Raman Spectroscopy of Iron-Oxide Core-Corona Nanoparticles: Effect of Synthesis Temperature

2020 ◽  
Vol 56 (6) ◽  
pp. 1159-1167
Author(s):  
V. A. Kotenev
Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 607
Author(s):  
Roberto Baca-Arroyo

Analog computing from recycling principle for next circular economy scenario has been studied with an iron oxide-coupled graphite/Fe–Si steel structure which was built using recycled waste materials, such as lead pencil and 3% Si steel (Fe–Si steel) foils. Proximity phenomena, such as disordered structure of iron oxide and magnetostriction-induced conduction, inside graphite lattice resulted in functional properties to advance analog architectures. Thermal oxidation was the synthesis route to produce iron oxide as coating film on Fe–Si steel foil, whose structure properties were validated by Raman spectroscopy where phase formation of hematite, α-Fe2O3, resulted as iron oxide thin-film. Three graphite layers with different compositions were also analyzed by Raman spectroscopy and used for studying electrical conduction in Fe–Si steel/α-Fe2O3/graphite structure from current–voltage plots at room temperature.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Alejandro Lapresta-Fernández ◽  
Alfonso Salinas-Castillo ◽  
Luis Fermín Capitán-Vallvey

AbstractEncapsulation of magnetic nanoparticles (MNPs) of iron (II, III) oxide (Fe3O4) with a thermopolymeric shell of a crosslinked poly(2-(2-methoxyethoxy)ethyl methacrylate) P(MEO2MA) is successfully developed. Magnetic aggregates of large size, around 150–200 nm are obtained during the functionalization of the iron oxide NPs with vinyl groups by using 3-butenoic acid in the presence of a water soluble azo-initiator and a surfactant, at 70 °C. These polymerizable groups provide a covalent attachment of the P(MEO2MA) shell on the surface of the MNPs while a crosslinked network is achieved by including tetraethylene glycol dimethacrylate in the precipitation polymerization synthesis. Temperature control is used to modulate the swelling-to-collapse transition volume until a maximum of around 21:1 ratio between the expanded: shrunk states (from 364 to 144 nm in diameter) between 9 and 49 °C. The hybrid Fe3O4@P(MEO2MA) microgel exhibits a lower critical solution temperature of 21.9 °C below the corresponding value for P(MEO2MA) (bulk, 26 °C). The MEO2MA coating performance in the hybrid microgel is characterized by dynamic light scattering and transmission electron microscopy. The content of preformed MNPs [up to 30.2 (wt%) vs. microgel] was established by thermogravimetric analysis while magnetic properties by vibrating sample magnetometry.


2017 ◽  
Vol 885 ◽  
pp. 012007 ◽  
Author(s):  
Maciej Jarzębski ◽  
Mikołaj Kościński ◽  
Tomasz Białopiotrowicz

2009 ◽  
Vol 1207 ◽  
Author(s):  
Michael John Fornasiero ◽  
Diana-Andra Borca-Tasciuc

AbstractNanofluids are engineered colloidal suspensions of nanometer-sized particles in a carrier fluid and are receiving significant attention because of their potential applications in heat transfer area. Theoretical investigations have shown that the enhanced thermal conductivity observed in nanofluids is due to nanoparticle clustering and networking. This provides a low resistance path to the heat flowing through the fluid. However, the surface coating of the nanoparticles, which is often used to provide stable dispersion over the long term, may act as a thermal barrier, reducing the effective thermal conductivity of the nanofluid. Moreover, nanofluids with the same type of nanoparticles may exhibit different effective thermal conductivities, depending upon the thermal properties and thickness of the coating. In this context, thermal conductivity characterization of well dispersed iron oxide nanoparticles with two different surface coatings was carried out employing the transient hot wire technique. The diameter of the iron oxide core was 35 nm and the coatings used were aminosilane and carboxymethyl-dextran (CMX) of 7nm in thickness. Preliminary results suggest that effective thermal conductivity of CMX coated nanoparticle suspensions is slightly higher than that of aminosilane coated nanoparticles. In both cases, the effective thermal conductivity is higher than that predicted by the Maxwell model for composite media.


2015 ◽  
Vol 54 (6) ◽  
pp. 2734-2741 ◽  
Author(s):  
Gökhan Elmaci ◽  
Carolin E. Frey ◽  
Philipp Kurz ◽  
Birgül Zümreoğlu-Karan

Biomaterials ◽  
2009 ◽  
Vol 30 (36) ◽  
pp. 6947-6954 ◽  
Author(s):  
Peter A. Jarzyna ◽  
Torjus Skajaa ◽  
Anita Gianella ◽  
David P. Cormode ◽  
Daniel D. Samber ◽  
...  

2015 ◽  
Vol 7 (34) ◽  
pp. 19342-19352 ◽  
Author(s):  
Steffen Kurzhals ◽  
Ronald Zirbs ◽  
Erik Reimhult

2017 ◽  
Vol 29 (3) ◽  
pp. 1279-1289 ◽  
Author(s):  
Alberto López-Ortega ◽  
Elisabetta Lottini ◽  
Giovanni Bertoni ◽  
César de Julián Fernández ◽  
Claudio Sangregorio

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