Effect of various sono-oxidation parameters on the desulfurization of diesel oil

2009 ◽  
Vol 49 (5) ◽  
pp. 436-441 ◽  
Author(s):  
Yongchuan Dai ◽  
Yutai Qi ◽  
Dezbi Zhao
2019 ◽  
Vol 40 (1) ◽  
pp. 7
Author(s):  
Marcelo Silveira de Farias ◽  
José Fernando Schlosser ◽  
Javier Solis Estrada ◽  
Gismael Francisco Perin ◽  
Alfran Tellechea Martini

The growing global demand of energy, the decrease of petroleum reserves and the current of environmental contamination problems, make it imperative to study renewable energy sources for use in internal combustion engines, in order to decrease the dependence on fossil fuels and reduce emissions of pollutant gases. This study aimed to evaluate the emissions of a diesel-cycle engine of an agricultural tractor that uses diesel S500 (B5) mixed with 3, 6, 9, 12 and 15% of hydrous ethanol. It determined emissions of CO2 (ppm), NOx (ppm), and opacity (k value) of gases. A standard procedure was applied considering eight operating modes (M1, M2, M3, M4, M5, M6, M7, and M8) by breaking with an electric dynamometer in a laboratory. The experimental design was completely randomized, with 60 replicates and a 6 x 8 factorial design. Greater opacity and gas emissions were observed when the engine operated with 3% ethanol, while lower emissions occurred with 12 and 15%. With these fuels, the reduction of opacity, CO2, and NOx, in relation to diesel oil, was 24.49 and 26.53%, 4.96 and 5.15%, and 6.59 and 9.70%, respectively. In conclusion, the addition of 12 and 15% ethanol in diesel oil significantly reduces engine emissions.


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1086
Author(s):  
Asma Abdulkareem ◽  
Anton Popelka ◽  
Patrik Sobolčiak ◽  
Aisha Tanvir ◽  
Mabrouk Ouederni ◽  
...  

This paper addresses the preparation and characterization of efficient adsorbents for tertiary treatment (oil content below 100 ppm) of oil/water emulsions. Powdered low-density polyethylene (LDPE) was modified by radio-frequency plasma discharge and then used as a medium for the treatment of emulsified diesel oil/water mixtures in the concentration range from 75 ppm to 200 ppm. Plasma treatment significantly increased the wettability of the LDPE powder, which resulted in enhanced sorption capability of the oil component from emulsions in comparison to untreated powder. Emulsions formed from distilled water and commercial diesel oil (DO) with concentrations below 200 ppm were used as a model of oily polluted water. The emulsions were prepared using ultrasonication without surfactant. The droplet size was directly proportional to sonication time and ranged from 135 nm to 185 nm. A sonication time of 20 min was found to be sufficient to prepare stable emulsions with an average droplet size of approximately 150 nm. The sorption tests were realized in a batch system. The effect of contact time and initial oil concentrations were studied under standard atmospheric conditions at a stirring speed of 340 rpm with an adsorbent particle size of 500 microns. The efficiency of the plasma-treated LDPE powder in oil removal was found to be dependent on the initial oil concentration. It decreased from 96.7% to 79.5% as the initial oil concentration increased from 75 ppm to 200 ppm. The amount of adsorbed oil increased with increasing contact time. The fastest adsorption was observed during the first 30 min of treatment. The adsorption kinetics for emulsified oils onto sorbent followed a pseudo-second-order kinetic model.


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