Summary Abstract: X‐ray photoelectron spectroscopy, temperature programmed desorption, and Auger electron spectroscopy investigation of the interaction of [Rh(CO)2Cl]2 with oxidized Al(100)

1988 ◽  
Vol 6 (3) ◽  
pp. 859-860 ◽  
Author(s):  
David N. Belton ◽  
Steven J. Schmieg
1993 ◽  
Vol 334 ◽  
Author(s):  
Wei Chen ◽  
Jeffrey T. Roberts

AbstractThe adsorption and reaction of titanium tetrachloride (TiC14) on W(100) was investigated using temperature programmed desorption mass spectrometry (TPRS), x-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), and low energy electron diffraction (LEED). TiC14 adsorbs molecularly on W(100) at 100 K. Desorption from the molecularly bound state occurs near 220 K. Competing with desorption is dissociation to adsorbed TiCl3, which reacts to form gaseous TiCl4 near 450 K. TiC13 also decomposes into atomically adsorbed Ti and Cl on the surface upon heating to 700 K.


1978 ◽  
Vol 32 (2) ◽  
pp. 175-177 ◽  
Author(s):  
L. Bradley ◽  
Y. M. Bosworth ◽  
D. Briggs ◽  
V. A. Gibson ◽  
R. J. Oldman ◽  
...  

The difficulties of nonuniform ion etching which hamper depth profiling by X-ray photoelectron spectroscopy (XPS) have been overcome by use of a mechanically scanned saddle-field ion source. The system and its calibration for uniformity are described, and its performance is illustrated by the depth profile of a Si3N4/SiO2/Si metal nitride oxide silicon device. This also allows the potential advantages of XPS profiling over Auger electron spectroscopy profiling to be discussed.


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