The 4875 Å Band System of cis Glyoxal

1971 ◽  
Vol 49 (3) ◽  
pp. 317-322 ◽  
Author(s):  
G. N. Currie ◽  
D. A. Ramsay
Keyword(s):  
High Resolution ◽  
Trans Isomer ◽  
Band System ◽  
Rotational Analysis ◽  
Molecular Constants ◽  
Rotational Constants ◽  
Type C ◽  
First Time ◽  
Cis Isomer

The 4875 Å band of glyoxal has been photographed in absorption under high resolution and a rotational analysis carried out. The band is of type C and the principal molecular constants are: A′ = 0.9069 cm−1, B′ = 0.1983 cm−1, C′ = 0.1627 cm−1, A″ = 0.8910 cm−1, B″ = 0.2066 cm−1, C″ = 0.1681 cm−1, v0 = 20 507.57 cm−1. The A-rotational constants are smaller by a factor of ~2 than the constants found earlier for trans glyoxal. The new results are consistent with the assignment of the band to an allowed 1B1–1A1 (π*–n) transition of cis glyoxal. Temperature studies indicate that the cis isomer lies 1125 ± 100 cm−1 above the trans isomer. This is the first time that cis glyoxal has been detected experimentally.

High-resolution studies of the Herzberg band system (C1Σ+ – A1Π]) in the 13C18O molecule

1988 ◽  
Vol 66 (11) ◽  
pp. 1012-1024 ◽  
Author(s):  
R. Kępa
Keyword(s):  
High Resolution ◽  
Band System ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Combined Analysis ◽  
Isotopic Molecule ◽  
Vibrational Constants ◽  
First Time ◽  
Π State

Seven bands ((0–0) – (0–6)) belonging to the Herzberg system of 13C18O have been recorded in emission using conventional photographic spectroscopy. For the first time, lines of this system have been recorded at high resolution and identified. After the rotational analysis of bands, the rotational constants of the C1Σ+ (ν = 0) and A1Π (ν = 0–6) states, as well as the vibrational constants of the A1Π state, have been determined. A combined analysis of the bands of the Herzberg and Ångström systems have made it possible to determine the constants of the B1Σ+ state more precisely. Numerous rotational perturbations observed in the A1Π state in this isotopic molecule have been analyzed.

Rotational Analysis of the A2Π–X2Σ+ Band System of the BeBr Molecule

1975 ◽  
Vol 53 (14) ◽  
pp. 1321-1326 ◽  
Author(s):  
M. Carleer ◽  
M. Herman ◽  
R. Colin
Keyword(s):  
High Resolution ◽  
Hollow Cathode ◽  
Band System ◽  
Rotational Analysis ◽  
Molecular Constants ◽  
Bromine Vapor

A rotational analysis has been performed on the 0–0 band of the A2Π–X2Σ+ transition of the BeBr molecule photographed at high resolution in emission from a beryllium hollow cathode in the presence of bromine vapor. The following principal molecular constants have been determined:[Formula: see text]

STRUCTURE OF THE BAND SPECTRUM OF THE CuBr MOLECULE: I. ROTATIONAL STRUCTURE OF THE C SYSTEM OF 63Cu81Br

1967 ◽  
Vol 45 (8) ◽  
pp. 2805-2807 ◽  
Author(s):  
P. Ramakoteswara Rao ◽  
K. V. S. R. Apparao
Keyword(s):  
Fine Structure ◽  
High Resolution ◽  
Structure Analysis ◽  
Band System ◽  
Rotational Structure ◽  
Band Spectrum ◽  
Rotational Analysis ◽  
Molecular Constants ◽  
Fine Structure Analysis

The C band system of 63Cu81Br, lying in the region 3 900–4 600 Å, has been photographed in emission under high resolution and rotational analysis of the (2–0), (1–0), (0–0), (0–1), (0–2), and (1–3) bands carried out. The system is shown to involve a 1Σ(C1Σ)–1Σ(X1Σ) transition. The molecular constants of 63Cu81Br obtained from this fine-structure analysis are as follows:[Formula: see text]

