Effect of temperature on chiroptical and conformational properties of acyclic ketoses
1980 ◽
Vol 45
(2)
◽
pp. 475-481
Keyword(s):
Conformational mobility of tetruloses, 2-pentuloses, D-3-pentulose and 4-deoxy-L-pentulose was studied by measuring temperature dependences of CD spectra in the region +40°C to -140°C in a methanol-ethanol (1:4) mixture. The changes in spectra reflect the population of rotamers around bonds to the carbonyl chromophore. The most stable conformers were determined by PCILO quantum chemical calculation.
2017 ◽
Vol 137
(11)
◽
pp. 626-631
◽
Keyword(s):
2008 ◽
Vol 891
(1-3)
◽
pp. 58-63
◽
2007 ◽
Vol 48
(1)
◽
pp. 166-169
◽
Keyword(s):