Zinc Complex with Tridentate ONO Schiff base Ligand: the Characterization and Nanostructure Thereof

A bent trinuclear zinc complex, [Zn{ZnIL}2]•DMF {H2L = 2,2'-[(2,2-Dimethyl-1,3-propanediyl)bis(iminomethylene)]bis[6-methoxyphenol]} was synthesized and characterized by standard spectroscopic methods and X-ray diffraction analysis. The existence of coordinated amino groups and iodide counter...

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Synthesis, structure and nitroaromatic sensing ability of a trinuclear zinc complex with a reduced Schiff base ligand: Assessment of the ability of the ligand to sense zinc ion

Polyhedron ◽

10.1016/j.poly.2020.114639 ◽

2020 ◽

Vol 187 ◽

pp. 114639 ◽

Cited By ~ 1

Author(s):

Mainak Karmakar ◽

Shouvik Chattopadhyay

Keyword(s):

Schiff Base ◽

Schiff Base Ligand ◽

Zinc Complex ◽

Zinc Ion ◽

Reduced Schiff Base

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On the importance of RH3C•••N tetrel bonding interactions in the solid state of a dinuclear zinc complex with a tetradentate Schiff base ligand

CrystEngComm ◽

10.1039/d0ce01864c ◽

2021 ◽

Author(s):

IPSITA MONDAL ◽

Antonio Frontera ◽

Shouvik Chattopadhyay

Keyword(s):

Schiff Base ◽

Solid State ◽

Schiff Base Ligand ◽

Zinc Complex ◽

X Ray ◽

Tetradentate Schiff Base

The synthesis and X-ray characterization of a new dinuclear Zn complex using a tetradentate N2O2 donor Schiff base and azide as anionic co-ligand of formula [(DMSO)2ZnL(µ1,1-N3)Zn(N3)2] (1) is reported herein....

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Synthesis, crystal structure and photoluminescent properties of an aromatic bridged Schiff base ligand and its zinc complex

Inorganica Chimica Acta ◽

10.1016/j.ica.2007.07.012 ◽

2008 ◽

Vol 361 (1) ◽

pp. 233-240 ◽

Cited By ~ 95

Author(s):

Tianzhi Yu ◽

Kai Zhang ◽

Yuling Zhao ◽

Changhui Yang ◽

Hui Zhang ◽

...

Keyword(s):

Crystal Structure ◽

Schiff Base ◽

Schiff Base Ligand ◽

Zinc Complex

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Near-Infrared Emitting Heterobinuclear Zn-Ln (Ln = Nd, Yb, Er,and Gd) Complexes Based on a Novel Asymmetric Schiff-Base Ligand

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.749.527 ◽

2013 ◽

Vol 749 ◽

pp. 527-532

Author(s):

Shun Sheng Zhao

Keyword(s):

Schiff Base ◽

Excited State ◽

Schiff Base Ligand ◽

Near Infrared ◽

Zinc Complex ◽

Intramolecular Energy Transfer ◽

Elementary Analysis ◽

Ft Ir ◽

Photophysical Studies ◽

Nir Luminescence

With the asymmetric Schiff-base zinc complex ZnL (H2L = N-(5-bromo-3-methoxysalicylidene)-N'-(5-(4-cyanophenyl)-3-methoxysalicylidene) phenylene-1,2-diamine) as the precursor, a series of heterobinuclear Zn-Ln complexes [ZnLnL(NO3)3(CH3CN)] (Ln = Nd, 1; Ln = Yb, 2; Ln = Er, 3; Ln = Gd, 4) are synthesized by the further reaction with Ln (NO3)3·6H2O, and characterized by FT-IR, FAB-MS and elementary analysis. Photophysical studies of these complexes show that the strong and characteristic NIR luminescence of Nd3+, Yb3+and Er3+ with emissive lifetimes in the microsecond range has been sensitized from the excited state of the asymmetric Schiff-base ligand due to effective intramolecular energy transfer.

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Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis

Dalton Transactions ◽

10.1039/d0dt03610b ◽

2021 ◽

Author(s):

Cyril Rajnák ◽

Romana Mičová ◽

Ján Moncoľ ◽

Ľubor Dlháň ◽

Christoph Krüger ◽

...

Keyword(s):

Schiff Base ◽

Schiff Base Ligand ◽

Spin Crossover ◽

Thermal Hysteresis ◽

Mononuclear Complex ◽

Hysteresis Width ◽

Thermally Induced

A pentadentate Schiff-base ligand 3,5Cl-L2− and NCSe− form a iron(iii) mononuclear complex [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).

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