The infrared spectrum of HNO

1983 ◽  
Vol 61 (7) ◽  
pp. 1106-1119 ◽  
Author(s):  
J. W. C. Johns ◽  
A. R. W. McKellar ◽  
E. Weinberger
Keyword(s):  
Fourier Transform ◽  
Infrared Spectrum ◽  
Flow System ◽  
Fourier Transform Spectrometer ◽  
Hydrogen Deuterium ◽  
Vibration Rotation

Vibration–rotation spectra of HNO (DNO) have been observed in a flow system following the reaction of hydrogen (deuterium) atoms with NO. The spectra were recorded at approximately Doppler limited resolution with a large Fourier transform spectrometer. Complete analyses have been made of the ν1 bands of HNO and DNO with the following results (in cm−1).[Formula: see text]Spectra of ν2 (NO stretching) were also observed in both HNO and DNO, but ν3 (bending) proved too weak to be detected in either molecule.

Lambda doubling in the infrared spectrum of SH

1984 ◽  
Vol 62 (12) ◽  
pp. 1420-1425 ◽  
Author(s):  
R. J. Winkel Jr. ◽  
Sumner P. Davis
Keyword(s):  
Fourier Transform ◽  
Infrared Spectrum ◽  
Ground State ◽  
Solar Observatory ◽  
Fourier Transform Spectrometer ◽  
Multiplet Splitting ◽  
National Solar Observatory ◽  
Vibration Rotation ◽  
The Fourier Transform ◽  
First Time

The (1–0), (2–1), and (3–2) infrared vibration–rotation bands of the X2Π ground state of sulfur monohydride were observed in emission from a furnace. Multiplet splitting produces two subbands, each of which exhibits lambda splitting. The band heads were observed for the first time, 285 lines were measured, and a calculation of lambda-doubling parameters was made. The spectrum was recorded using the Fourier transform spectrometer at the National Solar Observatory (Kitt Peak).

The infrared spectrum of CS

1984 ◽  
Vol 62 (12) ◽  
pp. 1414-1419 ◽  
Author(s):  
R. J. Winkel Jr. ◽  
Sumner P. Davis ◽  
Rubén Pecyner ◽  
James W. Brault
Keyword(s):  
Fourier Transform ◽  
Infrared Emission ◽  
Solar Observatory ◽  
Band Head ◽  
The Other ◽  
Fourier Transform Spectrometer ◽  
National Solar Observatory ◽  
Carbon Monosulfide ◽  
Vibration Rotation ◽  
The Fourier Transform

The infrared emission spectrum of carbon monosulfide was observed as a sequence of vibration–rotation bands in the X1Σ+ state, with strong heads of the Δν = 2 sequence degraded to the red. Eight bands of 12C32S were identified, and bands corresponding to the isotope 12C34S were also observed. The most prominent band head, that of the (2–0) band, is at 2585 cm−1, with the other heads spaced approximately 26 cm−1 to smaller wavenumbers. Our data, taken with the Fourier transform spectrometer at the National Solar Observatory (Kitt Peak) include the first reported laboratory observations of the band heads and as many as 200 lines in each band. These observations allowed the calculation of vibrational and rotational constants to higher order than previously reported.

High-Resolution Infrared Spectrum of Diazirine, H2CN2. Rovibrational Analysis of the Methylene Deformation Band

1988 ◽  
Vol 43 (4) ◽  
pp. 331-337 ◽  
Author(s):  
A. Gambi ◽  
A. Baldacci ◽  
S. Giorgianni
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Infrared Spectrum ◽  
Least Squares ◽  
Deformation Band ◽  
Fourier Transform Spectrometer ◽  
Centrifugal Distortion ◽  
Molecular Constants ◽  
Centrifugal Distortion Constants

Abstract The infrared spectrum of diazirine has been recorded at Doppler resolution with a high informa­tion Fourier transform spectrometer. The ν3 fundamental has been reinvestigated and the overall assignment of the rovibrational transitions has been carried out. From the least-squares analysis a more accurate set of molecular constants including the sextic centrifugal distortion constants has been determined for the level υ3 = 1 and will be reported here. The higher resolution achieved here allowed the assignment of weaker lines and many Q branch transitions. Moreover many blended lines have now been resolved and could be properly assigned.

