Laser-Induced Incandescence (LII) is used in this study to measure soot volume fractions in steady and flickering ethylene diffusion flames burning at atmospheric pressure. Better understanding of flickering flame behavior also promises to improve understanding of turbulent combustion systems. A very-high-speed solenoid valve is used to force the fuel flow rate with frequencies between 10 Hz and 200 Hz with the same mean fuel flow rate of steady flame. Periodic flame flickers are captured by two-dimensional phase-locked emission and LII images for eight phases (0° - 360°) covering each period. LII spectra scan for minimizing C2 swan band emission and broadband molecular florescence, a calibration procedure using extinction measurements, and corrections for laser extinction and LII signal trapping are carried out towards developing reliable LII for quantitative applications. A comparison between the steady and pulsed flames results and the effect of the oscillation frequency on soot volume fraction for the pulsed flames are presented.


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