The Rate Constant of Electron Impact Dissociation of Carbon Dioxide (Analytical Review of Calculation Methods and Known Results)

2021 ◽  
Vol 55 (6) ◽  
pp. 419-435
Author(s):  
Yu. A. Lebedev ◽  
V. A. Shakhatov
Keyword(s):  
Carbon Dioxide ◽  
Electron Impact ◽  
Rate Constant ◽  
Calculation Methods ◽  
Electron Impact Dissociation ◽  
Analytical Review

scholarly journals Electron impact dissociation of CO2 (a review)

2021 ◽  
Vol 9 (5) ◽  
pp. 365-392
Author(s):  
Yurii Lebedev ◽  
Vyasheslav Shakhatov
Keyword(s):  
Electric Field ◽  
Electron Impact ◽  
Rate Constant ◽  
Atmospheric Pressure ◽  
Gas Discharges ◽  
Electron Impact Dissociation ◽  
Mechanism Of Decomposition ◽  
Pure Carbon ◽  
Carbon Dioxide Co2 ◽  
Pure Carbon Dioxide

Based on a detailed analysis and generalization of the results of calculations of the energy spectrum of electrons using different models in gas discharges in pure carbon dioxide CO2 and in mixtures containing CO2 , the rate constant of CO2 dissociation by electron impact in a gas discharge of direct current at atmospheric pressure is found. It is shown that, at values of the reduced electric field from 55 Td to 100 Td, the predominant mechanism of decomposition of the CO2 molecule is the collision of CO2 molecules with electrons. An expression is obtained for calculating the rate constant of CO2 dissociation by electron impact as a function of the reduced electric field.

Electron-impact dissociation ofCD3+andCH3+ions producingCD2+,CH+, andC+fragment ions

2009 ◽  
Vol 79 (5) ◽  
Author(s):  
E. M. Bahati ◽  
M. Fogle ◽  
C. R. Vane ◽  
M. E. Bannister ◽  
R. D. Thomas ◽  
...  
Keyword(s):  
Electron Impact ◽  
Electron Impact Dissociation ◽  
Fragment Ions

Electron impact studies. VI. Mass spectra of esters and thioesters. Skeletal rearrangement on electron impact

1967 ◽  
Vol 20 (4) ◽  
pp. 689 ◽  
Author(s):  
JH Bowie ◽  
RG Cooks ◽  
P Jakobsen ◽  
S Lawesson ◽  
G Schroll
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
High Resolution ◽  
Electron Impact ◽  
Mass Spectra ◽  
Skeletal Rearrangement ◽  
Unsaturated Esters ◽  
Impact Studies ◽  
Unsaturated Alcohols ◽  
Metastable Ions

The mass spectra of representative series of simple alkyl acetoacetates, alkyl acetothioacetates, and some unsaturated esters derived from unsaturated alcohols or phenols are reported and discussed. The fragmentation schemes have been established by high resolution measurements, appropriate metastable ions, and by deuterium and 18O labelling. Many of the spectra show significant skeletal rearrangement fragments arising from either loss of carbon monoxide or carbon dioxide.

Experimental studies of electron impact dissociation of molecular ions

1996 ◽  
Author(s):  
Nada Djurić ◽  
Yang-Soo Chung ◽  
Barry Wallbank ◽  
Gordon H. Dunn
Keyword(s):  
Electron Impact ◽  
Experimental Studies ◽  
Molecular Ions ◽  
Electron Impact Dissociation

Electron-impact dissociation and transient properties of a stored LiH2 - beam

2006 ◽  
Vol 41 (1) ◽  
pp. 103-111 ◽  
Author(s):  
L. Lammich ◽  
S. Altevogt ◽  
H. Buhr ◽  
H. Kreckel ◽  
S. Krohn ◽  
...  
Keyword(s):  
Electron Impact ◽  
Electron Impact Dissociation

Polarization line shape of Balmer‐β from electron impact dissociation of H2

1984 ◽  
Vol 80 (5) ◽  
pp. 1754-1759 ◽  
Author(s):  
Robert S. Freund ◽  
David E. Donohue ◽  
Georgia J. Fisanick
Keyword(s):  
Electron Impact ◽  
Line Shape ◽  
Electron Impact Dissociation
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