Fabrication of Efficient Electrodes for Dye-Sensitized Solar Cells Using Additive Manufacturing

Author(s):  
Sagil James ◽  
Rinkesh Contractor ◽  
Chris Veyna ◽  
Galen Jiang

Dye-Sensitized Solar Cells (DSSC) are third generation solar cells used as an alternative to c-Si solar cells. DSSC are mostly flexible, easier to handle and are less susceptible to damage compared to c-Si solar cells. Additionally, DSSC is an excellent choice for indoor application as they perform better under diverse light condition. Most DSSCs are made of liquid medium sandwiched between two conductive polymer layers. However, DSSCs have significantly lower efficiencies compared to silicon solar cells. Also, use of liquid medium resulting in leaking of liquid, and occasional freezing during cold weather, and thermal expansion during hot weather conditions. DSSC can be manufactured in small quantities using relatively inexpensive solution-phase techniques such as roll-to-roll processing and screen printing technology. However, scaling-up the DSSC manufacturing from small-scale laboratory tests to sizeable industrial production requires better and efficient manufacturing processes. This research studies the feasibility of using additive manufacturing technique to fabricate electrodes of DSSC. The study aims to overcome the limitations of DSSCs including preventing leakage and providing more customized design. Experimental studies are performed to evaluate the effects of critical process parameters affecting the quality of electrodes for DSSC. Volume resistivity test is performed to evaluate the efficiency of the electrodes. In this study, the electrodes of DSSC are successfully fabricated using Fused Disposition Modeling (FDM) 3D printing technique. The results of this study would enable additive manufacturing technology towards rapid commercialization of DSSC technology.

2007 ◽  
Vol 119 ◽  
pp. 315-318
Author(s):  
Won Jae Lee ◽  
Easwaramoorthi Ramasamy ◽  
Dong Yoon Lee ◽  
Jae Sung Song

Dye sensitized solar cells (DSSC) have great potential alternative to expensive conventional solar cells, since high efficiency and relatively simple fabrication process. However, in large size cell, there is a key factor that delayed the entry of such cells in commercial market. Performance of large size cell is lower than small size cells, since a carrier loss occurs in high resistive TCO glass substrate. Here we demonstrate a simple method to reduce resistive loss and efficient collection of photo generated carriers via strip type cells with metal grids. Using strip type cells, we constitute series and parallel type DSSC panels in order to achieve required voltage and current respectively. Stripe cells were prepared from commercial TiO2 powder by screen printing method. In addition, metal grids were established adjacent to sealant line. Using these as unit cell, portable DSSC panels were assembled and I-V performance was carried out in indoor light condition (fluorescent light, 30mW/cm2) and standard condition (Pin 100 mW/cm2, AM 1.5).


2021 ◽  
Vol 9 ◽  
Author(s):  
Sarawut Tontapha ◽  
Pikaned Uppachai ◽  
Vittaya Amornkitbamrung

Dye-sensitized solar cells (DSSCs) have been developed as a promising photovoltaic cell type in recent decades because of their low cost, environmental friendliness, ease of fabrication, and suitability for a wide range of indoor and outdoor applications, especially under diverse shaded and low-light condition. They are typically composed of three main components: a transparent conducting oxide (TCO) substrate-based working electrode with wide-bandgap semiconductors and dye sensitizer molecules, an electrolytic mediator based on redox couple species, and a TCO-based counter electrode consisting of catalyst materials. The development of intrinsic and functional organic, inorganic, metal oxide, composite, and carbon-based materials has been intensively studied to enhance the efficiency of DSSCs. A simple and low-cost fabrication process that uses natural products is also considered essential for further large-scale production. In this article, we review the fabrication of various functional materials and their effects on DSSC performance.


Materials ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 1741 ◽  
Author(s):  
Dong-Suk Lim ◽  
Kwang-Won Park ◽  
Alan A. Wiles ◽  
Jongin Hong

We report the simple synthesis of two organic chromophores featuring an ethynyl-thienothiophene linker with an n-hexyl chain (CSD-03 and CSD-04), their optical and electrochemical properties, and their use as photosensitizers in dye-sensitized solar cells (DSSCs). Our theoretical and experimental studies show that adding the second thienothiophene allows for narrowing the bandgap of the molecule and thus ensuring more light harvesting in the visible region. The efficiencies of both CSD-03 (5.46 ± 0.03%) and CSD-04 (5.20 ± 0.03%) are comparable to that of N719 (5.92 ± 0.01%) in translucent DSSCs fabricated with 5 μm-thick TiO2 photoanodes.


2019 ◽  
Author(s):  
Ibrahim Olasegun Abdulsalami ◽  
Banjo Semire ◽  
Issa Adewale Bello

After experimental studies on the application of anthocyanidins as sensitizers in dye-sensitized solar cells (DSSCs) we have used computational methods to further elucidate the data obtained in the experimental study. In this study structural effects and electronic contributions of four anthocyanidins, cyanidin (Cy), delphinidin (Dp), malvidin (Mv) and pelargonidin (Pg), to improve the efficiency of DSSCs were investigated, using quantum chemical method, the density functional theory (DFT), to calculate parameters such as frontier molecular orbitals, band gap energies, reactivity descriptors.<br>


2019 ◽  
Author(s):  
Ibrahim Olasegun Abdulsalami ◽  
Banjo Semire ◽  
Issa Adewale Bello

After experimental studies on the application of anthocyanidins as sensitizers in dye-sensitized solar cells (DSSCs) we have used computational methods to further elucidate the data obtained in the experimental study. In this study structural effects and electronic contributions of four anthocyanidins, cyanidin (Cy), delphinidin (Dp), malvidin (Mv) and pelargonidin (Pg), to improve the efficiency of DSSCs were investigated, using quantum chemical method, the density functional theory (DFT), to calculate parameters such as frontier molecular orbitals, band gap energies, reactivity descriptors.<br>


2015 ◽  
Vol 17 (9) ◽  
pp. 6347-6358 ◽  
Author(s):  
Hashem Shahroosvand ◽  
Saeed Zakavi ◽  
Ahmad Sousaraei ◽  
Mortaza Eskandari

We report on the theoretical and experimental studies of the new dye-sensitized solar cells functionalized with 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin zinc(ii) complexes bearing 2- and 8-bromo substituents at the β positions.


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