Possibility of standardization of normalized fluorescent parameter as a measure of organic admixture concentration in water and atmosphere

Author(s):  
Viktor V. Fadeev
1993 ◽  
Vol 4 (1) ◽  
pp. 91-102 ◽  
Author(s):  
Hiroshi UCHIKAWA ◽  
Shunsuke HANEHARA ◽  
Daisuke SAWAKI ◽  
Tokuhiko SHIRASAKA
Keyword(s):  

2018 ◽  
Vol 26 (1) ◽  
pp. 69-72 ◽  
Author(s):  
O. V. Kovalenko ◽  
M. F. Bulaniy ◽  
V. Y. Vorovskiy ◽  
O. V. Khmelenko

Nanocrystals of ZnO:Mn were obtained by ultrasonic spray pyrolysis and had dimensions of d ~ 36 nm. The changes of photoluminescence end EPR spectra of these nanocrystals in dependence of Mn admixture concentration ( 2–8 at. %) and also at heat treatment in air during 1 hour at T = 850 ̊C were investigated. It is shown that under short-term (7–10 s) nonequilibrium conditions of ZnO:Mn nanocrystals forming, they consist of a nuclens and shell surface, in which, predominantly, the Mn admixture is concentrated. After annealing, the Mn admixture diffuses into the nucleus of a nanocrystal.


Author(s):  
Yu. V. Nuzhnov

Some problems of statistical modeling of turbulent flows associated with the hydrodynamic effects of intermittency of various dynamic and scalar fields are identified, and a justification of their solutions is proposed. At first examines some problems of statistical modeling of large-scale (energy-containing) turbulence structure under the conditions of turbulent and nonturbulent fluid intermittency in the turbulent flow. This primarily applies to the problem of obtaining the differential equations of hydrodynamics for conditional statistical moments (conditional averages), i.e. for single-point statistical moments of each of the intermittent media of turbulent flow. To solve this problem is given a mathematically rigorous justification of conducting the operation of conditional averaging of the Navier-Stokes equations. As a result was obtained the system of differential equations for the conditional averages of turbulent and nonturbulent fluid. The main advantage of the obtained differential equations for the conditional averages is that these equations don’t contain the source terms. Therewith is given a physical substantiation of transformation process of nonturbulent fluid in turbulent, that occurs in a thin superlayer, which separates turbulent and nonturbulent fluid. Here also is given a justification of conducting the operation of total averaging of the partial derivates, which, as it turns out, is not a permutational and leads to a number of specific features in comparison with the unconditional averaging in RANS. Another problem associated with statistical modeling of inhomogeneous turbulent flows, i.e. flows with an inhomogeneous field of scalar substance. It is known that the dynamic field with turbulent fluid does not coincide with the inhomogeneous field of scalar substance. To solve this problem is proposed a method of calculating the statistical characteristics both of the turbulent fluid and the inhomogeneous field of a passive admixture concentration. It is shown, that the conditional averages of the passive admixture concentration are significantly different. In conclusion we consider the problem of statistical modeling of diffusional turbulent combustion of not pre-mixed chemically reacting gases, expressly the modeling by the known method PDF with involving the “reduced fuel concentration” as the passive impurity concentration. To solve this problem is given a justification of new differential equations, allowing to carry out calculations only of the conditional averages for the intersection region of the dynamic field of the turbulent fluid and the inhomogeneous field of the passive impurity concentration. Some results of such calculations, performed in the self-similar field of diffusion turbulent propane plume, are presented together with the experimental data available in literature.


2019 ◽  
Vol 292 ◽  
pp. 114-119
Author(s):  
Martin Alexa ◽  
Dalibor Kocáb ◽  
Barbara Kucharczyková ◽  
Jan Kotrla

This paper deals with the relationship between chemical processes in the early stages of hydration of alkali-activated slag, volume changes and the development of the microstructure of this material. Two test pastes were produced for the purpose of the experiment - one with and the other without an organic admixture (isopropyl alcohol). The pastes were used to monitor autogenous shrinkage by measuring volume changes and at the same time the changes in the material during setting and early hardening using a modern ultrasonic instrument Vikasonic. The output of the described experiment is a detailed evaluation of the difference in the behaviour of the used alkali-activated paste with and without the addition of an organic admixture.


2012 ◽  
Vol 51 (1) ◽  
pp. 86-91 ◽  
Author(s):  
Vladimir Rumyantsev ◽  
Stanislav Fedorov ◽  
Konstantin Gumennyk

2021 ◽  
Vol 898 ◽  
pp. 57-65
Author(s):  
Pavla Bauerová ◽  
Pavel Reiterman ◽  
Petra Mácová ◽  
Zuzana Slížková ◽  
Martina Havelcová ◽  
...  

Oils, e.g. linseed oil, has been used as mortar admixtures or components of lime-oil mastic since ancient times. The reason was either to increase the mortar durability and/or to prolong the mortar/mastic workability. Historic mortars are conventionally analyzed by means of X-ray diffraction and thermal analysis, but these methods are not able to detect the organic compounds directly. The goal of the present research was to evaluate the applicability of thermal analysis, infra-red spectroscopy, solid state NMR spectroscopy and gas chromatography for detection and possible quantification of linseed oil in prepared mortar containing, beyond the oil, just lime and calcite. Both applied spectroscopies were able not only detect the presence of oil but may be used also for study of the oil chemical transformation in the alkaline environment of the lime mortar. Thermal analysis is not able to identify kind of organic admixture, but when it is known that it is e.g. linseed oil, its quantification by help of Evolved Gas Analysis is very good. The results of gas chromatography of mortar’s extract are affected by the polymerization of oil in mortar. The total organic content analysis is providing good information about the total amount of organics in mortar. There in not any single method, which could provide all information about the oil admixture in mortar (kind of oil, content of oil, fate of oil after mortar’s mixing) by itself; the combination of techniques must be used.


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