The d3Σ–a3Πr Transition of SiO
Keyword(s):
The triple headed and violet degraded band of SiO at 2970 Å has been excited in a high frequency discharge through a mixture of SiCl4, oxygen, and argon flowing at low pressures. From a study of the high resolution spectrum, this band has been assigned to a 3Σ–3Π transition. The final state has been identified with the well known a3Πr state of SiO, and the initial state has been designated as the d3Σ and located at 33 640 cm−1 above the a3Πr. The rotational constants determined for the d3Σ state are (in cm−1): [Formula: see text]
Keyword(s):
1994 ◽
Vol 164
(2)
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pp. 583-585
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2018 ◽
1990 ◽
Vol 15
(2)
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pp. A10
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2016 ◽
Vol 168
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pp. 29-39
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