Kinetics of Prompt Fluorescence Decay in Rubrene Films. Manifestations of the Migration of T Excitons

2017 ◽  
Vol 11 (6) ◽  
pp. 887-893 ◽  
Author(s):  
A. I. Shushin

1980 ◽  
Vol 32 (2) ◽  
pp. 155-160
Author(s):  
V. T. Koyava ◽  
V. I. Popechits ◽  
A. M. Sarzhevskii


The decay constants k T for phosphorescence and k D for delayed fluorescence have been measured for the same outgassed solutions of acenaphthene, pyrene, 1,2-benzanthracene and fluoranthene in liquid paraffin over a range of temperatures between – 70 and 30 °C. In all cases the luminescence decay is exponential and the intensity of delayed fluorescence is found to vary as the second power of incident light intensity; under these conditions the relation k D = 2 k T required by the triplet-triplet annihilation origin of delayed fluorescence is established over the temperature ranges in which delayed fluorescence and phosphorescence are exhibited simultaneously. Diffusional quenching of the triplet state 3 A by a solute impurity Q is believed to be responsible for the temperature (viscosity) dependence of k T and k D since ( a ) k T and k D are linear functions of solute concentration where this is examined, ( b ) by taking account of the reversibility of the quenching process 3 A + Q ⇌ A + 3 Q at higher temperatures (lower viscosities) the virtual independence of k on temperature exhibited for 1,2-benzanthracene and fluoranthene under these conditions may be explained. The resumed temperature dependence of k D for fluoranthrene at still higher temperatures is attributed to endothermic quenching of the triplet state by an impurity with a higher triplet state than that of the solute.



PLoS ONE ◽  
2013 ◽  
Vol 8 (4) ◽  
pp. e63127 ◽  
Author(s):  
Franziska Leunert ◽  
Hans-Peter Grossart ◽  
Volkmar Gerhardt ◽  
Werner Eckert


2015 ◽  
Vol 17 (30) ◽  
pp. 19844-19853 ◽  
Author(s):  
J. Michael Gruber ◽  
Jevgenij Chmeliov ◽  
Tjaart P. J. Krüger ◽  
Leonas Valkunas ◽  
Rienk van Grondelle

The two-exponential fluorescence decay kinetics of single LHCII complexes are quantitatively explained by a stochastic model of singlet–triplet annihilation.



1990 ◽  
Vol 46 (5) ◽  
pp. 359-369 ◽  
Author(s):  
S. Gangopadhyay ◽  
M.W. Pleil ◽  
W.L. Borst




1979 ◽  
Vol 545 (1) ◽  
pp. 165-174 ◽  
Author(s):  
G.S. Beddard ◽  
G.R. Fleming ◽  
G. Porter ◽  
G.F.W. Searle ◽  
J.A. Synowiec




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