Laser double optical resonance excitation-ionization of Mo with optogalvanic detection

We report on measurements of resonant three-step, two-colour ionization of atomic molybdenum, using a hollow cathode lamp (HCL) with optogalvanic detection. Wavelength scans were made for two specific transitions involved in the ionization pathways under investigation, namely 4d5(6S)5s 7S3 - 4d5(6S)5p 7P4 and 4d5(6S)5p 7P4 - 4d5(6S)6d 7D5.So-called ‘slow’ and ‘fast’ optogalvanic signals were observed for each pathway. Results confirm the HCL as a cost effective spectroscopic investigation tool. In particular its use in the optogalvanic mode of operation allows one to precisely, easily and reliably tune the wavelength of one or more lasers to resonances of interest for experiments in the general domain of atomic vapour laser isotope selection (AVLIS). The measurements are closely related to the Selective Production of Exotic Species (SPES) project at the ISOL facility and were performed in the recently established laser laboratory in Legnaro National Laboratories of INFN.

Resistive MHD modes in hollow cathodes external plasma

A significant number of plasma instabilities occur in the region just outside of hollow cathodes, depending on the injected gas flow, the current level and the application of an external magnetic field. In particular, the presence of an axial magnetic field induces a helical mode, affecting all the plasma parameters and the total current transported by the plasma. To explore the onset and behavior of this helical mode, the fluctuations in the plasma parameters in the current-carrying plume outside of a hollow cathode discharge have been investigated. The hollow cathode was operated at a current of 25 A, and at variable levels of propellant flow rate and applied magnetic fields. Electromagnetic probes were used to measure the electromagnetic fluctuations, and correlation analysis between each of the probe signals provided spatial-temporal characterization of the generated waves. Time-averaged plasma parameters, such as plasma potential and ion energy distribution function, were also collected in the near-cathode plume region by means of scanning emissive probe and retarding potential analyzer. The results show that the helical mode exists in the cathode plume at sufficiently high applied magnetic field, and is characterized by the presence of a finite electromagnetic component in the axial direction, detectable at discharge currents $\geq$ 25 A. A theoretical analysis of this mode reveals that one possible explanation is consistent with the hypotheses of resistive magnetohydrodynamics, which predicts the presence of helical modes in the forms of resistive kink. The analysis has been carried out by linear perturbation of the resistive MHD equations, from which it is possible to obtain the dispersion relation of the mode and find the $k-\omega$ unstable branch associated with the instability. These findings provided the basis for more detailed investigation of resistive MHD modes and their effect in the plume of hollow cathodes developed for electric propulsion application.

Recent Advances in Hollow Cathode Technology for Plasma-Enhanced ALD—Plasma Surface Modifications for Aluminum and Stainless-Steel Cathodes

Recent designs have allowed hollow cathode gas plasma sources to be adopted for use in plasma-enhanced atomic layer deposition with the benefit of lower oxygen contamination for non-oxide films (a brief review of this is provided). From a design perspective, the cathode metal is of particular interest since—for a given set of conditions—the metal work function should determine the density of electron emission that drives the hollow cathode effect. However, we found that relatively rapid surface modification of the metal cathodes in the first hour or more of operation has a stronger influence. Langmuir probe measurements and hollow cathode electrical characteristics were used to study nitrogen and oxygen plasma surface modification of aluminum and stainless-steel hollow cathodes. It was found that the nitridation and oxidation of these metal cathodes resulted in higher plasma densities, in some cases by more than an order of magnitude, and a wider range of pressure operation. Moreover, it was initially thought that the use of aluminum cathodes would not be practical for gas plasma applications, as aluminum is extremely soft and susceptible to sputtering; however, it was found that oxide and nitride modification of the surface could protect the cathodes from such problems, possibly making them viable.