High-resolution studies of the near-ultraviolet bands of oxygen: III: the system

1986 ◽  
Vol 64 (6) ◽  
pp. 726-732 ◽  
Author(s):  
B. Coquart ◽  
D. A. Ramsay
Keyword(s):  
High Resolution ◽  
Electron Configuration ◽  
Rotational Analysis ◽  
Molecular Constants ◽  
Rotational Constants ◽  
Near Ultraviolet ◽  
Path Lengths

Ten bands of the [Formula: see text] system of oxygen have been observed in absorption using longer path lengths than in the earlier work of Herzberg (1953). Rotational analysis of the bands confirms that the A′ 3Δu state is an inverted state as expected from electron-configuration arguments. Rotational assignments are given for the [Formula: see text] and [Formula: see text] sub-bands with ν′ = 2–11; weaker [Formula: see text] sub-bands are identified for ν′ = 5–11. Sub-band origins and rotational constants are given for all the bands. The following derived molecular constants are obtained:[Formula: see text]A comparison of the frequencies of the diffuse bands of oxygen with the sub-band origins of the [Formula: see text] bands shows convincingly that the diffuse bands can be assigned to a weak (O2)2 complex in which one of the O2 molecules is excited to the A′ 3Δu state.

The blΣ+–X3Σ− band system of the PBr molecule

1979 ◽  
Vol 57 (7) ◽  
pp. 1051-1058 ◽  
Author(s):  
R. Colin
Keyword(s):  
High Resolution ◽  
Microwave Discharge ◽  
Band System ◽  
Rotational Analysis ◽  
Molecular Constants

Six bands of the b1Σ+–X3Σ− transition of the PBr molecule have been observed in a microwave discharge of PBr3 + He. High resolution spectra have allowed the rotational analysis of the 0–0 and 1–1 bands. The principal molecular constants obtained are:X3Σ−: P79Br; ωe = 458.35 cm−1, Be = 0.16067 cm−1; P81Br; ωe = 457.78 cm−1, Be = 0.15958 cm−1; re = 2.1714 Å.B1Σ+: P79Br; ωe = 485.47 cm−1, Be = 0.16509 cm−1; P81Br; ωe = 483.84 cm−1, Be = 0.16399 cm−1; re = 2.1421 Å and Te = 11779.75 cm−1.

The rotational analysis of the A1Π–X1Σ+ system of Si130Te

1992 ◽  
Vol 70 (5) ◽  
pp. 291-294 ◽  
Author(s):  
Sheila Gopal ◽  
M. Singh ◽  
G. Lakshminarayana
Keyword(s):  
High Resolution ◽  
Emission Spectrum ◽  
Microwave Discharge ◽  
Band System ◽  
Rotational Structure ◽  
Quartz Tube ◽  
Rotational Analysis ◽  
Rotational Constants

The emission spectrum of Si130Te was excited by microwave discharge (2450 MHz) in a sealed quartz tube. The A1Π–X1Σ+ band system (3100–3900 Å) (1 Å = 10−10 m) photographed under high resolution on a 10.6 m Ebert grating spectrograph. The rotational analysis of 32 bands was carried out, which led to the determination of the accurate vibrational and rotational constants. The rotational structure belonging to ν′ > 9 levels appear to be perturbed.

