Densities, isobaric thermal expansion coefficients and isothermal compressibilities of linear alkylbenzene

Densities, refractive indices, speeds of sound and viscosities of the diethylene glycol dimethyl ether - methyl salicylate system were measured as a function of mole fraction at 298.15, 303.15, 308.15, 313.15 and 318.15 K. The results are fitted by a power series equation involving both the temperature and mole fraction variables. The basic physical data of the mixtures are further used to calculate the excess molar volume VE, changes in isentropic compressibility ∆β, changes in refractivity ∆R and changes in viscosity ∆η. The results are fitted by the Redlich-Kister polynomial relation. The isobaric thermal expansion coefficients of the mixtures are also determined from density measurements. The data are compared with those obtained from equations derived by differentiation of the Lorentz-Lorenz and Eykman relations. Refractive indices of the mixture are used to test the validity of mixing relations. The changes in isobaric thermal expansion coefficients ∆α of the mixtures were examined. Viscosity data were tested in terms of the McAllister, Heric and Auslaender relations.

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Densities, Apparent Molar Volume, Expansivities, Hepler’s Constant, and Isobaric Thermal Expansion Coefficients of the Binary Mixtures of Piperazine with Water, Methanol, and Acetone at T = 293.15 to 328.15 K

International Journal of Chemical Engineering ◽

10.1155/2018/8689534 ◽

2018 ◽

Vol 2018 ◽

pp. 1-10 ◽

Cited By ~ 2

Author(s):

Qazi Mohammed Omar ◽

Jean-Noël Jaubert ◽

Javeed A. Awan

Keyword(s):

Thermal Expansion ◽

Molar Volume ◽

Binary Mixtures ◽

Apparent Molar Volume ◽

Apparent Molar Volumes ◽

Molar Volumes ◽

Temperature Range ◽

Thermal Expansion Coefficients ◽

Isobaric Thermal Expansion ◽

Expansion Coefficients

The properties of 3 binary mixtures containing piperazine were investigated in this work. In a first step, the densities for the two binary mixtures (piperazine + methanol) and (piperazine + acetone) were measured in the temperature range of 293.15 to 328.15 K and 293.15 to 323.15 K, respectively, at atmospheric pressure by using a Rudolph research analytical density meter (DDM 2911). The concentration of piperazine in the (piperazine + methanol) mixture was varied from 0.6978 to 14.007 mol/kg, and the concentration of piperazine in the (piperazine + acetone) mixture was varied from 0.3478 to 1.8834 mol/kg. On the other hand, the density data for the (piperazine + water) mixture were taken from the literature in the temperature range of 298.15 to 328.15 K. In a second step, for the 3 investigated systems, the apparent molar volume (Vϕ) and the limiting apparent molar volume (Vϕ0) at infinite dilution were calculated using the Redlich–Mayer equation. The limiting apparent molar volumes (Vϕ0) were used to study the influence of the solute-solvent and solute-solute interactions. The temperature dependency of the apparent molar volumes was used to estimate the apparent molar expansibility, Hepler’s constant ∂2Vϕ0/∂T2P, and isobaric thermal expansion coefficients αP.

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ChemInform Abstract: PHYSICAL MEASUREMENTS ON IRON-ALUMINUM ALLOYS CONTAINING 10-50 AT.% ALUMINUM. III. THERMAL EXPANSION COEFFICIENTS OF THE ALLOYS CONTAINING 20-50 AT.% ALUMINUM

Chemischer Informationsdienst ◽

10.1002/chin.198203008 ◽

1982 ◽

Vol 13 (3) ◽

Author(s):

W. KOESTER ◽

T. GOEDECKE

Keyword(s):

Thermal Expansion ◽

Aluminum Alloys ◽

Thermal Expansion Coefficients ◽

Iron Aluminum ◽

Physical Measurements ◽

Expansion Coefficients ◽

Iron Aluminum Alloys

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Impact of embedded voids on thin-films with high thermal expansion coefficients mismatch

Applied Physics Letters ◽

10.1063/1.5011394 ◽

2018 ◽

Vol 112 (4) ◽

pp. 042109 ◽

Cited By ~ 6

Author(s):

Khaled H. Khafagy ◽

Tarek M. Hatem ◽

Salah M. Bedair

Keyword(s):

Thin Films ◽

Thermal Expansion ◽

Thermal Expansion Coefficients ◽

High Thermal Expansion ◽

Expansion Coefficients

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Influence of Cr deficiency on sintering, thermal expansion and electrical properties of La0.75Sr0.25Cr1−xO3−δ as a SOFC interconnect material

Modern Physics Letters B ◽

10.1142/s021798491650127x ◽

2016 ◽

Vol 30 (11) ◽

pp. 1650127 ◽

Cited By ~ 2

Author(s):

Yi Ren ◽

Wen Ma ◽

Xiaoying Li ◽

Jun Wang ◽

Yu Bai ◽

...

