The catalytic activity of tertiary phosphines, arsines, stibines, and quarternary phosphonium salts in reaction of terephthalic acid with ethylene oxide

1976 ◽  
Vol 41 (1) ◽  
pp. 101-109 ◽  
Author(s):  
J. Málek ◽  
P. Šilhavý
Keyword(s):  
Catalytic Activity ◽  
Ethylene Oxide ◽  
Terephthalic Acid ◽  
Phosphonium Salts ◽  
Tertiary Phosphines

scholarly journals The Effects of Solvents on the Reaction of Terephthalic Acid and Ethylene Oxide

1971 ◽  
Vol 74 (12) ◽  
pp. 2485-2490 ◽  
Author(s):  
Hideo OKEDA ◽  
Kisaburo YAMAGAMI ◽  
Kichiji ENOKI ◽  
Toshiyuki TANI
Keyword(s):  
Ethylene Oxide ◽  
Terephthalic Acid

Role of Counterions in the Catalytic Activity and Phase Equilibria of Phosphonium Salts in Water†

Langmuir ◽  
2000 ◽  
Vol 16 (1) ◽  
pp. 166-171 ◽  
Author(s):  
Giorgio Cerichelli ◽  
Camillo La Mesa ◽  
Luciana Luchetti ◽  
Giovanna Mancini
Keyword(s):  
Catalytic Activity ◽  
Phase Equilibria ◽  
Phosphonium Salts

Effects of DTAB on Performance of Nano Pd/C Catalyst for Purification of Terephthalic Acid

2013 ◽  
Vol 662 ◽  
pp. 140-144 ◽  
Author(s):  
Fa Xin Xiao ◽  
Yan Song Li ◽  
Xin Yang Xu ◽  
Xiao Ni Shen ◽  
Yong Peng Ren ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Catalytic Activity ◽  
Activated Carbon ◽  
Specific Surface ◽  
Terephthalic Acid ◽  
Dodecyltrimethylammonium Bromide ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Palladium Particles ◽  
Stable Structures

The 0.5 wt.% Pd/C catalysts used for purification of terephthalic acid(TA) were prepared, and the effects of dodecyltrimethylammonium bromide(DTAB) concentration on activity and microstructure of catalysts were investigated by means of SEM, TEM, XRD,HPLC,specific surface area(BET) and porosity test. The results show that DTAB can increase the activity of Pd/C catalysts, and the catalytic activity increases with the increase in DTAB concentration and nearly remains constant with further increase after it exceeds 0.5 wt.%.. DTAB can clean the surface of activated carbon and diminish the palladium size of Pd/C catalysts. The addition of DTAB has effects in crystal structure of nano Pd/C catalysts, and the Pd crystal planes of (111) and (200) was replaced by a broad reflections after DTAB added. DTAB tends to form various meta-stable structures(spherical or cylindrical)at the solid-liquid interface that helps finer grain for mation and hinders subsequent coarsening of the palladium particles.

Kinetics of the reaction between terephthalic acid and ethylene oxide under high pressure

1976 ◽  
Vol 31 (6) ◽  
pp. 427-433 ◽  
Author(s):  
S. Bhatia ◽  
M. Gopala Rao ◽  
M. Someswara Rao
Keyword(s):  
High Pressure ◽  
Ethylene Oxide ◽  
Terephthalic Acid ◽  
Kinetics Of

scholarly journals The Effects of Catalysts on the Reaction of Terephthalic Acid and Ethylene Oxide

1973 ◽  
pp. 132-136 ◽  
Author(s):  
Kichiji Enoki ◽  
Toshiyuki Tani ◽  
Hideo Okeda ◽  
Kisaburo Yamagami
Keyword(s):  
Ethylene Oxide ◽  
Terephthalic Acid

scholarly journals Communication—Fe-MOF Exhibits Higher Oxygen Evolution Ability by Electronic Modulation of Sodium Hypochlorite

2021 ◽  
Author(s):  
Guomei Mu ◽  
Yujie Miao ◽  
Mengjiao Wu ◽  
Qiaoyue Xiang ◽  
Dunmin Lin ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Catalytic Activity ◽  
Oxygen Evolution ◽  
Sodium Hypochlorite ◽  
Terephthalic Acid ◽  
Function Theory ◽  
Nickel Foam ◽  
Density Function Theory ◽  
The Third ◽  
Fe Sites

Abstract Development of robust alkaline oxygen evolution reaction electrocatalysts is crucial for the efficiency of water splitting. Herein, Fe-MOF nanocones array on nickel foam are synthesized by introducing sodium hypochlorite, leading to Cl substitution of terephthalic acid in Fe-MOFs (Fe-MOF-Cl/NF). Experimental results show that Fe-MOF-Cl/NF exhibits enhanced OER activity over Fe-MOF/NF, lowering η50 from 292.4 to 222.7 mV. In combination with density function theory calculations, the improved OER performance is attributed to engineering electronic structure of Fe sites which accelerate the third step from *O to *OOH, and promote OER kinetics. Additionally, Fe-MOF-Cl/NF can retain catalytic activity for 100 h.

Production of bis(?-ethoxy)terephthalate from terephthalic acid and ethylene oxide

1977 ◽  
Vol 9 (1) ◽  
pp. 25-29 ◽  
Author(s):  
T. I. Samsonova ◽  
G. D. Mikhailov ◽  
V. A. Malykh ◽  
A. S. Chegolya
Keyword(s):  
Ethylene Oxide ◽  
Terephthalic Acid
Sign in / Sign up

Export Citation Format

Share Document