Determination of the characteristic linear dimension for calculating the thermohydraulic parameters of a porous structure

2013 ◽  
Vol 51 (1) ◽  
pp. 135-137 ◽  
Author(s):  
Yu. A. Zeigarnik ◽  
F. P. Ivanov
2019 ◽  
Vol 109 ◽  
pp. 00101
Author(s):  
Oleksandr Topal ◽  
Iryna Holenko ◽  
Inna Diakun

The results of determination of parameters of porous structure of coal and char particles are presented. They were determined using gas adsorption method and thermal decomposition of particles in air oxygen. The porous structure parameters allow predicting char reactivity change at different temperatures as well as during conversion in accordance with Random Pore Model (RPM-model).


2019 ◽  
Vol 7 (2) ◽  
pp. 42-54 ◽  
Author(s):  
А. Синцов ◽  
A. Sintsov ◽  
Владимир Девисилов ◽  
Vladimir Devisilov

In this paper have been presented a new model of the porous structure, as well as an analysis of possibilities of a new method for experimental investigation of porous permeable materials and determination of their structural characteristics. An analysis for the majority of used in analytical calculations geometric models for a porous medium has been presented, and a model for a porous material in the form of porous matrix’s elementary cells has been proposed. Each of the cells contains a capillary channel with a variable cross-section. Volumetric structural characteristics, as well as dependencies of surface structural characteristics over the porous matrix’s thickness, are identical to these parameters, which have been obtained during the experimental study of a porous material. As a result of use of an original experimental technology offered by authors, and of experiment processing the porous matrix’s structure can be completely defined. The problem of creating an experimental setup, allowing determine the porous matrix’s characteristics, has been formulated. One of possible options for the experimental stand has been considered.


2014 ◽  
Vol 26 (1) ◽  
pp. 189-198 ◽  
Author(s):  
Giovanni Barbera ◽  
Germana Barone ◽  
Vincenza Crupi ◽  
Francesca Longo ◽  
Giacomo Maisano ◽  
...  

2016 ◽  
Vol 70 (5) ◽  
pp. 565-572 ◽  
Author(s):  
Remy Vala ◽  
Donbebe Wankasi ◽  
Ezekiel Dikio

In this paper, we report the synthesis of metal organic framework of uranium 1,2,4,5-benzene tetracarboxylic acid (U-H4btec MOF) by solvothermal method. The obtained MOF was characterized by Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray diffraction spectroscopy (XRD), Energy dispersive spectroscopy (EDS), thermogravimetric and differential thermogravimetric analysis (TGA/DTA). The morphology of the uranium 1,2,4,5-benzene tetracarboxylic acid MOF observed by SEM, revealed the presence of flaky porous structure. Adsorption of Cr3+ from aqueous solution onto the uranium 1,2,4,5-benzene tetracarboxylic acid MOF was systematically studied. Langmuir and Freundlich adsorption isotherms were applied to determine the adsorption capacity of the MOF to form a monolayer. Kinetic determination of the adsorption of Cr3+ suggested both chemisorption and physisorption probably due to the presence of carbonyl groups within the MOF and its porous structure.


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