Keyword(s):

Thermal Expansion ◽

Electrical Properties ◽

Perovskite Phase ◽

Ignition Process ◽

Thermal Expansion Coefficients ◽

Auto Ignition ◽

Pure Perovskite Phase ◽

Maximum Conductivity ◽

Expansion Coefficients ◽

Interconnect Material

The SOFC interconnect materials La[Formula: see text]Sr[Formula: see text]Cr[Formula: see text]O[Formula: see text] [Formula: see text]–[Formula: see text] were prepared using an auto-ignition process. The influences of Cr deficiency on their sintering, thermal expansion and electrical properties were investigated. All the samples were pure perovskite phase after sintering at 1400[Formula: see text]C for 4 h. The cell volume of La[Formula: see text]Sr[Formula: see text]Cr[Formula: see text]O[Formula: see text] decreased with increasing Cr deficient content. The relative density of the sintered bulk samples increased from 93.2% [Formula: see text] to a maximum value of 94.7% [Formula: see text] and then decreased to 87.7% [Formula: see text]. The thermal expansion coefficients of the sintered bulk samples were in the range of [Formula: see text]–[Formula: see text] (30–1000[Formula: see text]C), which are compatible with that of YSZ. Among the investigated samples, the sample with 0.02 Cr deficiency had a maximum conductivity of 40.4 Scm[Formula: see text] and the lowest Seebeck coefficient of 154.8 [Formula: see text]VK[Formula: see text] at 850[Formula: see text]C in pure He. The experimental results indicate that La[Formula: see text]Sr[Formula: see text]Cr[Formula: see text]O[Formula: see text] has the best properties and is much suitable for SOFC interconnect material application.

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Novel Silicon-Elastomers for Advanced Soft Lithography

MRS Proceedings ◽

10.1557/proc-0947-a03-26 ◽

2006 ◽

Vol 947 ◽

Author(s):

Kyung Choi

Keyword(s):

Thermal Expansion ◽

High Resolution ◽

Soft Lithography ◽

Materials Properties ◽

Nano Scale ◽

Thermal Expansion Coefficients ◽

High Thermal Expansion ◽

Expansion Coefficients

ABSTRACTHigh resolution pattern transfers in the nano-scale regime have been considerable challenges in ‘soft lithography’ to achieve nanodevices with enhanced performances. In this technology, the resolution of pattern integrations is significantly rely on the materials' properties of polydimethylsiloxane (PDMS) stamps. Since commercial PDMS stamps have shown limitations in nano-scale resolution soft lithography due to their low physical toughness and high thermal expansion coefficients, we developed stiffer, photocured PDMS silicon elastomers designed, specifically for nano-sized soft lithography and photopatternable nanofabrications.

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Thermal expansion coefficients of NH4ReO4and NH4IO4down to 58 K

The Journal of Chemical Physics ◽

10.1063/1.448439 ◽

1985 ◽

Vol 82 (3) ◽

pp. 1611-1612 ◽

Cited By ~ 10

Author(s):

Stanley L. Segel ◽

H. Karlsson ◽

T. Gustavson ◽

K. Edstrom

Keyword(s):

Thermal Expansion ◽

Thermal Expansion Coefficients ◽

Expansion Coefficients

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Organizing Cells Within Non-Periodic Microarchitectured Materials That Achieve Graded Thermal Expansions

Volume 2B: 41st Design Automation Conference ◽

10.1115/detc2015-46638 ◽

2015 ◽

Author(s):

Jonathan B. Hopkins ◽

Lucas A. Shaw ◽

Todd H. Weisgraber ◽

George R. Farquar ◽

Christopher D. Harvey ◽

...

Keyword(s):

Finite Element Analysis ◽

Thermal Expansion ◽

Young’S Modulus ◽

Young's Modulus ◽

Element Analysis ◽

Thermal Expansion Coefficients ◽

Large Lattice ◽

Unit Cells ◽

Expansion Coefficients ◽

Bulk Behavior

The aim of this paper is to introduce an approach for optimally organizing a variety of different unit cell designs within a large lattice such that the bulk behavior of the lattice exhibits a desired Young’s modulus with a graded change in thermal expansion over its geometry. This lattice, called a graded microarchitectured material, can be sandwiched between two other materials with different thermal expansion coefficients to accommodate their different expansions or contractions caused by changing temperature while achieving a desired uniform stiffness. First, this paper provides the theory necessary to calculate the thermal expansion and Young’s modulus of large multi-material lattices that consist of periodic (i.e., repeating) unit cells of the same design. Then it introduces the theory for calculating the graded thermal expansions of a large multimaterial lattice that consists of non-periodic unit cells of different designs. An approach is then provided for optimally designing and organizing different unit cells within a lattice such that both of its ends achieve the same thermal expansion as the two materials between which the lattice is sandwiched. A MATLAB tool is used to generate images of the undeformed and deformed lattices to verify their behavior and various examples are provided as case studies. The theory provided is also verified and validated using finite element analysis and experimentation.

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