scholarly journals Stacked Average Far-infrared Spectrum of Dusty Star-forming Galaxies from theHerschel/SPIRE Fourier Transform Spectrometer

2017 ◽  
Vol 848 (1) ◽  
pp. 30 ◽  
Author(s):  
Derek Wilson ◽  
Asantha Cooray ◽  
Hooshang Nayyeri ◽  
Matteo Bonato ◽  
Charles M. Bradford ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Infrared Spectrum ◽  
Far Infrared ◽  
Fourier Transform Spectrometer ◽  
Star Forming

The high-resolution infrared spectrum of BrCl

1994 ◽  
Vol 72 (11-12) ◽  
pp. 1145-1154 ◽  
Author(s):  
Hiromichi Uehara ◽  
Toichi Konno ◽  
Yasushi Ozaki ◽  
Koui Horiai ◽  
Kuniaki Nakagawa ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Standard Deviation ◽  
High Resolution ◽  
Infrared Spectrum ◽  
Potential Function ◽  
Internuclear Distance ◽  
Spectral Lines ◽  
Fourier Transform Spectrometer ◽  
Isotopic Species ◽  
Correction Terms

The high-resolution infrared spectrum of BrCl has been observed with a Fourier transform spectrometer. About 850 spectral lines for the Δν = 1 sequences of the four isotopic species, 79Br35Cl, 81Br35Cl, 79Br37Cl, and 81Br37Cl have been measured between 417 and 461 cm−1. They have been fitted with a standard deviation of 0.000 146 cm−1 to a Dunham potential function using eight coefficients that included two Watson-type Δ correction terms. Dunham Yij coefficients have been derived for each of the four isotopic species. The equilibrium internuclear distance re of BrCl is 2.136 053 28 (67) Å.

The antisymmetric stretching fundamental band of free MgD2

2004 ◽  
Vol 82 (6) ◽  
pp. 947-950 ◽  
Author(s):  
Alireza Shayesteh ◽  
Dominique RT Appadoo ◽  
Iouli Gordon ◽  
Peter F Bernath
Keyword(s):  
Fourier Transform ◽  
Emission Spectrum ◽  
Electrical Discharge ◽  
Bond Distance ◽  
Infrared Emission ◽  
Fourier Transform Spectrometer ◽  
High Temperature Furnace ◽  
Vibration Rotation ◽  
First Time ◽  
Temperature Furnace

The gaseous MgD2 molecule has been synthesized for the first time in an electrical discharge inside a high-temperature furnace. The high-resolution infrared emission spectrum of MgD2 was recorded with a Fourier transform spectrometer, and the antisymmetric stretching mode (v3) was detected near 1176.5 cm–1. The v3 band was rotationally analyzed, and the r0 Mg—D bond distance was determined to be 1.700 874(8) Å.Key words: gaseous MgD2, vibration-rotation emission spectrum, Mg-D bond distance.

scholarly journals The Infrared Spectrum of Diazirine, H2C15N2 Rovibrational Analysis of the V3 Fundamental

1986 ◽  
Vol 41 (9) ◽  
pp. 1159-1165 ◽  
Author(s):  
Jürgen Vogt ◽  
Alberto Gambi
Keyword(s):  
Fourier Transform ◽  
Infrared Spectrum ◽  
Fourier Transform Spectrometer ◽  
Centrifugal Distortion ◽  
Mid Infrared ◽  
Centrifugal Distortion Constants

The mid-infrared spectrum of 15N-labeled diazirine has been recorded using a Fourier transform spectrometer at a resolution of 0.08 cm-1. The v3 fundamental at 1452.49 cm-1 which essentially corresponds to a symmetric methylene deformation has been analyzed in detail. The rovibrational assignment is given and, using Watson’s A-reduced Hamiltonian, the rotational and centrifugal distortion constants for the v3 = 1 level could be determined.

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