Rotational analysis of the B2Σ+ – A2Πi system of the 12C16O+ molecule

1987 ◽  
Vol 65 (1) ◽  
pp. 94-100 ◽  
Author(s):  
Z. Jakubek ◽  
R. Kepa ◽  
A. Para ◽  
M. Rytel
Keyword(s):  
High Resolution ◽  
Least Squares ◽  
Least Squares Method ◽  
Nonlinear Least Squares ◽  
Spin Rotation ◽  
Spin Orbit ◽  
Rotational Analysis ◽  
Molecular Constants ◽  
Nonlinear Least Squares Method ◽  
First Time

The three bands (0–0, 1–0, 0–1) of the B2Σ+ – A2Πi system of the 12C16O+ molecule have been photographed at high resolution. In total, 824 lines were measured, from which 608 were fitted by a nonlinear least squares method to determine 33 molecular constants. The band-by-band results were merged to obtain 23 molecular constants for the B2Σ+, ν = 0 and 1, and A2Πi, ν = 0 and 1, states. The Λ-doubling constants and spin-orbit constants in the A2Πi, ν = 1 state and spin-rotation constants in the B2Σ+, ν = 0 and 1 states were obtained for the first time, and other constants were defined more precisely.

Spectrum of SO: Analysis of the B3Σ−–X3Σ− and A3 Π–X3Σ− band systems

1969 ◽  
Vol 47 (9) ◽  
pp. 979-994 ◽  
Author(s):  
R. Colin
Keyword(s):  
Absorption Spectrum ◽  
High Resolution ◽  
Microwave Discharge ◽  
Flash Photolysis ◽  
Band System ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Π State

The absorption spectrum of SO radicals produced by flash photolysis of a mixture of COS + O2 + Ar is investigated. A partial rotational analysis of the previously known bands of the B3Σ−–X3Σ− transition which lie in the region of 1900 to 2400 Å is presented, and the predissociations and perturbations of the B3Σ−state are discussed. A complex red-degraded band system near 2500 Å, previously observed in emission and attributed to SO2, is shown to be due to a 3Π–X3Σ− transition of the SO molecule. Effective rotational constants of the 3Π state are derived from the analysis of these bands photographed at high resolution. In order to obtain the vibrational numbering of the 3Π–X3Σ− bands, these were also photographed in emission from a microwave discharge through a mixture of S18O2 + S16O2. A general discussion of the currently known states of the SO molecule is given.

Rotational Analysis of the A2Π–X2Σ+ Band System of the BeCl Molecule

1972 ◽  
Vol 50 (2) ◽  
pp. 171-184 ◽  
Author(s):  
R. Colin ◽  
M. Carleer ◽  
F. Prevot
Keyword(s):  
High Resolution ◽  
Microwave Discharge ◽  
Band System ◽  
Opposite Sign ◽  
Electronic Configuration ◽  
Rotational Analysis ◽  
Molecular Constants ◽  
Π State

A rotational analysis has been performed on the 0–0, 1–1, 1–0, and 2–1 bands of the A2Π–X2Σ+ band system of the BeCl molecule photographed at high resolution in emission from a microwave discharge. The following principal molecular constants have been obtained.[Formula: see text]Inspection of the low J value lines shows that the A2Π state is a regular state derived from the electronic configuration σ2σ2π4π although the Λ-doubling constants p and q are of opposite sign.

STRUCTURE OF THE BAND SPECTRUM OF CuCl MOLECULE: II. ROTATIONAL STRUCTURE OF THE F–X BAND SYSTEM OF Cu65Cl35

1962 ◽  
Vol 40 (4) ◽  
pp. 412-422 ◽  
Author(s):  
P. Ramakoteswara Rao ◽  
R. K. Asundi ◽  
J. K. Brody
Keyword(s):  
High Resolution ◽  
Electronic Transition ◽  
Band System ◽  
Rotational Structure ◽  
Band Spectrum ◽  
Rotational Analysis ◽  
Molecular Constants ◽  
X Band ◽  
Π State

The F–X band system of Cu65Cl35 extending from 3700 to 4200 Å has been photographed in emission under high resolution. Rotational analysis of the (3,0), (2,0), (1,0), (0,0), (0,1), and (0,2) bands of the system has been made. The electronic transition involved is found to be 1Π–1Σ. The Λ-type doubling in the 1Π state is negligible. The principal molecular constants obtained are as follows (cm−1 units)[Formula: see text]

Sign in / Sign up

Export Citation Format

Share Document