Densities, Refractive Indices, Speeds of Sound and Shear Viscosities of Diethylene Glycol Dimethyl Ether Methyl Salicylate at Temperatures from 298.15 to 318.15 K

1994 ◽  
Vol 59 (7) ◽  
pp. 1511-1524 ◽  
Author(s):  
Tejraj M. Aminabhavi ◽  
Hemant T. S. Phayde ◽  
Rajashekhar S. Khinnavar

Densities, refractive indices, speeds of sound and viscosities of the diethylene glycol dimethyl ether - methyl salicylate system were measured as a function of mole fraction at 298.15, 303.15, 308.15, 313.15 and 318.15 K. The results are fitted by a power series equation involving both the temperature and mole fraction variables. The basic physical data of the mixtures are further used to calculate the excess molar volume VE, changes in isentropic compressibility ∆β, changes in refractivity ∆R and changes in viscosity ∆η. The results are fitted by the Redlich-Kister polynomial relation. The isobaric thermal expansion coefficients of the mixtures are also determined from density measurements. The data are compared with those obtained from equations derived by differentiation of the Lorentz-Lorenz and Eykman relations. Refractive indices of the mixture are used to test the validity of mixing relations. The changes in isobaric thermal expansion coefficients ∆α of the mixtures were examined. Viscosity data were tested in terms of the McAllister, Heric and Auslaender relations.

1978 ◽  
Vol 56 (22) ◽  
pp. 2803-2807 ◽  
Author(s):  
Osamu Kiyohara ◽  
Patrick J. D'Arcy ◽  
George C. Benson

Densities of water + tetrahydrofuran mixtures were measured at 5 K intervals of temperature from 288.15 to 308.15 K. Excess thermal expansion coefficients and partial molar excess thermal expansivities at 298.15 K over the whole mole fraction range were derived from the results. The significance of the expansivities is discussed in terms of the structural changes accompanying the formation of the mixture.


2018 ◽  
Vol 63 (7) ◽  
pp. 1167-1172
Author(s):  
V. Yo. Stadnyk ◽  
B. V. Andrievskii ◽  
V. B. Stakhura ◽  
Z. A. Kogut

2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Qazi Mohammed Omar ◽  
Jean-Noël Jaubert ◽  
Javeed A. Awan

The properties of 3 binary mixtures containing piperazine were investigated in this work. In a first step, the densities for the two binary mixtures (piperazine + methanol) and (piperazine + acetone) were measured in the temperature range of 293.15 to 328.15 K and 293.15 to 323.15 K, respectively, at atmospheric pressure by using a Rudolph research analytical density meter (DDM 2911). The concentration of piperazine in the (piperazine + methanol) mixture was varied from 0.6978 to 14.007 mol/kg, and the concentration of piperazine in the (piperazine + acetone) mixture was varied from 0.3478 to 1.8834 mol/kg. On the other hand, the density data for the (piperazine + water) mixture were taken from the literature in the temperature range of 298.15 to 328.15 K. In a second step, for the 3 investigated systems, the apparent molar volume (Vϕ) and the limiting apparent molar volume (Vϕ0) at infinite dilution were calculated using the Redlich–Mayer equation. The limiting apparent molar volumes (Vϕ0) were used to study the influence of the solute-solvent and solute-solute interactions. The temperature dependency of the apparent molar volumes was used to estimate the apparent molar expansibility, Hepler’s constant ∂2Vϕ0/∂T2P, and isobaric thermal expansion coefficients αP.


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